GB809658A - Polymerisable compositions - Google Patents
Polymerisable compositionsInfo
- Publication number
- GB809658A GB809658A GB287/56A GB28756A GB809658A GB 809658 A GB809658 A GB 809658A GB 287/56 A GB287/56 A GB 287/56A GB 28756 A GB28756 A GB 28756A GB 809658 A GB809658 A GB 809658A
- Authority
- GB
- United Kingdom
- Prior art keywords
- epoxypropyl
- tri
- dimethylaminomethyl
- acid
- phenyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
- C09D133/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
A polymerizable composition comprises a copolymer of methyl methacrylate with a minor amount of a polymerizable carboxylic acid, a polyepoxy compound, a basic organic catalyst, a solvent and a polymeric plasticizer. The polymerizable carboxylic acid may be methacrylic, acrylic, crotonic, fumaric, maleic or itaconic acid; in place of the acid, an anhydride such as maleic anhydride may be used and other components such as acrylates and methacrylates may be present in the copolymer in minor amount. The polyepoxy compound may be 1 : 2-3 : 4 - diepoxybutane, 1 : 2-5 : 6 - diepoxy - 2 : 5 - dimethylhexane, methyl di(2 : 3 - epoxypropyl) acetate, 1 : 4 - divinylbenzene diepoxide, di - (2 : 3 - epoxy propyl) ether, glycerol tri - (2 : 3 - epoxypropyl) ether, m - or p - di - (2 : 3 - epoxypropyl) - benzene, 1 : 3 : 5 - tri (2 : 3 - epoxy propoxy) - benzene, 2 : 2 - di - [4 - (2 : 3 - epoxypropoxy) phenyl] propane, N : N - di - (2 : 3 - epoxypropyl) - aniline, N : N - di - (2 : 3 - epoxypropyl) p - anisidine, (2 : 3-epoxy) sorbate dimer, di-(2 : 3 epoxypropyl) sebacate, itaconate, or isophthalate, tri-(2 : 3-epoxypropyl trimesate or N : N-di - (2 : 3 - epoxypropyl) p - t p - toluene sulphonamide. Other polyepoxides which may be used are polymers obtained by reacting polyhydric phenols with epichlorhydrin or glycerol dichlorhydrins in presence of alkali. Mixtures of polyepoxides with monoepoxides such as phenyl 2 : 3-epoxypropyl ether and 2 : 3-epoxypropylN-phenylcarbamate may also be used. The catalyst may be 2 : 4 : 6-tri (dimethylaminomethyl) phenol, triethylamine, dimethylaniline, pyridine, N : N - dimethyl - 1 : 3 - propanediamine, diethylenetriamine, 2 : 5 - di (dimethylaminomethyl) - quinol, N : N - dimethyl - cyclohexylamine, N : N - dimethylbenzylamine, N : N : N1 : N1 - tetramethylhexamethylene diamine, 2 - (dimethylaminomethyl) cyclohexanone, phenyl - 2 - (dimethylamino) ethyl ketone, di - [2 - (diethylamino) ethyl] adipate, N - ethylhexamethyleneimine, hexamethyleneimine, N - methylbenzylamine, benzyltrimethylammonium hydroxide, or a substance which breaks down on heating to give amines such as benzyltrimethylammonium acetate or the triacetate from 2 : 4 : 6-tri-(dimethylaminomethyl) phenol. The solvent may be xylene, butanol, toluene, methyl ethyl ketone, ethyl acetate or mixtures thereof. The polymeric plasticizer is preferably a liquid mixed polyester formed by the condensation of a glycol, an aliphatic dicarboxylic acid and an aromatic monocarboxylic acid, and optionally also an aliphatic monocarboxylic acid, or mixtures thereof, as described in Specification 775,764. The composition may also contain pigments such as titanium dioxide and iron oxides. The compositions may be used to coat light alloy, steel or wood surfaces by spraying or brushing, polymerization being then effected by stoving, generally at 60-120 DEG C.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB17019/57A GB846485A (en) | 1957-05-29 | 1957-05-29 | Improvements in or relating to polymerisable compositions |
Publications (1)
Publication Number | Publication Date |
---|---|
GB809658A true GB809658A (en) | 1959-02-25 |
Family
ID=10087758
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB287/56A Expired GB809658A (en) | 1957-05-29 | 1956-01-04 | Polymerisable compositions |
GB17019/57A Expired GB846485A (en) | 1957-05-29 | 1957-05-29 | Improvements in or relating to polymerisable compositions |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB17019/57A Expired GB846485A (en) | 1957-05-29 | 1957-05-29 | Improvements in or relating to polymerisable compositions |
Country Status (3)
Country | Link |
---|---|
BE (1) | BE557752A (en) |
GB (2) | GB809658A (en) |
NL (2) | NL105262C (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2635177B1 (en) * | 1976-08-05 | 1978-02-16 | Basf Ag | LOW-SOLVENT STOVE ENAMELS |
US4786675A (en) * | 1984-12-21 | 1988-11-22 | Nippon Zeon Co., Ltd. | Sealed semiconductor containing an epoxy resin composition |
WO2007072141A2 (en) * | 2005-12-23 | 2007-06-28 | Eureka Projekt Società A Responsabilità Limitata Per I Servizi | Composition and method for manufacturing a product |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE588068A (en) * | 1959-02-26 |
-
0
- NL NL216185D patent/NL216185A/xx unknown
- BE BE557752D patent/BE557752A/xx unknown
- NL NL105262D patent/NL105262C/xx active
-
1956
- 1956-01-04 GB GB287/56A patent/GB809658A/en not_active Expired
-
1957
- 1957-05-29 GB GB17019/57A patent/GB846485A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2635177B1 (en) * | 1976-08-05 | 1978-02-16 | Basf Ag | LOW-SOLVENT STOVE ENAMELS |
US4786675A (en) * | 1984-12-21 | 1988-11-22 | Nippon Zeon Co., Ltd. | Sealed semiconductor containing an epoxy resin composition |
WO2007072141A2 (en) * | 2005-12-23 | 2007-06-28 | Eureka Projekt Società A Responsabilità Limitata Per I Servizi | Composition and method for manufacturing a product |
WO2007072141A3 (en) * | 2005-12-23 | 2007-11-29 | Keiper Holding S R L | Composition and method for manufacturing a product |
Also Published As
Publication number | Publication date |
---|---|
GB846485A (en) | 1960-08-31 |
NL105262C (en) | |
BE557752A (en) | |
NL216185A (en) |
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