GB751934A - Improvements in or relating to the copolymerisation of a 2-aryl-alkene-1 and an alpha, beta-olefinic aldehyde - Google Patents
Improvements in or relating to the copolymerisation of a 2-aryl-alkene-1 and an alpha, beta-olefinic aldehydeInfo
- Publication number
- GB751934A GB751934A GB27140/54A GB2714054A GB751934A GB 751934 A GB751934 A GB 751934A GB 27140/54 A GB27140/54 A GB 27140/54A GB 2714054 A GB2714054 A GB 2714054A GB 751934 A GB751934 A GB 751934A
- Authority
- GB
- United Kingdom
- Prior art keywords
- propene
- phenyl
- reaction
- butene
- aldehyde
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/06—Oxidation
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Phenolic Resins Or Amino Resins (AREA)
Abstract
An alpha-beta olefinic aldehyde is copolymerized with a 2-arylalkene-1 containing at least three carbon atoms in the alkene group by heating a liquid mixture of the monomers at 50 DEG to 200 DEG C., preferably 80 DEG to 150 DEG C. The aldehyde may be acrolein or 2-methyl, 2-ethyl, 2-isopropyl, 2-isobutyl, 2-neopentyl, 2-octyl or 2-phenyl propenal. The hydrocarbon may be 2-phenyl-propene, -butene-1, -pentene-1, -3-methyl-butene-1, -octene-1 or -octadecene-1, 2 - (4 - methylphenyl) propene - 1, 2 - (2 - isopropylphenyl) butene-1, 2-(4-phenyl-phenylheptene-1) heptene-1, 2-(2,4-dimethyl phenyl) propene-1, 2-(2,4,6-trimethylphenyl) propene-1, or 2-naphthenyl-propene-1. Copolymerization may be effected in the presence of a peroxy catalyst such as benzoyl, acetyl, lauroyl or ditertiary-butyl peroxide or tertiary-butyl hydroperoxide. The copolymers are soluble in acetone, benzene, toluene, dioxane, chloroform and pyridine, and may be used in combination with nitrocellulose, polyvinyl chloride-acetate and varnish oils in the production of films and for moulding. The copolymers will undergo further reaction in the following ways: (a) hydrogenation to form polyhydric alcohols by reduction of the aldehyde groups. These polyhydric alcohols may be mixed with heat-convertible urea-formaldehyde or melamine-formaldehyde resins and baked as a film to form surface coatings; they may be esterified with polycarboxylic acids to form new alkyd resins, or with unsaturated fatty acids, such as are obtainable from soybean oil, dehydrated castor oil and linseed oil to form synthetic drying oils; (b) oxidation to obtain resinous polycarboxylic acids which may be esterified with alcohols to give esters or neutralized with ammonia and/or soda to give salts useful as soil conditioners; (c) reaction with mercaptans to form polymercaptals; (d) reaction with hydroxylamine to form polyoximes; (e) reaction with formaldehyde, ammonia, amines, phenols, urea or melamine to give modified resins.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US751934XA | 1953-09-21 | 1953-09-21 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB751934A true GB751934A (en) | 1956-07-04 |
Family
ID=22124159
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB27140/54A Expired GB751934A (en) | 1953-09-21 | 1954-09-20 | Improvements in or relating to the copolymerisation of a 2-aryl-alkene-1 and an alpha, beta-olefinic aldehyde |
Country Status (2)
Country | Link |
---|---|
FR (1) | FR1112430A (en) |
GB (1) | GB751934A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2985610A (en) * | 1958-07-18 | 1961-05-23 | Monsanto Chemicals | Condensation products of polymeric oximes and aminoplasts and method of making same |
US3234164A (en) * | 1955-03-23 | 1966-02-08 | Degussa | Conversion of non-fusible and insoluble polyacroleins with hydroxyl amine |
-
1954
- 1954-09-20 GB GB27140/54A patent/GB751934A/en not_active Expired
- 1954-09-21 FR FR1112430D patent/FR1112430A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3234164A (en) * | 1955-03-23 | 1966-02-08 | Degussa | Conversion of non-fusible and insoluble polyacroleins with hydroxyl amine |
US2985610A (en) * | 1958-07-18 | 1961-05-23 | Monsanto Chemicals | Condensation products of polymeric oximes and aminoplasts and method of making same |
Also Published As
Publication number | Publication date |
---|---|
FR1112430A (en) | 1956-03-14 |
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