GB770310A - Compositions which contain surface-active components - Google Patents
Compositions which contain surface-active componentsInfo
- Publication number
- GB770310A GB770310A GB15592/54A GB1559254A GB770310A GB 770310 A GB770310 A GB 770310A GB 15592/54 A GB15592/54 A GB 15592/54A GB 1559254 A GB1559254 A GB 1559254A GB 770310 A GB770310 A GB 770310A
- Authority
- GB
- United Kingdom
- Prior art keywords
- carbon atoms
- sodium
- contain
- aromatic hydrocarbons
- sulphonates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
As surface-active components of compositions required to include such components, use is made of sulphonic acids or their salts derived from alkylated aromatic hydrocarbons of the formula ArC(R1)(R2)(R3), wherein Ar is an aryl radical and R1, R2 and R3 are alkyl radicals which contain a total of 8-17 carbon atoms and are such that two can be selected so that one contains not more than twice the number of carbon atoms in the other, the third containing at most the same number of carbon atoms as the larger of the other two. Suitably sulphonates are derived from alkylated aromatic hydrocarbons of the formula above in which Ar is a phenyl radical and R1, R2 and R3 contain 5,5 and 1, 6,6 and 1, 7,7 and 1, 4,4 and 4, 5,5 and 5, 8,6 and 1, 6,4 and 1 or 5,3 and 1 carbon atoms respectively, and experimental results are given in which the properties of these sulphonates are compared with those of sulphonated alkylbenzenes of similar structure but in which R1, R2 and R3 contain 6,6 and 6, 12,0 and 0, 10,1 and 0, or 9,1 and 1 carbon atoms respectively. Alkylated aromatic hydrocarbons of the formula above may be obtained by alkylating aromatic hydrocarbons (1) with dimerized olefines containing 6-8 carbon atoms in the molecule, the olefines being obtainable by cracking petroleum fractions, or (2) with olefines prepared by reacting a symmetrical or asymmetrical aliphatic ketone with a Grignard reagent to yield a tertiary alcohol, which is then dehydrated in known manner.ALSO:As surface-active components of compositions required to include such components, use is made of sulphonic acids or their salts derived from alkylated aromatic hydrocarbons of the formula ArC(R1)(R2)(R3, wherein Ar is an aryl radical and R1, R2 and R3 are alkyl radicals which contain a total of 8-17 carbon atoms and are such that two can be selected so that one contains not more than twice the number of carbon atoms in the other, the third containing at most the same number of carbon atoms as the larger of the other two. Suitable sulphonates are derived from alkylated aromatic hydrocarbons of the formula above in which Ar is a phenyl radical and R1, R2 and R3 contain 5, 5 and 1, 6, 6 and 1, 7, 7 and 1, 4, 4 and 4, 5, 5 and 5, 8, 6 and 1, 6, 4 and 1 or 5, 3 and 1 carbon atoms respectively and experimental results are given which the properties of these sulphonates are compared with those of sulphonated alkylbenzenes of similar structure but in which R1, R2 and R3 contain 6, 6 and 6, 12, 0 and 0, 10, 1 and 0 or 9, 1 and 1 carbon atoms respectively. Alkylated aromatic hydrocarbons of the formula above may be obtained by alkylating aromatic hydrocarbons (1) with dimerized olefines containing 6-8 carbon atoms in the molecule, the olefines being obtainable by cracking petroleum fractions, or (2) with olefines prepared by reacting a symmetrical or asymmetrical aliphatic ketone with a Grignard reagent to yield a tertiary alcohol, which is then dehydrated in known manner. The sulphonates may be used as dispersing, emulsifying, wetting or foaming agents or textile auxiliaries or as constituents of biocidal compositions, but they are particularly useful as components of detergent compositions, which compositions may also contain sodium sulphate, sodium carbonate, sodium phosphates, e.g. sodium pyrophosphate, tri- or tetrapolyphosphate or hexametaphosphates, sodium silicates, e.g. sodium metasilicate or alkaline or neutral sodium silicate, borax, cellulose or starch derivatives, e.g. sodium carboxymethyl cellulose, oxidizing bleaching agents, e.g. persulphates, perborates or percarbonates, optical bleaching agents, e.g. that sold under the Registered Trade Mark "Tinopal SP," urea, and other surface-active substances which may be anionic, cationic or non-ionic, e.g. other alkylaryl sulphonates or alkylphenol-ethylene oxide condensation products.ALSO:As surface-active components of detergent compositions use