GB727717A - Improvements in methods of chemically modifying butyl rubber and products resulting therefrom - Google Patents
Improvements in methods of chemically modifying butyl rubber and products resulting therefromInfo
- Publication number
- GB727717A GB727717A GB28483/53A GB2848353A GB727717A GB 727717 A GB727717 A GB 727717A GB 28483/53 A GB28483/53 A GB 28483/53A GB 2848353 A GB2848353 A GB 2848353A GB 727717 A GB727717 A GB 727717A
- Authority
- GB
- United Kingdom
- Prior art keywords
- parts
- butyl rubber
- butyl
- butadiene
- methods
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Butyl rubber is vulcanized by heating it with a dimethylol phenol and chlorosulphonated polythene in the presence of zinc oxide or of a zinc salt of a fatty acid. The Butyl rubber may be derived from isobutylene or ethyl methyl ethylene and butadiene, isoprene, piperylene, 1,2-, 1,3-, 1,4-, or 2,3-dimethyl butadiene or 1-ethyl butadiene. The dimethylol phenol may be resinous or not, and specified are 2,6-di-methylol 4-hydrocarbon phenols where the hydrocarbon is methyl, tertiary-butyl, octyl, tertiary-octyl, dodecyl, phenyl, benzyl, alpha, alpha-dimethyl-benzyl and cyclohexyl. Specified zinc salts are the laurate and stearate. Preferred amounts of phenol are about 4 to 15 parts, of chlorosulphonated polythene about 2 to 10 parts, and of zinc oxide (or its salt equivalent) 1 to 5 parts, all per 100 parts of Butyl, while preferred temperatures are 320-370 DEG F. The rubber may be compounded with reinforcing material, e.g. carbon black, and used for curing bags or inner tubes. Specification 718,768 is referred to.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US727717XA | 1952-12-30 | 1952-12-30 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB727717A true GB727717A (en) | 1955-04-06 |
Family
ID=22109649
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB28483/53A Expired GB727717A (en) | 1952-12-30 | 1953-10-15 | Improvements in methods of chemically modifying butyl rubber and products resulting therefrom |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB727717A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0032123A2 (en) * | 1980-01-04 | 1981-07-15 | Monsanto Company | Mono-olefin polymers having methylol phenolic groups grafted thereto, a process for their production and polymer blends containing them |
-
1953
- 1953-10-15 GB GB28483/53A patent/GB727717A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0032123A2 (en) * | 1980-01-04 | 1981-07-15 | Monsanto Company | Mono-olefin polymers having methylol phenolic groups grafted thereto, a process for their production and polymer blends containing them |
EP0032123A3 (en) * | 1980-01-04 | 1981-07-22 | Monsanto Company | Mono-olefin polymers having methylol phenolic groups grafted thereto, a process for their production and polymer blends containing them |
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