GB820654A - Improvements in and relating to the coating of refractory metal compound composites - Google Patents
Improvements in and relating to the coating of refractory metal compound compositesInfo
- Publication number
- GB820654A GB820654A GB1457/56A GB145756A GB820654A GB 820654 A GB820654 A GB 820654A GB 1457/56 A GB1457/56 A GB 1457/56A GB 145756 A GB145756 A GB 145756A GB 820654 A GB820654 A GB 820654A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alloy
- base
- melting point
- coating
- inch
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011248 coating agent Substances 0.000 title abstract 7
- 238000000576 coating method Methods 0.000 title abstract 7
- 239000002131 composite material Substances 0.000 title abstract 2
- 150000002736 metal compounds Chemical class 0.000 title 1
- 239000003870 refractory metal Substances 0.000 title 1
- 238000002844 melting Methods 0.000 abstract 11
- 230000008018 melting Effects 0.000 abstract 11
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 10
- 229910052804 chromium Inorganic materials 0.000 abstract 9
- 229910045601 alloy Inorganic materials 0.000 abstract 8
- 239000000956 alloy Substances 0.000 abstract 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 8
- 229910052742 iron Inorganic materials 0.000 abstract 6
- 229910052759 nickel Inorganic materials 0.000 abstract 6
- 239000002184 metal Substances 0.000 abstract 5
- 229910052751 metal Inorganic materials 0.000 abstract 5
- 239000000463 material Substances 0.000 abstract 4
- 229910052750 molybdenum Inorganic materials 0.000 abstract 4
- 229910052721 tungsten Inorganic materials 0.000 abstract 4
- 229910052799 carbon Inorganic materials 0.000 abstract 3
- 238000010438 heat treatment Methods 0.000 abstract 3
- 229910052710 silicon Inorganic materials 0.000 abstract 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 abstract 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- 229910018487 Ni—Cr Inorganic materials 0.000 abstract 2
- 239000011230 binding agent Substances 0.000 abstract 2
- 238000005422 blasting Methods 0.000 abstract 2
- 238000009750 centrifugal casting Methods 0.000 abstract 2
- 230000006698 induction Effects 0.000 abstract 2
- 229910052749 magnesium Inorganic materials 0.000 abstract 2
- 229910052748 manganese Inorganic materials 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 229910000599 Cr alloy Inorganic materials 0.000 abstract 1
- 229910000990 Ni alloy Inorganic materials 0.000 abstract 1
- 238000005275 alloying Methods 0.000 abstract 1
- 229910052786 argon Inorganic materials 0.000 abstract 1
- 239000007767 bonding agent Substances 0.000 abstract 1
- -1 borides Chemical class 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 229910017052 cobalt Inorganic materials 0.000 abstract 1
- 239000010941 cobalt Substances 0.000 abstract 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 238000005238 degreasing Methods 0.000 abstract 1
- 238000009792 diffusion process Methods 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 229910052734 helium Inorganic materials 0.000 abstract 1
- 239000001307 helium Substances 0.000 abstract 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 230000003993 interaction Effects 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000011159 matrix material Substances 0.000 abstract 1
- 239000000155 melt Substances 0.000 abstract 1
- 150000001247 metal acetylides Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 150000004767 nitrides Chemical class 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 229940098458 powder spray Drugs 0.000 abstract 1
- 238000003825 pressing Methods 0.000 abstract 1
- 230000001737 promoting effect Effects 0.000 abstract 1
- 230000001681 protective effect Effects 0.000 abstract 1
- 229910021332 silicide Inorganic materials 0.000 abstract 1
- 239000007921 spray Substances 0.000 abstract 1
- 238000005507 spraying Methods 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F7/00—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression
- B22F7/06—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite workpieces or articles from parts, e.g. to form tipped tools
- B22F7/08—Manufacture of composite layers, workpieces, or articles, comprising metallic powder, by sintering the powder, with or without compacting wherein at least one part is obtained by sintering or compression of composite workpieces or articles from parts, e.g. to form tipped tools with one or more parts not made from powder
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Composite Materials (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Turbine Rotor Nozzle Sealing (AREA)
- Coating By Spraying Or Casting (AREA)
Abstract
In a method of producing cladded thermal elements, e.g turbine blades, by coating with a ductile heat resistant metal a composite base comprising refractory grains of the carbides, borides, nitrides or silicides of Ti, Zr, Cr, Mo, W, V, Cb, or Ta or mixtures thereof in a matrix of heat resistant binder metal, containing a low melting phase based on the interaction of the binder metal and refractory grains, the heating which effects bonding is carried out so that at least one of the materials is maintained at a solidus temperature approaching within 100 DEG C. of its lowest melting point in the presence of a liquid bonding phase, for no longer than 120 minutes, to inhibit excessive diffusion of embrittling agents into the coating. Either the low melting phase of the base may be utilized as the bonding agent, the temperature used being 100 DEG C. or more below the melting point of the coating material; or the base may be maintained at a temperature no nearer than within 100 DEG C. of the melting point of its lowest melting phase, the coating material