GB842802A - Water-soluble azo or anthraquinone dyestuffs containing methylol groups, a process for their production, and dyeings obtained therewith - Google Patents
Water-soluble azo or anthraquinone dyestuffs containing methylol groups, a process for their production, and dyeings obtained therewithInfo
- Publication number
- GB842802A GB842802A GB15751/58A GB1575158A GB842802A GB 842802 A GB842802 A GB 842802A GB 15751/58 A GB15751/58 A GB 15751/58A GB 1575158 A GB1575158 A GB 1575158A GB 842802 A GB842802 A GB 842802A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- ureido
- formaldehyde
- sulphonic acid
- naphthol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B43/00—Preparation of azo dyes from other azo compounds
- C09B43/006—Preparation of azo dyes from other azo compounds by introduction of hydrocarbon radicals on C-atom of azo dye
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Abstract
The invention comprises water-soluble dyes of formula: [D-]-(CH2OH)n wherein D is an azo or anthraquinone dyestuff radical having at least one water-solubilising group and in which hydrogen atoms susceptible to reaction with formaldehyde have been replaced by methylol groups, and n is 1 to 8. They are prepared by reacting a suitable dye or intermediate with formaldehyde in a medium of pH 6 to 11 and if necessary converting the intermediate to an azo or anthraquinone dye. Specified water-solubilising groups are carboxylic and sulphonic acid or acid amide, ureido or sulphone groups. The dyestuffs dye cellulose, wool, silk, leather and synthetic polyamide and polyurethane fibres, preferably in the presence of acids or acid salts, in red, brown, yellow and blue shades. In examples: (1) the following dyes are reacted with formaldehyde in alkaline medium:-3-aminophenol --> 2-amino-5-naphthol-7-sulphonic acid, 1-amino- 4-(41-ureido-orcarbonamido - phenyl)- aminoanthraquinone- 2-sulphonic acid, sulphanilic acid --> 2-ureido-5-naphthol-7-sulphonic acid or 1-ureido-8-naphthol- 3 : 6 -disulphonic acid and sulphanilamide --> 2-ureido -5- naphthol -7- sulphonic acid; (2) the product obtained by reacting phenol with aqueous formaldehyde is coupled with the diazo compound from 1-amino -3 : 4- dichlorobenzene-5- sulphonic acid or anthranilic acid; (3) as in (2) the reaction product of formaldehyde and 3-hydroxyphenylurea is coupled with diazotised sulphanilamide; (4) the dyes sulphanilamide or 4-aminophenylurea --> 2 : 4-dimethylol-phenol are prepared.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE842802X | 1957-05-18 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB842802A true GB842802A (en) | 1960-07-27 |
Family
ID=6770994
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB15751/58A Expired GB842802A (en) | 1957-05-18 | 1958-05-16 | Water-soluble azo or anthraquinone dyestuffs containing methylol groups, a process for their production, and dyeings obtained therewith |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB842802A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3195973A (en) * | 1960-04-02 | 1965-07-20 | Hoechst Ag | N-methylolated diamino-dihydroxyanthraquinones, mixtures thereof and their production |
US3248379A (en) * | 1962-11-21 | 1966-04-26 | Gen Aniline & Film Corp | Fiber reactive dyestuffs and process for their preparation |
US3617190A (en) * | 1965-11-16 | 1971-11-02 | Stevens & Co Inc J P | Methylolated sulfonamides and crosslinking of polymers therewith |
US3617192A (en) * | 1965-11-22 | 1971-11-02 | Cotton Producers Inst | Crosslinking of cellulosic materials with products produced by the reaction of alkyl sulfonamides and formaldehyde under alkaline conditions |
-
1958
- 1958-05-16 GB GB15751/58A patent/GB842802A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3195973A (en) * | 1960-04-02 | 1965-07-20 | Hoechst Ag | N-methylolated diamino-dihydroxyanthraquinones, mixtures thereof and their production |
US3248379A (en) * | 1962-11-21 | 1966-04-26 | Gen Aniline & Film Corp | Fiber reactive dyestuffs and process for their preparation |
US3617190A (en) * | 1965-11-16 | 1971-11-02 | Stevens & Co Inc J P | Methylolated sulfonamides and crosslinking of polymers therewith |
US3617192A (en) * | 1965-11-22 | 1971-11-02 | Cotton Producers Inst | Crosslinking of cellulosic materials with products produced by the reaction of alkyl sulfonamides and formaldehyde under alkaline conditions |
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