GB781628A - Granular compositions and process for the preparation thereof - Google Patents
Granular compositions and process for the preparation thereofInfo
- Publication number
- GB781628A GB781628A GB1990155A GB1990155A GB781628A GB 781628 A GB781628 A GB 781628A GB 1990155 A GB1990155 A GB 1990155A GB 1990155 A GB1990155 A GB 1990155A GB 781628 A GB781628 A GB 781628A
- Authority
- GB
- United Kingdom
- Prior art keywords
- water
- sodium
- agents
- alkali
- condensates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title abstract 3
- -1 polyoxyethylene Polymers 0.000 abstract 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract 4
- 229910052783 alkali metal Inorganic materials 0.000 abstract 4
- 239000003599 detergent Substances 0.000 abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 4
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 235000014113 dietary fatty acids Nutrition 0.000 abstract 2
- 239000000194 fatty acid Substances 0.000 abstract 2
- 229930195729 fatty acid Natural products 0.000 abstract 2
- 150000004665 fatty acids Chemical class 0.000 abstract 2
- 239000006260 foam Substances 0.000 abstract 2
- 239000003979 granulating agent Substances 0.000 abstract 2
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract 2
- 235000017550 sodium carbonate Nutrition 0.000 abstract 2
- 235000019832 sodium triphosphate Nutrition 0.000 abstract 2
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 abstract 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 1
- 229910019142 PO4 Inorganic materials 0.000 abstract 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 abstract 1
- 239000004372 Polyvinyl alcohol Substances 0.000 abstract 1
- 239000004115 Sodium Silicate Substances 0.000 abstract 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 230000001476 alcoholic effect Effects 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 150000001346 alkyl aryl ethers Chemical class 0.000 abstract 1
- 150000001642 boronic acid derivatives Chemical class 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 230000001427 coherent effect Effects 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 abstract 1
- 239000000975 dye Substances 0.000 abstract 1
- 150000002191 fatty alcohols Chemical class 0.000 abstract 1
- 230000009969 flowable effect Effects 0.000 abstract 1
- 239000008187 granular material Substances 0.000 abstract 1
- 150000004677 hydrates Chemical class 0.000 abstract 1
- 230000036571 hydration Effects 0.000 abstract 1
- 238000006703 hydration reaction Methods 0.000 abstract 1
- 230000002209 hydrophobic effect Effects 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 239000003112 inhibitor Substances 0.000 abstract 1
- 229910017053 inorganic salt Inorganic materials 0.000 abstract 1
- HZRMTWQRDMYLNW-UHFFFAOYSA-N lithium metaborate Chemical compound [Li+].[O-]B=O HZRMTWQRDMYLNW-UHFFFAOYSA-N 0.000 abstract 1
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 abstract 1
- 229910001486 lithium perchlorate Inorganic materials 0.000 abstract 1
- 150000002894 organic compounds Chemical class 0.000 abstract 1
- 235000021317 phosphate Nutrition 0.000 abstract 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 abstract 1
- 239000000049 pigment Substances 0.000 abstract 1
- 229920001515 polyalkylene glycol Polymers 0.000 abstract 1
- 229920000223 polyglycerol Polymers 0.000 abstract 1
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical class [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 abstract 1
- 239000001120 potassium sulphate Substances 0.000 abstract 1
- 235000011151 potassium sulphates Nutrition 0.000 abstract 1
- 239000003352 sequestering agent Substances 0.000 abstract 1
- 229940071207 sesquicarbonate Drugs 0.000 abstract 1
- 229910052708 sodium Inorganic materials 0.000 abstract 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 abstract 1
- 229960001922 sodium perborate Drugs 0.000 abstract 1
- 229910000031 sodium sesquicarbonate Inorganic materials 0.000 abstract 1
- 235000018341 sodium sesquicarbonate Nutrition 0.000 abstract 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 1
- PMZURENOXWZQFD-UHFFFAOYSA-L sodium sulphate Substances [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 abstract 1
- 235000011152 sodium sulphate Nutrition 0.000 abstract 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000003784 tall oil Substances 0.000 abstract 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 abstract 1
- 150000003568 thioethers Chemical class 0.000 abstract 1
- TWQULNDIKKJZPH-UHFFFAOYSA-K trilithium;phosphate Chemical class [Li+].[Li+].[Li+].[O-]P([O-])([O-])=O TWQULNDIKKJZPH-UHFFFAOYSA-K 0.000 abstract 1
- WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 abstract 1
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 abstract 1
- 239000000080 wetting agent Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2/00—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/0082—Special methods for preparing compositions containing mixtures of detergents one or more of the detergent ingredients being in a liquefied state, e.g. slurry, paste or melt, and the process resulting in solid detergent particles such as granules, powders or beads
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Granular detergent compositions are produced by forming a flowable paste from (a) a granulating agent (which may be a non-ionic detergent) consisting of a polar organic compound having alcoholic hydroxyl as the only terminal polar radical and a molecular weight of about 150 or greater; (b) water; and (c) an alkali-metal inorganic salt in a hydratable form, present in a quantity sufficient to take up substantially all the water as water of hydration. The paste is mixed and aerated until semi-solid nodules have formed, and is then quiescently aged to produce a rigid friable mass of coherent, apparently dry, spheroidal agglomerate granules. Compounds suitable as granulating agents include the polyalkylene glycols and polyglycerols and their derivatives, such as their mono-alkyl ethers and thioethers, alkylphenol monoethers and monoesters of fatty acids, alkanolamides of fatty acids, fatty alcohols and polymeric alcohols such as polyvinyl alcohol. It is preferred to use the surface-active polyoxyethylene condensates from hydrophobic compounds containing at least about 8 carbon atoms, the condensates containing 6-30 ethenoxy groups per molecule, such as the alkyl phenol or tall oil condensates. Examples of the alkali metal salts to be used are sodium and potassium sulphates, sodium carbonate, sesquicarbonate and bicarbonate, lithium perchlorate, borates such as lithium metaborate and sodium perborate, and phosphates such as pentasodium tripolyphosphate, tetrasodium pyrophosphate, and mono-, di-and tri-sodium and lithium orthophosphates, all of which form stable hydrates at room temperature. It is preferred to use Type II pentasodium tripolyphosphate and soda ash in ratios of from 1:4 to 4:1. The ratio of alkali-metal salt to non-ionic detergent is usually between 35:1 to 2:1, and the ratio of alkali metal salt to water is generally between 8:1 and 2:1. The compositions may also contain 3-14 per cent of sodium silicate, and may also include anionic detergents. Such optional additives as dyes, pigments, foam or detergency improvers, sequestering agents, foam depressants, wetting agents, water-treating agents, bleaches, corrosion inhibitors or anti-redeposition agents may also be included.
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| BE540473D BE540473A (en) | 1955-07-08 | ||
| US454388A US2874123A (en) | 1954-09-07 | 1954-09-07 | Process for the preparation of granular compositions |
| CH345963D CH345963A (en) | 1955-07-08 | 1955-06-28 | Process for making a product formed from spherical grains |
| DEC11507A DE1016881B (en) | 1955-07-06 | 1955-07-06 | Process for the manufacture of a cleaning agent |
| GB1990155A GB781628A (en) | 1955-07-08 | 1955-07-08 | Granular compositions and process for the preparation thereof |
| FR1137472D FR1137472A (en) | 1955-07-08 | 1955-08-04 | Process for manufacturing granular compositions and products, in particular detersive products, obtained by implementing said process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1990155A GB781628A (en) | 1955-07-08 | 1955-07-08 | Granular compositions and process for the preparation thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB781628A true GB781628A (en) | 1957-08-21 |
Family
ID=10137036
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1990155A Expired GB781628A (en) | 1954-09-07 | 1955-07-08 | Granular compositions and process for the preparation thereof |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE540473A (en) |
| CH (1) | CH345963A (en) |
| FR (1) | FR1137472A (en) |
| GB (1) | GB781628A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2151207A5 (en) * | 1971-08-25 | 1973-04-13 | Colgate Palmolive Co |
-
0
- BE BE540473D patent/BE540473A/xx unknown
-
1955
- 1955-06-28 CH CH345963D patent/CH345963A/en unknown
- 1955-07-08 GB GB1990155A patent/GB781628A/en not_active Expired
- 1955-08-04 FR FR1137472D patent/FR1137472A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| CH345963A (en) | 1960-04-30 |
| BE540473A (en) | |
| FR1137472A (en) | 1957-05-29 |
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