GB844310A - Plasticised vinyl chloride resins - Google Patents

Plasticised vinyl chloride resins

Info

Publication number
GB844310A
GB844310A GB35631/57A GB3563157A GB844310A GB 844310 A GB844310 A GB 844310A GB 35631/57 A GB35631/57 A GB 35631/57A GB 3563157 A GB3563157 A GB 3563157A GB 844310 A GB844310 A GB 844310A
Authority
GB
United Kingdom
Prior art keywords
acids
glutaric
acid
vinyl chloride
alcohol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB35631/57A
Inventor
Roxburgh Richmond Aitken
Lawrence Michael Dadson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Imperial Chemical Industries Ltd
Original Assignee
Imperial Chemical Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imperial Chemical Industries Ltd filed Critical Imperial Chemical Industries Ltd
Priority to GB35631/57A priority Critical patent/GB844310A/en
Publication of GB844310A publication Critical patent/GB844310A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/09Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Vinyl chloride resins are plasticized by use of neopentyl glycol-glutaric polyester. Up to 50% molar of the glutanric acid may be replaced by other dicarboxylic acids, preferably higher homologues of glutaric acid and up to 50% molar of the neopentyl glycol may be replaced by other dihydric glycols preferably p containing 5 or more carbon atoms. The plasticizer may be modified by inclusion of at least one (a) fatty oil acid, preferably lauric, palmitic or stearic acids or mixtures obtained by hydrolysis of animal and vegetable oils and fats (e.g. coconut oil), or (b) aliphatic monohydric C4-20, preferably C7-18 alcohol, such as n-butanol, 2-ethylhexanol, isooctanol, isodecanol, 3:5:5-trimethylhexanol, tridecyl alcohol or the mixture of alcohols of Specification 707,235. In the examples, polyvinyl chloride is plasticized, but also mentioned are interpolymers of vinyl chloride with a minor amount of, e.g. vinyl acetate, vinylidene chloride, styrene and the esters, nitrile and anides of acrylic, methacrylic, fumaric and maleic acids. Also specified are succinic and adipic acids (as the "other dicarboxylic acids"), calcium stearate and tetrabutyl titonate. The polyester plasticizer may be prepared, for example, by reaction of neopentyl alcohol with either glutaric acid or methyl glutaric.
GB35631/57A 1957-11-15 1957-11-15 Plasticised vinyl chloride resins Expired GB844310A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB35631/57A GB844310A (en) 1957-11-15 1957-11-15 Plasticised vinyl chloride resins

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB35631/57A GB844310A (en) 1957-11-15 1957-11-15 Plasticised vinyl chloride resins

Publications (1)

Publication Number Publication Date
GB844310A true GB844310A (en) 1960-08-10

Family

ID=10379864

Family Applications (1)

Application Number Title Priority Date Filing Date
GB35631/57A Expired GB844310A (en) 1957-11-15 1957-11-15 Plasticised vinyl chloride resins

Country Status (1)

Country Link
GB (1) GB844310A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3330789A (en) * 1963-06-06 1967-07-11 Emery Industries Inc Linear polymeric polyester vinyl resin plasticizers and plasticized compositions
EP0245665A2 (en) * 1986-05-15 1987-11-19 National Distillers And Chemical Corporation Improved copolyester plasticizers for polyvinyl chloride
EP0292599A1 (en) * 1987-05-29 1988-11-30 National Distillers And Chemical Corporation Improved copolyester plasticizers for polyvinyl chloride
US5247012A (en) * 1989-12-08 1993-09-21 The Geon Company Glutaric acid based polyester internally plasticized PVC

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3330789A (en) * 1963-06-06 1967-07-11 Emery Industries Inc Linear polymeric polyester vinyl resin plasticizers and plasticized compositions
EP0245665A2 (en) * 1986-05-15 1987-11-19 National Distillers And Chemical Corporation Improved copolyester plasticizers for polyvinyl chloride
EP0245665A3 (en) * 1986-05-15 1988-03-30 National Distillers And Chemical Corporation Improved copolyester plasticizers for polyvinyl chloride
EP0292599A1 (en) * 1987-05-29 1988-11-30 National Distillers And Chemical Corporation Improved copolyester plasticizers for polyvinyl chloride
US5247012A (en) * 1989-12-08 1993-09-21 The Geon Company Glutaric acid based polyester internally plasticized PVC
US5290852A (en) * 1989-12-08 1994-03-01 The Geon Company Glutaric acid based polyester internally plasticized PVC

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