being up to 250 DEG C. above its melting point. Again a bond promoting pre-coat alloy generally similarly in composition to the principal coating and which melts at the temperature employed, may be utilized. The thickness of any such intermediate layer should not exceed one quarter that of the principal coat. A protective atmosphere such as hydrogen, nitrogen, helium, argon; or a sub-atmospheric pressure, may be provided. The Specification describes the application of the coating metal by spraying, centrifugal casting, and the lightly pressing on of a thin sheet. In Example 1 a body of TiC grains bonded with a high temperature resistant Ni alloy after grit blasting and degreasing is pre-coated using a powder spray torch with approximately 0.002 inch of a low melting point alloy containing 3 to 5% B, up to 1% C, 1 to 3.5% Si, less than 5% total of Fe, Mn and Mg, the balance being Ni-Cr in the ratio 4 parts Ni to 1 part Cr. It is bonded by electric induction heating in a vacuum furnace at 1050 DEG -1100 DEG for fifteen minutes. After cooling and grit blasting the specimen is spray coated with about 0.01 inch of alloy comprising more than 95% Ni-Cr (4 parts Ni to 1 part Cr) and the balance Fe, Mg, C, Si, its melting point being of the order 1400 DEG C. The whole is re-heated in the induction vacuum furnace at 1100 DEG C. for 1 hour. Alternatively the preliminary heating to bond the pre-coat is omitted. In Example 3 a similar base material and a 0.01 inch sheet of a Ni-base alloy comprising 14% Cr, 6% Fe and balance Ni with a melting point of 1395 DEG C. were cleaned and degreased. The sheet was placed around the carbide body, the assembly put in a mould internally simulating a turbine nozzle vane, the halves of the mould were held together by a weight exerting about 1 lb. per sq. inch, and the whole heated in a vacuum furnace at 1290 DEG C. for 1 hour. In Example 4 a TiC skeleton infiltrated with an 80% Ni, 20% Cr alloy was coated by centrifugal casting with an alloy comprising 52% Co, 27% Cr, 12% Ni and 9% W which was melted and heated at 1400 DEG C. The infiltrated body was maintained for about half a minute between 1000 DEG to 1100 DEG C., i.e. more than 100 DEG C. below the lowest melting phase which is in the neighbourhood of 1200 DEG C. Other alloys instanced as applicable are Nickel base with (a) 13 to 15% Cr, 6 to 7% Fe; (b) 13 to 16% Cr, 15 to 19% Mo, 3.5 to 5.5% W, 4 to 7% Fe; (c) 4 to 6% Al; Cobalt base with (a) 25% Cr, 6% Mo; (b) 26% Cr, 10% Ni, 7.5% W; Iron base with (a) 16 to 20% Cr, 6 to 10% Ni; (b) 25% Ni, 16% Cr, 6% Mo. Precoat alloys may comprise an iron group metal with at least one of Mg up to 20%, B to 5%, P to 12%, Si to 4%, Mn to 2%, C to 2%, the total of these alloying ingredients not exceeding about 20% of the alloy.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US820654XA | 1955-01-28 | 1955-01-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB820654A true GB820654A (en) | 1959-09-23 |
Family
ID=22168823
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1457/56A Expired GB820654A (en) | 1955-01-28 | 1956-01-16 | Improvements in and relating to the coating of refractory metal compound composites |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB820654A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4608318A (en) * | 1981-04-27 | 1986-08-26 | Kennametal Inc. | Casting having wear resistant compacts and method of manufacture |
-
1956
- 1956-01-16 GB GB1457/56A patent/GB820654A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4608318A (en) * | 1981-04-27 | 1986-08-26 | Kennametal Inc. | Casting having wear resistant compacts and method of manufacture |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3542530A (en) | Nickel or cobalt base with a coating containing iron chromium and aluminum | |
US5359770A (en) | Method for bonding abrasive blade tips to the tip of a gas turbine blade | |
US4313760A (en) | Superalloy coating composition | |
US2994124A (en) | Clad cermet body | |
CA1148036A (en) | Corrosion resistant coatings for metal articles | |
US6302318B1 (en) | Method of providing wear-resistant coatings, and related articles | |
US3313633A (en) | High temperature flame spray powder | |
US20170233852A1 (en) | Wear resistant and corrosion resistant cobalt-based alloy powders and applications thereof | |
JPH01119657A (en) | Frame spray coated hard alloy product | |
CA2286257A1 (en) | Cobalt-base composition and method for diffusion braze repair of superalloy articles | |
US3378392A (en) | High temperature flame spray powder and process | |
EP0511318B1 (en) | Plasma spraying of rapidly solidified aluminum base alloys | |
US4615864A (en) | Superalloy coating composition with oxidation and/or sulfidation resistance | |
KR20020019448A (en) | Bond coats for turbine components and method of applying the same | |
CA1202768A (en) | Method for forming braze-bonded abrasive turbine blade tip | |
KR970069231A (en) | Nickel Brazing Material | |
JPS6054389B2 (en) | Ferrous metal substrate with alloy coating | |
US3672849A (en) | Cermet-type alloy coating on metal base | |
CN109351957A (en) | Laser melting coating iron(-)base powder and preparation method thereof | |
CA1096660A (en) | Wear and corrosion resistant nickel-base alloy | |
US3573963A (en) | Method of coating nickel base alloys with a mixture of tungsten and aluminum powders | |
US4906529A (en) | Method of producing an erosion-resistant surface/layer on a metallic workpiece | |
CN107716933B (en) | A kind of interface purification method of the wear-resisting antioxidant coating of single crystal super alloy | |
US2899338A (en) | Thermal element | |
JP2988281B2 (en) | Ceramic / metal composite powder for thermal spraying and method for forming thermal spray coating |