GB793070A - Improved hydrocarbon resin - Google Patents

Improved hydrocarbon resin

Info

Publication number
GB793070A
GB793070A GB31611/55A GB3161155A GB793070A GB 793070 A GB793070 A GB 793070A GB 31611/55 A GB31611/55 A GB 31611/55A GB 3161155 A GB3161155 A GB 3161155A GB 793070 A GB793070 A GB 793070A
Authority
GB
United Kingdom
Prior art keywords
per cent
resin
maleic anhydride
reaction
effected
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB31611/55A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Esso Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co, Esso Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of GB793070A publication Critical patent/GB793070A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/52Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
    • C08G63/54Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/553Acids or hydroxy compounds containing cycloaliphatic rings, e.g. Diels-Alder adducts
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F240/00Copolymers of hydrocarbons and mineral oils, e.g. petroleum resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The softening-point of a resin prepared by Friedel-Crafts polymerization of a steamcracked petroleum fraction containing 10 to 35 per cent diolefins, 30 to 65 per cent olefins and 0 to 60 per cent aromatics, paraffins and naphthenes, e.g. a gas oil fraction, is raised by reaction with maleic anhydride followed by cross-linking at a temperature of 125 DEG to 250 DEG C. with a polyhydric alcohol, an amino alcohol, an aminophenol, a hydrazine or a thioglycol. Specified compounds are ethylene and propylene glycols, glycerine, 2-(hydroxymethyl) propanediol - 1,3; ethanolamine, triethanolamine; diamide, methyl and ethyl hydrazines; monothioglycol and thiodiglycol. Oxygen is preferably excluded. The original resin, which is a non-aromatic unsaturated hydrocarbon resin, may be produced using catalysts such as aluminium chloride or bromide, boron trifluoride and solutions, slurries or complexes thereof, residual catalyst being quenched and purification effected by addition of methyl alcohol, water or caustic alkali, followed by vacuum and/or steam distillation. The reaction with maleic anhydride is effected at a temperature above 130 DEG C., optionally using a catalyst such as t.-butyl hydroperoxide or di-t-butyl peroxide. The products, which are suitable for use in floor tiles, may be subjected to oxidation, polymerization, esterification, and acetal and ketal formation.
GB31611/55A 1954-12-16 1955-11-04 Improved hydrocarbon resin Expired GB793070A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US793070XA 1954-12-16 1954-12-16

Publications (1)

Publication Number Publication Date
GB793070A true GB793070A (en) 1958-04-09

Family

ID=22149694

Family Applications (1)

Application Number Title Priority Date Filing Date
GB31611/55A Expired GB793070A (en) 1954-12-16 1955-11-04 Improved hydrocarbon resin

Country Status (2)

Country Link
DE (1) DE1053784B (en)
GB (1) GB793070A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3381022A (en) * 1963-04-23 1968-04-30 Lubrizol Corp Polymerized olefin substituted succinic acid esters
US3535290A (en) * 1968-01-12 1970-10-20 Gulf Research Development Co Process for preparing polymeric anhydrides
US5665842A (en) * 1993-12-21 1997-09-09 Mbt Holding Ag Organic compounds

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5039451B2 (en) * 1972-06-08 1975-12-17

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE864151C (en) * 1944-05-28 1953-01-22 Bayer Ag Process for the production of hardened high molecular weight products
US2529322A (en) * 1947-08-20 1950-11-07 Standard Oil Dev Co Process of preparing synthetic drying oils
US2662874A (en) * 1950-11-01 1953-12-15 Goodrich Co B F Preparation of plastic condensable synthetic rubbers and subsequent elasto-condensation thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3381022A (en) * 1963-04-23 1968-04-30 Lubrizol Corp Polymerized olefin substituted succinic acid esters
US3535290A (en) * 1968-01-12 1970-10-20 Gulf Research Development Co Process for preparing polymeric anhydrides
US5665842A (en) * 1993-12-21 1997-09-09 Mbt Holding Ag Organic compounds
US5668195A (en) * 1993-12-21 1997-09-16 Mbt Holding Ag Fluidifying agents for cementitious compositions based random copolymers, compositions comprising the same, and methods for their use

Also Published As

Publication number Publication date
DE1053784B (en) 1959-03-26

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