GB849066A - Interpolymers and compositions containing the same - Google Patents

Interpolymers and compositions containing the same

Info

Publication number
GB849066A
GB849066A GB38366/58A GB3836658A GB849066A GB 849066 A GB849066 A GB 849066A GB 38366/58 A GB38366/58 A GB 38366/58A GB 3836658 A GB3836658 A GB 3836658A GB 849066 A GB849066 A GB 849066A
Authority
GB
United Kingdom
Prior art keywords
weight
formaldehyde
mixtures
mixture
interpolymers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB38366/58A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of GB849066A publication Critical patent/GB849066A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
    • C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02—Homopolymers or copolymers of hydrocarbons
    • C09D125/04—Homopolymers or copolymers of styrene
    • C09D125/08—Copolymers of styrene
    • C09D125/14—Copolymers of styrene with unsaturated esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
    • C09D161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C09D161/32—Modified amine-aldehyde condensates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
    • C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
    • C08L61/22—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
    • C08L61/24—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds with urea or thiourea

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

Interpolymers of 55 to 85% by weight of styrene, 5 to 35% by weight of ethyl acrylate and 5 to 15% by weight of methacrylic acid may be prepared by polymerising a mixture of monomers having the specified proportions in the presence of 25 to 400%, based on the weight of said mixture, of an aromatic solvent for said mixture at a temperature of 125 DEG to 200 DEG C. until substantially all the monomers are polymerised. The solvent may be benzene, toluene, xylene or mixtures thereof, and polymerisation may be effected in the presence of initiators, e.g. ditertiary-butyl peroxide, benzaldehyde peroxide, cumene hydroperoxide, 2,2-bis(tertiary-butylperoxy) butane, tertiary-butyl peracetate and diazoamino benzene, activators, inhibitors, surface active agents and chain transfer agents. The interpolymers may be used in coating compositions comprising compatible mixtures of 30 to 90% by weight of the interpolymer and 70 to 10% of melamine-formaldehyde-monohydric alcohol condensates, urea-formaldehyde-monohydric alcohol condensates or mixtures thereof, in solution in volatile organic solvents. The condensates may be prepared by reacting (1) urea and formaldehyde or a reaction product thereof, e.g. dimethylol urea, and (2) melamine and formaldehyde or a reaction product thereof, e.g. tetra-, penta- or hexamethylol melamine, with saturated monohydric alcohols, e.g. methanol, ethanol, propanol or butanol. Specified solvents are aromatic and aliphatic hydrocarbons, alcohols, ketones and esters, e.g. xylene, methyl ethyl ketone, butanol and mixtures thereof. The coating compositions may also contain pigments, e.g. metal oxides such as titanium dioxide, hydroxides, chromates, silicates, sulphides, sulphates and carbonates, carbon blacks, organic dyestuffs and lakes, and metal flake pigments such as aluminium. Specification 686,234 is referred to.
GB38366/58A 1958-02-27 1958-11-27 Interpolymers and compositions containing the same Expired GB849066A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US849066XA 1958-02-27 1958-02-27

Publications (1)

Publication Number Publication Date
GB849066A true GB849066A (en) 1960-09-21

Family

ID=22187949

Family Applications (1)

Application Number Title Priority Date Filing Date
GB38366/58A Expired GB849066A (en) 1958-02-27 1958-11-27 Interpolymers and compositions containing the same

Country Status (4)

Country Link
BE (1) BE576209A (en)
DE (1) DE1135118B (en)
FR (1) FR1217796A (en)
GB (1) GB849066A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3201374A (en) * 1961-06-21 1965-08-17 Du Pont Terpolymers containing at least 65% ethylene
US3215678A (en) * 1961-06-21 1965-11-02 Du Pont Copolymers of ethylene with vinyl esters and alpha-beta ethylenically unsaturated acids
US3434979A (en) * 1965-05-11 1969-03-25 Harry P Gregor Oleophilic-hydrophilic ion exchange resins
US4559162A (en) * 1981-03-10 1985-12-17 Ciba-Geigy Corporation Compositions of polymers based on acrylic acid, solvents, surfactants and, if appropriate, silicone oils, their preparation and their use as anti-foams and deaerating agents

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL8501949A (en) * 1985-07-08 1987-02-02 Dow Chemical Nederland STYRENE POLYMER RESIN WITH IMPROVED LIQUID PROPERTIES.

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2681897A (en) * 1950-10-06 1954-06-22 American Cyanamid Co Surface coating compositions comprising aminoplast resins and a thermoplastic copolymer containing a polymerized hydroxy alkyl ester of an alpha, beta ethylenically unsaturated carboxylic acid
BE548767A (en) * 1956-06-18 1956-12-18

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3201374A (en) * 1961-06-21 1965-08-17 Du Pont Terpolymers containing at least 65% ethylene
US3215678A (en) * 1961-06-21 1965-11-02 Du Pont Copolymers of ethylene with vinyl esters and alpha-beta ethylenically unsaturated acids
US3434979A (en) * 1965-05-11 1969-03-25 Harry P Gregor Oleophilic-hydrophilic ion exchange resins
US4559162A (en) * 1981-03-10 1985-12-17 Ciba-Geigy Corporation Compositions of polymers based on acrylic acid, solvents, surfactants and, if appropriate, silicone oils, their preparation and their use as anti-foams and deaerating agents

Also Published As

Publication number Publication date
BE576209A (en)
DE1135118B (en) 1962-08-23
FR1217796A (en) 1960-05-05

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