GB846574A - Process for the manufacture of para-xylene - Google Patents
Process for the manufacture of para-xyleneInfo
- Publication number
- GB846574A GB846574A GB1564657A GB1564657A GB846574A GB 846574 A GB846574 A GB 846574A GB 1564657 A GB1564657 A GB 1564657A GB 1564657 A GB1564657 A GB 1564657A GB 846574 A GB846574 A GB 846574A
- Authority
- GB
- United Kingdom
- Prior art keywords
- oxides
- mixed
- volume
- metals
- nitrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
- C07C5/393—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
- C07C5/41—Catalytic processes
- C07C5/412—Catalytic processes with metal oxides or metal sulfides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
- C07C2523/04—Alkali metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of rare earths
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/26—Chromium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/28—Molybdenum
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/30—Tungsten
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Para-xylene is prepared by the aromatisation of diisobutylene, triiso-butylene, their hydrogenation products or mixtures of such compounds over a solid aromatisation catalyst at 450-650 DEG C. and 0,4-0,9 vol. of liquid hydrocarbon feed per vol. of catalyst per hour in the presence of at least 30% by volume of nitrogen and/or methane based on the total volume of hydrocarbon feed plus diluent. Preferably 65-80% of nitrogen or methane is used. Suitable catalysts are the oxides of Group VI metals which may be supported on a Group III metal oxide and activated with oxides of alkali metals and/or alkaline earth metals and/or rare earth metals and/or zinc. They may also be mixed with metallic platinum or palladium or in the form of mixed compounds or mixed with oxides of titanium, zirconium, thorium or vanadium. Preferred catalysts contain 5-40% chromia, 1-10% potassia, 0,5-5% ceria and 93,5-45% gamma-alumina. Water vapour is undesirable and should be kept below 0,5% by volume of the reactants. Specifications 777,732 and 795,235 are referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE198742X | 1956-05-16 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB846574A true GB846574A (en) | 1960-08-31 |
Family
ID=5757150
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1564657A Expired GB846574A (en) | 1956-05-16 | 1957-05-16 | Process for the manufacture of para-xylene |
Country Status (3)
Country | Link |
---|---|
AT (1) | AT198742B (en) |
FR (1) | FR1175109A (en) |
GB (1) | GB846574A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005054160A1 (en) * | 2003-11-25 | 2005-06-16 | E. I. Du Pont De Nemours And Company | Process for the preparation of xylene |
-
1957
- 1957-05-14 FR FR1175109D patent/FR1175109A/en not_active Expired
- 1957-05-14 AT AT198742D patent/AT198742B/en active
- 1957-05-16 GB GB1564657A patent/GB846574A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005054160A1 (en) * | 2003-11-25 | 2005-06-16 | E. I. Du Pont De Nemours And Company | Process for the preparation of xylene |
Also Published As
Publication number | Publication date |
---|---|
AT198742B (en) | 1958-07-25 |
FR1175109A (en) | 1959-03-20 |
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