GB779100A - Heterocyclic magnesium chloride complexes - Google Patents
Heterocyclic magnesium chloride complexesInfo
- Publication number
- GB779100A GB779100A GB6211/55A GB621155A GB779100A GB 779100 A GB779100 A GB 779100A GB 6211/55 A GB6211/55 A GB 6211/55A GB 621155 A GB621155 A GB 621155A GB 779100 A GB779100 A GB 779100A
- Authority
- GB
- United Kingdom
- Prior art keywords
- tetrahydrofuran
- heterocyclic
- quinolyl
- substituted
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- -1 Heterocyclic magnesium chloride complexes Chemical class 0.000 title abstract 13
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract 5
- 108010021119 Trichosanthin Proteins 0.000 abstract 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 2
- DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical group C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 abstract 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 abstract 2
- FGYBDASKYMSNCX-UHFFFAOYSA-N 2,5-dichlorothiophene Chemical compound ClC1=CC=C(Cl)S1 FGYBDASKYMSNCX-UHFFFAOYSA-N 0.000 abstract 1
- YSMYHWBQQONPRD-UHFFFAOYSA-N 2-chlorofuran Chemical compound ClC1=CC=CO1 YSMYHWBQQONPRD-UHFFFAOYSA-N 0.000 abstract 1
- JWUJQDFVADABEY-UHFFFAOYSA-N 2-methyltetrahydrofuran Chemical compound CC1CCCO1 JWUJQDFVADABEY-UHFFFAOYSA-N 0.000 abstract 1
- XJPZKYIHCLDXST-UHFFFAOYSA-N 4,6-dichloropyrimidine Chemical compound ClC1=CC(Cl)=NC=N1 XJPZKYIHCLDXST-UHFFFAOYSA-N 0.000 abstract 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 abstract 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 1
- 239000005864 Sulphur Substances 0.000 abstract 1
- WOXGSKHIWBTGPR-UHFFFAOYSA-M [Cl-].ClC=1C=C2N=C3C=CC(=CC3=C(C2=CC1)[Mg+])OC Chemical class [Cl-].ClC=1C=C2N=C3C=CC(=CC3=C(C2=CC1)[Mg+])OC WOXGSKHIWBTGPR-UHFFFAOYSA-M 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- RDHPKYGYEGBMSE-UHFFFAOYSA-N bromoethane Chemical compound CCBr RDHPKYGYEGBMSE-UHFFFAOYSA-N 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000013078 crystal Substances 0.000 abstract 1
- 229910052731 fluorine Inorganic materials 0.000 abstract 1
- 239000011737 fluorine Substances 0.000 abstract 1
- 125000000524 functional group Chemical group 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 229910052740 iodine Inorganic materials 0.000 abstract 1
- 239000011630 iodine Substances 0.000 abstract 1
- 239000011777 magnesium Substances 0.000 abstract 1
- 229910052749 magnesium Inorganic materials 0.000 abstract 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 1
- 229910052757 nitrogen Inorganic materials 0.000 abstract 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 150000003254 radicals Chemical class 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 abstract 1
- 125000001544 thienyl group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/02—Magnesium compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Plural Heterocyclic Compounds (AREA)
Abstract
The invention comprises heterocyclic magnesium chloride complexes of formula R(MgClnQ)a where Q is tetramethylene or pentamethylene oxide which may be substituted by substituted or unsubstituted alkyl radicals, a is an integer not exceeding 2, n is a small number from 1 to 3 and R is a heterocyclic radical containing at least one of the elements oxygen, sulphur or tertiary nitrogen in the ring and in which any or all of the hydrogen atoms of the ring structure of the radical may be replaced by chlorine, fluorine or substituted or unsubstituted alkyl, aryl, alkoxy or aryloxy radicals, the said substituents in the compound Q or the heterocyclic radical containing no functional group reactive under the conditions for forming the complex and, in the case of the compound Q, such that they do not block formation of the complex. Examples specified of Q are tetrahydrofuran, tetrahydropyran and 2-methyl-tetrahydrofuran: the compound Q may also form a solvent for the reaction. A large number of heterocyclic chlorides are specified. The reaction may be initiated by use of ethylbromide and an iodine crystal with or without addition of ether. The examples describe the preparation of tetrahydrofuran complexes of thienyl, a -pyridyl, 2-quinolyl, 6-quinolyl, 8-quinolyl, 2-benzoxazolyl, 2 - benzo - thiazolyl, 2 - methyl - benzothiazol-5-yl, 6 - chloro - 2 - methoxy - acrid - 9 - yl magnesium chlorides and also those produced by reacting magnesium with 4,6-dichloropyrimidine, 2 - chlorofuran, and 2,5-dichlorothiophene in the presence of tetrahydrofuran.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US779100XA | 1954-09-16 | 1954-09-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB779100A true GB779100A (en) | 1957-07-17 |
Family
ID=22140735
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB6211/55A Expired GB779100A (en) | 1954-09-16 | 1955-03-02 | Heterocyclic magnesium chloride complexes |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB779100A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2959589A (en) * | 1957-11-22 | 1960-11-08 | Metal & Thermit Corp | Heterocyclic magnesium chloridecyclic ether grignard reagents |
| US2959596A (en) * | 1957-11-22 | 1960-11-08 | Metal & Thermit Corp | Aryl chloride-cyclic ether grignard reagents |
| JPS52136162A (en) * | 1976-04-28 | 1977-11-14 | Kouichi Niihama | Preparation of 33methyll22*33methyll22 butenyl*furan |
-
1955
- 1955-03-02 GB GB6211/55A patent/GB779100A/en not_active Expired
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2959589A (en) * | 1957-11-22 | 1960-11-08 | Metal & Thermit Corp | Heterocyclic magnesium chloridecyclic ether grignard reagents |
| US2959596A (en) * | 1957-11-22 | 1960-11-08 | Metal & Thermit Corp | Aryl chloride-cyclic ether grignard reagents |
| JPS52136162A (en) * | 1976-04-28 | 1977-11-14 | Kouichi Niihama | Preparation of 33methyll22*33methyll22 butenyl*furan |
| JPS5439374B2 (en) * | 1976-04-28 | 1979-11-27 |
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