GB840325A - Resinous products - Google Patents

Resinous products

Info

Publication number
GB840325A
GB840325A GB2097/57A GB209757A GB840325A GB 840325 A GB840325 A GB 840325A GB 2097/57 A GB2097/57 A GB 2097/57A GB 209757 A GB209757 A GB 209757A GB 840325 A GB840325 A GB 840325A
Authority
GB
United Kingdom
Prior art keywords
acrylamide
interpolymer
specified
solution
vinyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2097/57A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
PPG Industries Inc
Original Assignee
Pittsburgh Plate Glass Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pittsburgh Plate Glass Co filed Critical Pittsburgh Plate Glass Co
Priority claimed from US665109A external-priority patent/US2978437A/en
Publication of GB840325A publication Critical patent/GB840325A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D157/00—Coating compositions based on unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D157/06—Homopolymers or copolymers containing elements other than carbon and hydrogen
    • C09D157/12—Homopolymers or copolymers containing elements other than carbon and hydrogen containing nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/52—Amides or imides
    • C08F20/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
    • C08F20/58—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing oxygen in addition to the carbonamido oxygen, e.g. N-methylolacrylamide, N-acryloylmorpholine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/62—Monocarboxylic acids having ten or more carbon atoms; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Paints Or Removers (AREA)
  • Phenolic Resins Or Amino Resins (AREA)
  • Epoxy Resins (AREA)

Abstract

A heat-hardenable resinous material comprises an interpolymer of an acrylamide and at least two other ethylenically-unsaturated monomers, one of which is an ethylenically-unsaturated acid, the p interpolymer having amido hydrogen atoms replaced by the structure -ROR1, wherein R is a saturated lower aliphatic hydrocarbon radical and R1 is hydrogen or a lower alkyl radical. Amides specified are acrylamide, methacrylamide and itaconic diamide. Acids specified are acrylic, methacrylic, crotonic, maleic, fumaric and itaconic acids. Other monomers specified are methyl, ethyl, butyl, isobutyl, hexyl and octyl acrylates, glycidyl acrylate, durenediol and dimethylbenzyl methacrylates, styrene, vinyl toluene, dibutyl maleate, maleic anhydride, allyl acetoacetate, vinyl pyridines, vinyl ketones and vinyl ethers. The resinous material may be obtained by condensing the acrylamide interpolymer with a lower aliphatic aldehyde; alternatively the acrylamide may first be reacted with the aldehyde and then copolymerized with the other monomers. Aldehydes specified are formaldehyde, trioxymethylene, hexamethylene tetramine, acetaldehyde and butyraldehyde. If the reaction with the aldehyde is carried out in the presence of an alkanol etherification of the alkylol groups results. The resinous materials are useful in coating applications for which purpose they may compound with additional materials; in the example an acrylamide/styrene/ethyl acrylate/ acrylic acid interpolymer is reacted with a butanol solution of formaldehyde and then formulated into a coating composition by admixture with titanium dioxide, a solution of an epoxy resin in a mixture of methyl isobutyl ketone and xylol, pine oil, "Cellosolve" (Registered Trade Mark) acetate and a silicone solution. The Specification gives details of the preparation of the acrylamide polymers with the aid of specified solvents, catalysts and modifiers. Specification 826,652 is referred to.ALSO:Primed and unprimed steel panels are coated by spraying with an enamel comprising a formaldehyde modified styrene/ethyl acrylate/acrylamide/acrylic acid interpolymer, a solution of an epoxy resin, titanium dioxide "Cellosolve" (Registered Trade Mark) acetate, pine oil and a silicone solution, followed by the curing of the resulting coatings by heating at 300 DEG F. Specification 826,652 is referred to.
GB2097/57A 1956-01-31 1957-01-21 Resinous products Expired GB840325A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US840325XA 1956-01-31 1956-01-31
US665109A US2978437A (en) 1957-06-12 1957-06-12 Water-insoluble condensation products of aldehydes and acrylamide interpolymers

Publications (1)

Publication Number Publication Date
GB840325A true GB840325A (en) 1960-07-06

Family

ID=26770542

Family Applications (2)

Application Number Title Priority Date Filing Date
GB2097/57A Expired GB840325A (en) 1956-01-31 1957-01-21 Resinous products
GB18639/58A Expired GB883229A (en) 1956-01-31 1958-06-11 Resinous products

Family Applications After (1)

Application Number Title Priority Date Filing Date
GB18639/58A Expired GB883229A (en) 1956-01-31 1958-06-11 Resinous products

Country Status (3)

Country Link
DE (2) DE1083548B (en)
FR (1) FR1172128A (en)
GB (2) GB840325A (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1191925B (en) * 1962-02-15 1965-04-29 Basf Ag Coating agent for the production of heat-hardenable coatings from polymerisation products
DK412776A (en) * 1975-09-18 1977-03-19 Cassella Farbwerke Mainkur Ag COLD WATER SOLUBLE STATIC COPOLYMERISATES, THEIR PREPARATION AND USE
EP1545875B1 (en) 2002-08-15 2012-10-03 Valspar Sourcing, Inc. Durable polyester coating

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE654989C (en) * 1930-05-06 1938-01-06 Ig Farbenindustrie Ag Process for the preparation of polymerization products

Also Published As

Publication number Publication date
DE1089549B (en) 1960-09-22
GB883229A (en) 1961-11-29
FR1172128A (en) 1959-02-05
DE1083548B (en) 1960-06-15

Similar Documents

Publication Publication Date Title
US2870117A (en) Coating composition comprising an epoxy resin and an aldehyde-reacted polymer of acrylamide and metallic surface coated therewith
US2978437B1 (en) Reexamination certificate
US3341497A (en) Organic solvent soluble perfluorocarbon copolymers
US2980652A (en) Unsaturated derivatives of n-(omega-aminoalkyl)-1, 3-cyclodiazolidin-2-ones and copolymers thereof
GB1330661A (en) Pulverisable acrylate resins
GB1237903A (en)
GB1107321A (en) Acrylic coating compositions
GB1128450A (en) Aqueous compositions comprising carboxy-containing copolymers
US3369008A (en) N-(cyclic ureidoalkyl) crotonamides and polymers thereof
GB942454A (en) Surface-coating compositions
GB991878A (en) Hard and flexible stoving enamels
ES306998A1 (en) Methylolated urea and melamine etherified with butanol and polyethyleneglycol as emulsion polymerization agents
US2940943A (en) Resinous coating composition comprising nitrocellulose and aldehyde modified amide polymer and metallic surface coated therewith
US3896073A (en) Aqueous dispersions of film-forming
GB840325A (en) Resinous products
GB1065031A (en) Heat-curable thermosetting compositions
GB989470A (en) Production of alkylolated acrylamide-containing interpolymers and etherified derivatives thereof
US3011993A (en) Blends of aldehyde-substituted amide interpolymers with polyethylene and methods of blending the same
GB890149A (en) Soft, non-woven fibrous product and process for preparing the same
GB973528A (en) Resinous compositions
GB1012798A (en) N-substituted acetamide compounds
US3347836A (en) Thermosetting methylolated acrylic polymer
US3178394A (en) Composition comprising acrylamide-styrene-formaldehyde reaction product with an organic diisocyanate
US3298978A (en) Interpolymers of aldehyde modified amides and polyallyl ethers of polyhydric alcohols
GB977820A (en) Coating composition