GB727587A - Process for scrubbing impurities from gases, more especially from carbon dioxide produced by fermentation - Google Patents
Process for scrubbing impurities from gases, more especially from carbon dioxide produced by fermentationInfo
- Publication number
- GB727587A GB727587A GB11163/52A GB1116352A GB727587A GB 727587 A GB727587 A GB 727587A GB 11163/52 A GB11163/52 A GB 11163/52A GB 1116352 A GB1116352 A GB 1116352A GB 727587 A GB727587 A GB 727587A
- Authority
- GB
- United Kingdom
- Prior art keywords
- formaldehyde
- gas
- sulphuric acid
- concentrated sulphuric
- gases
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
- C10K1/10—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
- C10K1/102—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids containing free acid
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/50—Carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12F—RECOVERY OF BY-PRODUCTS OF FERMENTED SOLUTIONS; DENATURED ALCOHOL; PREPARATION THEREOF
- C12F3/00—Recovery of by-products
- C12F3/02—Recovery of by-products of carbon dioxide
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- Bioinformatics & Cheminformatics (AREA)
- General Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Genetics & Genomics (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Treating Waste Gases (AREA)
- Gas Separation By Absorption (AREA)
Abstract
Carbon dioxide produced by fermentation is freed from impurities such as fusel alcohols, thioethers, mercaptans, disulphides, hydrogen sulphide, skatole and cadaverine by bringing the gases into contact with a solution of formaldehyde in sulphuric acid, substantially free of water. The gas-washing liquid may be prepared by introducing gaseous formaldehyde into concentrated sulphuric acid or by dissolving solid para-formaldehyde in concentrated sulphuric acid. Sulphur dioxide contaminant may be removed by a prior passage of the gas through a tower containing wetted limestone and after treatment with the formaldehyde sulphuric acid mixture the gas may be passed through a further scrubber containing concentrated sulphuric acid to remove traces of formaldehyde. If the latter purification step is admitted the gas contains small quantities of formaldehyde or its oxidation product, formic acid, and this gas may be used in the production of dry ice or in the production of Seltzer water.ALSO:Gases produced by fermentation are freed from impurities such as fusel alcohols, thioethers, mercaptans, disulphides, hydrogen sulphide, skatole and cadaverine by bringing the gases into contact with a solution of formaldehyde in sulphuric acid, substantially free of water. The process is particularly applicable to carbon dioxide. The gas washing liquid may be prepared by introducing gaseous formaldehyde into concentrated sulphuric acid or by dissolving solid para-formaldehyde in concentrated sulphuric acid. Sulphur dioxide contaminant may be removed by a prior passage of the gas through a tower containing wetted limestone and after treatment with the formaldehyde/sulphuric acid mixture the gas may be passed through a further scrubber containing concentrated sulphuric acid to remove traces of formaldehyde. If the latter purification step is admitted the gas contains small quantities of formaldehyde or its oxidation product, formic acid, and this gas may be used in the production of dry ice or in the production of Seltzer water.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE727587X | 1951-05-11 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB727587A true GB727587A (en) | 1955-04-06 |
Family
ID=6635502
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB11163/52A Expired GB727587A (en) | 1951-05-11 | 1952-05-02 | Process for scrubbing impurities from gases, more especially from carbon dioxide produced by fermentation |
Country Status (2)
Country | Link |
---|---|
DE (1) | DE890633C (en) |
GB (1) | GB727587A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1454881A1 (en) * | 2003-03-07 | 2004-09-08 | RCH Holding AG | Brewing process |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE502005000285D1 (en) | 2005-02-16 | 2007-02-15 | Krones Ag | Aerosol separator in a plant for the recovery of carbon dioxide |
-
0
- DE DENDAT890633D patent/DE890633C/en not_active Expired
-
1952
- 1952-05-02 GB GB11163/52A patent/GB727587A/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1454881A1 (en) * | 2003-03-07 | 2004-09-08 | RCH Holding AG | Brewing process |
Also Published As
Publication number | Publication date |
---|---|
DE890633C (en) | 1953-08-13 |
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