is made of sulphonic acids or their salts derived from alkylated aromatic hydrocarbons of the formula ArC(R1)(R2)(R3), wherein Ar is an aryl radical and R1, R2 and R3 are alkyl radicals which contain a total of 8-17 carbon atoms and are such that two can be selected so that one contains not more than twice the number of carbon atoms in the other, the third containing at most the same number of carbon atoms as the larger of the other two. Suitable sulphonates are derived from alkylated aromatic hydrocarbons of the formula above in which Ar is a phenyl radical and R1, R2 and R3 contain 5,5 and 1, 6,6 and 1, 7,7 and 1, 4,4 and 4, 5,5 and 5, 8,6 and 1, 6,4 and 1 or 5,3 and 1 carbon atoms respectively, and experimental results are given in which the properties of these sulphonates are compared with those of sulphonated alkylbenzenes of similar structure but in which R1, R2 and R3 contain 6, 6 and 6, 12,0 and 0, 10,1 and 0 or 9,1 and 1 carbon atoms respectively. The compositions may also contain sodium sulphate, sodium carbonate, sodium phosphates, e.g. sodium pyrophosphate, tri- or tetra-polyphosphate or hexametaphosphates, sodium silicates, e.g. sodium metasilicate or alkaline or neutral sodium silicate, borax, cellulose or starch derivatives, e.g. sodium carboxymethyl cellulose, oxidizing bleaching agents, e.g. persulphates, perborates or percarbonates, optical bleaching agents, e.g. that sold under the Registered Trade Mark "Tinopal SP" urea, and other surface-active substances which may be anionic, cationic or nonionic, e.g. other alkylaryl sulphonates or alkylphenol-ethylene oxide condensation products.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL178695A NL178695B (en) | 1953-05-29 | 1953-05-29 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB770310A true GB770310A (en) | 1957-03-20 |
Family
ID=46941010
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB15592/54A Expired GB770310A (en) | 1953-05-29 | 1954-05-26 | Compositions which contain surface-active components |
Country Status (6)
Country | Link |
---|---|
US (1) | US2796429A (en) |
BE (1) | BE529128A (en) |
CH (1) | CH330486A (en) |
FR (1) | FR1105032A (en) |
GB (1) | GB770310A (en) |
NL (1) | NL178695B (en) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2956025A (en) * | 1955-03-22 | 1960-10-11 | California Research Corp | Sulfonate detergent compositions with improved foam characteristics |
US2956026A (en) * | 1955-03-22 | 1960-10-11 | California Research Corp | Sulfonate detergent compositions |
US3093590A (en) * | 1956-08-08 | 1963-06-11 | Purex Corp Ltd | Trichlorocyanuric acid bleach with spray-dried base |
US2944028A (en) * | 1956-09-12 | 1960-07-05 | California Research Corp | Sulfonate detergent compositions |
BE616998A (en) * | 1960-09-23 | |||
US3298912A (en) * | 1963-10-02 | 1967-01-17 | Emery Industries Inc | Emulsifiable toxicant solution containing emulsifier of alkaryl sulfonic acid polyoxyalkylated polyamine salt |
US3425940A (en) * | 1966-06-30 | 1969-02-04 | Exxon Research Engineering Co | Non-staining liquid lubricant |
US6048904A (en) * | 1998-12-01 | 2000-04-11 | Exxon Research And Engineering Co. | Branched alkyl-aromatic sulfonic acid dispersants for solublizing asphaltenes in petroleum oils |
US7332460B2 (en) * | 2004-07-15 | 2008-02-19 | Chevron Oronite Company Llc | Alkylxylene sulfonates for enhanced oil recovery processes |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2500024A (en) * | 1950-03-07 | Aqueous detergent | ||
US2467170A (en) * | 1947-10-15 | 1949-04-12 | Du Pont | Alkyl substituted aromatic sulfonates |
US2525024A (en) * | 1947-12-26 | 1950-10-10 | Allied Chem & Dye Corp | Process of producing alkyl benzene hydrocarbon sulfonates |
US2681362A (en) * | 1949-10-07 | 1954-06-15 | Sun Oil Co | Alkyl substituted benzene sulfonate |
-
0
- BE BE529128D patent/BE529128A/xx unknown
-
1953
- 1953-05-29 NL NL178695A patent/NL178695B/xx unknown
-
1954
- 1954-05-17 US US430398A patent/US2796429A/en not_active Expired - Lifetime
- 1954-05-26 GB GB15592/54A patent/GB770310A/en not_active Expired
- 1954-05-26 CH CH330486D patent/CH330486A/en unknown
- 1954-05-26 FR FR1105032D patent/FR1105032A/en not_active Expired
Also Published As
Publication number | Publication date |
---|---|
NL178695B (en) | 1956-06-15 |
US2796429A (en) | 1957-06-18 |
CH330486A (en) | 1958-06-15 |
FR1105032A (en) | 1955-11-25 |
BE529128A (en) |
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