GB849376A - New disazo pigments - Google Patents
New disazo pigmentsInfo
- Publication number
- GB849376A GB849376A GB823158A GB823158A GB849376A GB 849376 A GB849376 A GB 849376A GB 823158 A GB823158 A GB 823158A GB 823158 A GB823158 A GB 823158A GB 849376 A GB849376 A GB 849376A
- Authority
- GB
- United Kingdom
- Prior art keywords
- aminophenyl
- terephthalamide
- chloro
- formula
- conh
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B35/00—Disazo and polyazo dyes of the type A<-D->B prepared by diazotising and coupling
- C09B35/02—Disazo dyes
- C09B35/039—Disazo dyes characterised by the tetrazo component
- C09B35/28—Disazo dyes characterised by the tetrazo component the tetrazo component containing two aryl nuclei linked by at least one of the groups —CON<, —SO2N<, —SO2—, or —SO2—O—
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Photoreceptors In Electrophotography (AREA)
Abstract
Diamines of formula NH2-X-NHCO-Y-CONH-X-NH2, wherein X is a substituted or unsubstituted benzene ring having the-CONH-and-NH2-groups in the meta-or para-positions and Y is an arylene radical optionally substituted by halogen, are prepared by reacting a functional derivative (e.g. anhydride, ester or acid chloride) of an aryl dicarboxylic acid with a m-or p-nitroaniline and reducing the nitro groups to amino groups. They are used as components in the preparation of disazo pigments (see Group IV(c) ). In an example a mixture of 2-chloro-4-nitroaniline, terephthaloyl chloride and toluene is refluxed and the precipitated N: N1-di(21-chloro-41-nitrophenyl)-terephthalamide is filtered off and reduced with iron and hydrochloric acid in ethanol to N : N1-di (21-chloro-41-aminophenyl)-terephthalamide. Diamines specified include N : N1-di (21-methoxy51-aminophenyl) isophthalamide, N : N1-di (21-methyl-41-aminophenyl) terephthalamide, 2 : 5-dichloro - N : N1 - di (21 - methoxy - 51 - amino - phenyl) - terephthalamide and N : N1 - di (21 - methoxy-51-aminophenyl)-naphthalamide.ALSO:The invention comprises disazo pigments of formula: <FORM:0849376/IV (c)/1> wherein R is an alkyl or aryl radical, Ar is an aryl radical, X is a substituted or unsubstituted benzene ring wherein the -CONH- and -N=N-groups are in the meta- or parapositions to each other and Y is an arylene radical optionally substituted by halogen. They are prepared by coupling 2 moles of an amide of formula R.COCH2 CONHAr with 1 mole of a tetrazorised diamine of formula H2N-X-NHCO-Y-CONH-X-NH2. Alternatively they may be prepared by reacting 1 mole of a functional derivative (e.g. anhydride, ester or acid halide) of an aryl dicarboxylic acid with 2 moles of an aminoazo compound of formula: <FORM:0849376/IV (c)/2> The pigments are used to colour rubber, synthetic polymers and paints in yellow shades. In an example N : N1-di(21-chloro -41- aminophenyl)- terephthalamide is tetrazotised and coupled with acetoacet -mxylidide. Further components specified include N : N1 -di(21-methoxy -51- aminophenyl)-isophthalamide, 2-chloro- or 2 : 5-dichloro-N : N1-di(21-chloro41- aminophenyl)-terephthalamide and N : N1-di(21-methoxy-51-aminophenyl)-naphthalamide; acetoacet(4-chloro -2 : 5- dimethoxy) anilide, benzoylacetanilide and acetoacet-alpha-naphthylamide.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB823158A GB849376A (en) | 1958-03-14 | 1958-03-14 | New disazo pigments |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB823158A GB849376A (en) | 1958-03-14 | 1958-03-14 | New disazo pigments |
Publications (1)
Publication Number | Publication Date |
---|---|
GB849376A true GB849376A (en) | 1960-09-28 |
Family
ID=9848486
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB823158A Expired GB849376A (en) | 1958-03-14 | 1958-03-14 | New disazo pigments |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB849376A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2846092A (en) * | 1956-12-10 | 1958-08-05 | Northrop Aircraft Inc | Dolly including a winch mechanism |
EP0055380A1 (en) * | 1980-12-23 | 1982-07-07 | Hoechst Aktiengesellschaft | Disazo compounds, methods for their preparation and their use |
-
1958
- 1958-03-14 GB GB823158A patent/GB849376A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2846092A (en) * | 1956-12-10 | 1958-08-05 | Northrop Aircraft Inc | Dolly including a winch mechanism |
EP0055380A1 (en) * | 1980-12-23 | 1982-07-07 | Hoechst Aktiengesellschaft | Disazo compounds, methods for their preparation and their use |
US4732975A (en) * | 1980-12-23 | 1988-03-22 | Hoechst Aktiengesellschaft | Disazo compounds |
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