GB843865A - Improvements in or relating to a water soluble aluminium complex astringent material - Google Patents
Improvements in or relating to a water soluble aluminium complex astringent materialInfo
- Publication number
- GB843865A GB843865A GB96658A GB96658A GB843865A GB 843865 A GB843865 A GB 843865A GB 96658 A GB96658 A GB 96658A GB 96658 A GB96658 A GB 96658A GB 843865 A GB843865 A GB 843865A
- Authority
- GB
- United Kingdom
- Prior art keywords
- sodium
- lactic
- acid
- complex
- radical
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0216—Solid or semisolid forms
- A61K8/0229—Sticks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/042—Gels
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/58—Metal complex; Coordination compounds
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
Abstract
The invention comprises water-soluble complexes having the following formula when isolated in the pH range of approximately 7-8: X2HAIR2,YH2O in which X is sodium or potassium, R is an acid radical of glycollic, gluconic, lactic or a -hydroxy-isobutyric acid, and Y is an integer having a value sufficient to provide the complex with an approximate molecular weight of 355 to 365 when using sodium as X and the lactic acid radical as R. They are prepared by slowly reacting 2 moles of glycollic, gluconic, lactic or a -hydroxy-isobutyric acid with one mole of a sodium or potassium aluminate complex in which the ingredients are present in the ratio of 1 gram atom of aluminium to 1-2 moles of sodium or potassium hydroxide and cooling the reaction mixture to a temperature below 40 DEG C. Preferably the reaction product is subsequently neutralised with an acid or an acid salt to decrease the pH of the reaction product to a value in the range of 6,0 to 8,0. The products have astringent and anti-perspirant properties and may be incorporated in astringent and antiperspirant compositions (see Group VI) and in soap gel sticks (see Group III).ALSO:Water-soluble complexes of formula XHAlR2.YH2O (X is sodium or potassium, R is an acid radical of glycollic, gluconic, lactic or a -hydroxy-isobutyric acid, and Y is an integer having a value sufficient to provide the complex with an approximate molecular weight of 355 to 365 when using sodium as X and the lactic radical as R) when isolated in the pH range of approximately 7-8 are used in soap gel sticks. The soap gel sticks are in general composed of the complex, soap, water and alcohol, the proportions of which vary throughout wide ranges. The soap may be the alkali metal salt of a saturated fatty acid such as myristic, stearic, palmitic, lauric, behenic and tridecylic acids. Ethyl and propyl alcohols are the preferred alcohols. In addition to the above ingredients there may also be incorporated in the sticks small amounts of perfume, colouring matter, deodorants, and moisture-retention agents.ALSO:Water-soluble complexes of the formula XHAlR2 YH2O (X is sodium or potassium, R is an acid radical of glycollic, gluconic, lactic or a -hydroxy isobutyric acid, and Y is an integer having a value sufficient to provide the complex with an approximate molecular weight of 355 to 365 when using sodium as X and the lactic radical as R), when isolated in the pH range of approximately 7-8, are used in antiperspirant and astringent compositions., They may be used in the form of aqueous or aqueous alcoholic solutions. In addition a perfume, an emulsifier for the perfume such as sorbitan monolaurate, monopalmitate and monostearate polyoxyethylene derivatives, and a thickner, such as glycerol monostearate, carboxymethylcellulose or a gum, may be present. The complexes may also be incorporated into cream bases which include an oil phase which may be a synthetic or natural oil, and an emulsifier which may be the partial ester of fatty acids with glycerin, glycol or other polyhydric alcohols and their polyoxyethylene ethers, and stabilisers such as the sodium salts of sulphated monoglycerides of cocoanut oil fatty acids, sodium alkyl sulphates and salts of alkyl aromatic sulphonates.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB96658A GB843865A (en) | 1958-01-10 | 1958-01-10 | Improvements in or relating to a water soluble aluminium complex astringent material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB96658A GB843865A (en) | 1958-01-10 | 1958-01-10 | Improvements in or relating to a water soluble aluminium complex astringent material |
Publications (1)
Publication Number | Publication Date |
---|---|
GB843865A true GB843865A (en) | 1960-08-10 |
Family
ID=9713656
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB96658A Expired GB843865A (en) | 1958-01-10 | 1958-01-10 | Improvements in or relating to a water soluble aluminium complex astringent material |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB843865A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4265878A (en) * | 1979-06-07 | 1981-05-05 | Dow Corning Corporation | Antiperspirant stick compositions |
US9731999B2 (en) | 2011-09-23 | 2017-08-15 | Iqbal Gill | Chemical admixtures for hydraulic cements |
-
1958
- 1958-01-10 GB GB96658A patent/GB843865A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4265878A (en) * | 1979-06-07 | 1981-05-05 | Dow Corning Corporation | Antiperspirant stick compositions |
US9731999B2 (en) | 2011-09-23 | 2017-08-15 | Iqbal Gill | Chemical admixtures for hydraulic cements |
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