GB850449A - Colored nacreous materials and method for production thereof - Google Patents
Colored nacreous materials and method for production thereofInfo
- Publication number
- GB850449A GB850449A GB30796/58A GB3079658A GB850449A GB 850449 A GB850449 A GB 850449A GB 30796/58 A GB30796/58 A GB 30796/58A GB 3079658 A GB3079658 A GB 3079658A GB 850449 A GB850449 A GB 850449A
- Authority
- GB
- United Kingdom
- Prior art keywords
- nacreous
- sulphides
- suspension
- thioacetamide
- particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0015—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings
- C09C1/0021—Pigments exhibiting interference colours, e.g. transparent platelets of appropriate thinness or flaky substrates, e.g. mica, bearing appropriate thin transparent coatings comprising a core coated with only one layer having a high or low refractive index
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/0078—Pigments consisting of flaky, non-metallic substrates, characterised by a surface-region containing free metal
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/10—Interference pigments characterized by the core material
- C09C2200/102—Interference pigments characterized by the core material the core consisting of glass or silicate material like mica or clays, e.g. kaolin
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/10—Interference pigments characterized by the core material
- C09C2200/1054—Interference pigments characterized by the core material the core consisting of a metal
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/10—Interference pigments characterized by the core material
- C09C2200/1062—Interference pigments characterized by the core material the core consisting of an organic compound, e.g. Liquid Crystal Polymers [LCP], Polymers or natural pearl essence
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/10—Interference pigments characterized by the core material
- C09C2200/1087—Interference pigments characterized by the core material the core consisting of bismuth oxychloride, magnesium fluoride, nitrides, carbides, borides, lead carbonate, barium or calcium sulfate, zinc sulphide, molybdenum disulphide or graphite
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C2220/00—Methods of preparing the interference pigments
- C09C2220/10—Wet methods, e.g. co-precipitation
Abstract
Nacreous particulate material such as pearl essence lead sub-carbonate, bismuth oxychloride, &c., is coloured by suspending individual particles of the material in a liquid medium and precipitating colouring matter on them in situ, the rate of precipitation being controlled so that precipitated colouring matter is deposited directly on the individual particles without destroying their characteristic geometry. Precipitation may be effected by the addition to the liquid suspension of dilute solutions e.g. of approximately 0,1% to 10% concentration, of two chemical reagents or a second reagent may be added continuously or incrementally, after the first. The coloured nacreous material may be included in surface coating compositions such as paints, nitrocellulose lacquers, fingernail polishes in the proportion of up to 10% of the total weight, in plastics by addition to the ingredients prior to polymerization thereof, and may be employed in the manufacture of leather wearing apparel. According to an example, crystals of natural pearl essence were suspended in 10 c.c. ethyl acetate and the suspension was then stirred into a solution of 1,13 g. thioacetamide in 65 c.c. ethyl acetate. A solution of 1,1g. chlorauric acid tri-hydrate in 40 c.c. ethyl acetate was added dropwise with stirring to the suspension of pearl essence containing the dissolved thioacetamide, the rate of dropwise addition being regulated so that substantially all of the aurous thioacetamide precipitate deposited on the suspended pearl essence as it was formed. 