GB847676A - Process for the polymerisation of vinyl chloride - Google Patents

Process for the polymerisation of vinyl chloride

Info

Publication number
GB847676A
GB847676A GB3384557A GB3384557A GB847676A GB 847676 A GB847676 A GB 847676A GB 3384557 A GB3384557 A GB 3384557A GB 3384557 A GB3384557 A GB 3384557A GB 847676 A GB847676 A GB 847676A
Authority
GB
United Kingdom
Prior art keywords
magnesium
dioxan
diethyl
prepared
ether
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3384557A
Inventor
Laurence Stephen Rayner
Percy Arthur Small
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BE572533D priority Critical patent/BE572533A/xx
Priority to NL99445D priority patent/NL99445C/xx
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB3384557A priority patent/GB847676A/en
Priority to FR1214309D priority patent/FR1214309A/en
Publication of GB847676A publication Critical patent/GB847676A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/02—Monomers containing chlorine
    • C08F14/04—Monomers containing two carbon atoms
    • C08F14/06—Vinyl chloride

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Vinyl chloride is polymerised by contact with a dialkyl (preferably ditertiary alkyl) magnesium compound, particularly ditertiary butyl magnesium but diethyl magnesium is also mentioned. The polymerisation is conducted in an organic solvent, preferably etheric, e.g. diethyl ether and/or dioxan. In the Examples, the magnesium compound is prepared by adding dioxan to a solution of the corresponding Grignard reagent in ether whereupon a Mg Cl2 complex is precipitated, the desired compound removing in the supernatan liquid. Purification of the polymer may be effected by treatment with water, steam, alcohols such as methanol or butanol and/or acids (e.g. HCl), and dissolving in e.g. tetrahydrofuran followed by precipitation with e.g. methanol. It is stated that polyvinyl chlorides of high crystallisibilities can be prepared according to the invention and measurement of this characteristic is described.ALSO:Di-tertiary butyl and diethyl magnesium are prepared by treating ether solutions of tertiarybutyl magnesium chloride and ethyl magnesium bromide, respectively, with dioxan and removing the magnesium chloride complex precipitated.
GB3384557A 1957-10-30 1957-10-30 Process for the polymerisation of vinyl chloride Expired GB847676A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
BE572533D BE572533A (en) 1957-10-30
NL99445D NL99445C (en) 1957-10-30
GB3384557A GB847676A (en) 1957-10-30 1957-10-30 Process for the polymerisation of vinyl chloride
FR1214309D FR1214309A (en) 1957-10-30 1958-10-30 Process for the polymerization of vinyl chloride

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB3384557A GB847676A (en) 1957-10-30 1957-10-30 Process for the polymerisation of vinyl chloride

Publications (1)

Publication Number Publication Date
GB847676A true GB847676A (en) 1960-09-14

Family

ID=10358196

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3384557A Expired GB847676A (en) 1957-10-30 1957-10-30 Process for the polymerisation of vinyl chloride

Country Status (4)

Country Link
BE (1) BE572533A (en)
FR (1) FR1214309A (en)
GB (1) GB847676A (en)
NL (1) NL99445C (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3856767A (en) * 1971-04-21 1974-12-24 A Sturt Polymerisation process
US9915431B2 (en) 2013-03-14 2018-03-13 Honeywell International Inc. Gas pilot burner assembly

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3856767A (en) * 1971-04-21 1974-12-24 A Sturt Polymerisation process
US9915431B2 (en) 2013-03-14 2018-03-13 Honeywell International Inc. Gas pilot burner assembly

Also Published As

Publication number Publication date
NL99445C (en)
BE572533A (en)
FR1214309A (en) 1960-04-07

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