25 c.c. pyridine was added to the stirred suspension and the reaction mixture was heated on a water bath at 90 DEG C. for about 10 minutes. The reaction mixture was centrifuged, the precipitate was washed first with methanol and then with ethyl acetate. The washed product imparted an attractive greenish-gold colour, exhibiting the characteristic pearly lustre of the original pearl essence, to a fingernail lacquer in which it was suspended. A further example is directed to making a silvery-grey coloured nacreous product by precipitating on to nacreous particles, at a pH of about 7,5, metallic gold by reaction between hydroxylamine and chlorauric acid both in methanolic solution. In other examples, the following substances respectively were precipitated on to the nacreous particles: cadmium, manganese, antimony and iron sulphides; mixed antimony and iron sulphides; mixed antimony, iron and tin sulphides; mixed tin and cadmium sulphides; mixed tin and iron sulphides; nickel dimethyl glyoxime; palladiumdimethyl glyoxime; palladium furil dioxime; silver; and phosphomolybdate-dye complexes.ALSO:Nacreous particulate material such as pearl essence, lead subcarbonate, bismuth oxychloride, mercurous chloride, talc, brucite, stilbite &c., is coloured by suspending individual particles of the material in a liquid medium and precipitating colouring matter on them in situ, the rate of precipitation being controlled so that precipitated colouring matter is deposited directly on the individual particles without destroying their characteristic geometry. Precipitation may be effected by the addition to the liquid suspension of dilute solutions e.g. of approximately 0.1% to 10% concentration, of two chemical reagents or a second reagent may be added continuously or incrementally after the first. According to an example, a bright yellow coloured nacreous product was made by precipitating on to nacreous particles palladium dimethyl glyoxime by adding dropwise to a suspension of the nacreous particles containing a methanolic solution of dimethyl glyoxime and 2-amino-2-methyl-1-propanol, palladium chloride in a solution of hydrochloric acid and methanol. Examples of other metal compounds which may be precipitated on the nacreous materials relate to aurous thioacetamide by reaction between thioacetamide and chlorauric acid trihydrate, cadmium, manganese, antimony, iron and tin sulphides and mixed sulphides, nickel dimethyl glyoxime by reaction between nickel chloride and dimethyl glyoxime, and palladium furil dioxime.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US850449XA | 1957-11-26 | 1957-11-26 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB850449A true GB850449A (en) | 1960-10-05 |
Family
ID=22189104
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB30796/58A Expired GB850449A (en) | 1957-11-26 | 1958-09-26 | Colored nacreous materials and method for production thereof |
Country Status (2)
Country | Link |
---|---|
FR (1) | FR1212490A (en) |
GB (1) | GB850449A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1273098B (en) * | 1961-05-04 | 1968-07-18 | Mearl Corp Ossining | Mother-of-pearl pigment |
DE1467468B2 (en) * | 1961-06-28 | 1971-09-30 | Du Pont | Mica flake pigment and its use for the production of coating agents and self-supporting plastic films |
EP1443083A1 (en) * | 2003-02-03 | 2004-08-04 | MERCK PATENT GmbH | Pearlescent pigments based on selectively absorbing layers of chalcogenide, oxychalcogenide and mixed chalcogenides |
GB2576627A (en) * | 2018-07-20 | 2020-02-26 | Johnson Matthey Plc | Nanoparticles and preparation method |
-
1958
- 1958-09-26 GB GB30796/58A patent/GB850449A/en not_active Expired
- 1958-10-17 FR FR1212490D patent/FR1212490A/en not_active Expired
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1273098B (en) * | 1961-05-04 | 1968-07-18 | Mearl Corp Ossining | Mother-of-pearl pigment |
DE1467468B2 (en) * | 1961-06-28 | 1971-09-30 | Du Pont | Mica flake pigment and its use for the production of coating agents and self-supporting plastic films |
DE1467468C3 (en) * | 1961-06-28 | 1972-05-04 | Du Pont | Mica flake pigment and its use for the production of coating agents and self-supporting plastic films |
EP1443083A1 (en) * | 2003-02-03 | 2004-08-04 | MERCK PATENT GmbH | Pearlescent pigments based on selectively absorbing layers of chalcogenide, oxychalcogenide and mixed chalcogenides |
GB2576627A (en) * | 2018-07-20 | 2020-02-26 | Johnson Matthey Plc | Nanoparticles and preparation method |
GB2576627B (en) * | 2018-07-20 | 2023-02-22 | Johnson Matthey Plc | Nanoparticles and preparation method |
Also Published As
Publication number | Publication date |
---|---|
FR1212490A (en) | 1960-03-24 |
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