GB721886A - Processes for the preparation of basic alkaline earth metal petroleum sulphonates - Google Patents

Processes for the preparation of basic alkaline earth metal petroleum sulphonates

Info

Publication number
GB721886A
GB721886A GB30480/51A GB3048051A GB721886A GB 721886 A GB721886 A GB 721886A GB 30480/51 A GB30480/51 A GB 30480/51A GB 3048051 A GB3048051 A GB 3048051A GB 721886 A GB721886 A GB 721886A
Authority
GB
United Kingdom
Prior art keywords
sulphonate
oil
earth metal
alkaline
water
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB30480/51A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bataafsche Petroleum Maatschappij NV
Original Assignee
Bataafsche Petroleum Maatschappij NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bataafsche Petroleum Maatschappij NV filed Critical Bataafsche Petroleum Maatschappij NV
Publication of GB721886A publication Critical patent/GB721886A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M159/00Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
    • C10M159/12Reaction products
    • C10M159/20Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products
    • C10M159/24Reaction mixtures having an excess of neutralising base, e.g. so-called overbasic or highly basic products containing sulfonic radicals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C309/00Sulfonic acids; Halides, esters, or anhydrides thereof
    • C07C309/01Sulfonic acids
    • C07C309/62Sulfonated fats, oils or waxes of undetermined constitution
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07GCOMPOUNDS OF UNKNOWN CONSTITUTION
    • C07G99/00Subject matter not provided for in other groups of this subclass
    • C07G99/002Compounds of unknown constitution containing sulfur
    • C07G99/0024Overbased compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/046Overbasedsulfonic acid salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/02Groups 1 or 11
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/04Groups 2 or 12
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00Specific manufacturing methods for lubricant compositions
    • C10N2070/02Concentrating of additives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Lubricants (AREA)

Abstract

Oil-soluble basic alkaline-earth metal petroleum sulphonates suitable as lubricant additives are prepared by converting an oil-soluble alkali-metal petroleum sulphonate dissolved in a petroleum fraction and contaminated with inorganic salts and/or water-soluble petroleum sulphonates, into the oil-soluble neutral alkaline-earth metal sulphonate by treatment with a water-soluble alkaline earth metal salt and converting the neutral alkaline-earth metal sulphonate into an oil-soluble basic alkaline-earth metal sulphonate by treatment with at least a molar equivalent of a basic inorganic alkaline earth metal compound, calculated on the alkaline earth metal sulphonate present in the petroleum fraction, the solution of the alkali or neutral alkaline earth metal sulphonate in the petroleum fraction being washed with water so as to remove said contaminants before the conversion into the basic alkaline earth metal sulphonate is carried out, the amount of water used being at least 50 per cent, preferably 100 to 500 per cent, by volume based on the volume of the solution of alkali-metal sulphonate in the petroleum fraction; a minor amount of a monohydric alcohol having not more than 12 carbon atoms may be added to the washing water. The initial petroleum solution of alkali-metal sulphonate is preferably prepared from a petroleum oil having lubricating properties and containing naphthenic hydrocarbons. The oil may be solvent extracted with furfural, sulphur dioxide or other like solvent and the raffinate purified by a sulphuric acid treatment. The raffinate is sulphonated at about 75 DEG to 200 DEG F. with fuming sulphuric acid, the product diluted with water, an aqueous sludge phase removed and the oil phase containing desired sulphonic acids neutralized with a basic alkali-metal compound. The preferred embodiment of the invention comprises simultaneously converting the alkali-metal sulphonate in this oil solution into the neutral alkaline-earth metal sulphonate and washing the solution and thereafter converting the neutral salt into the basic alkaline earth metal salt. Thus, the sodium sulphonate-oil solution may be contacted at about 200 DEG F. with the large quantity of wash water specified and with at least a molar equivalent of calcium chloride, preferably two molar equivalents, p sufficient to convert the sodium sulphonate and sodium sulphate present into the corresponding neutral calcium salts and for a period of time sufficient for substantial conversion to occur, a resulting aqueous phase of pH not greater than 8 is separated, and the oil phase treated at about 200 DEG F. with a minor amount of water plus at least a molar equivalent of calcium hydroxide based on the calcium sulphonate in the oil phase and preferably with 0.4 to 0.8 molar equivalent of calcium chloride based on amount of sodium sulphonate present originally in the oil solution. The resulting oil solution of basic calcium sulphonate may be clarified by settling or drying to remove water and filtered. Graphs (not shown) indicate that this filtration is much easier than that required in prior processes wherein there is no washing of the sulphonate-oil solution as specified. The calcium hydroxide and chloride may be replaced by other basic alkaline earth metal compounds and water-soluble alkaline earth metal salts, including those of barium, strontium and magnesium. An example is given wherein the initial oil solution of sodium petroleum sulphonates is derived from a lubricating oil of viscosity 400 S.S.U. at 100 DEG F., and the solution contains 13 per cent sodium sulphonates, 5 per cent water, 2 per cent inorganic salts and the remainder unsulphonated oil. Specification 603,238 is referred to.ALSO:Lubricating oil compositions comprising oil-soluble basic alkaline-earth metal sulphonates are prepared by converting an oil-soluble alkali-metal petroleum sulphonate dissolved in a petroleum fraction and contaminated with inorganic salts and/or water-soluble sulphonates into the oil soluble neutral alkaline-earth metal sulphonate by treatment with a water-soluble alkaline-earth metal salt and converting the neutral alkaline earth-metal sulphonate into the basic alkaline-earth metal salt by treatment with at least a molar equivalent of a basic inorganic alkaline-earth metal compound, calculated on the alkaline-earth metal sulphonate present in the petroleum fraction, the solution of the alkali-metal or neutral alkaline-earth metal sulphonate in the petroleum fraction being washed with water so as to remove said contaminants before the conversion into the basic alkaline-earth metal sulphonate is carried out, the amount of water used being at least 50 per cent, preferably 100 to 500 per cent, by volume based on the volume of the solution of alkali-metal sulphonate in the petroleum fraction; a minor proportion of a monohydric alcohol containing not more than 12 carbon atoms may be present in the wash water. The initial oil solution of alkali-metal sulphonate may be prepared from a petroleum oil having lubricating properties and containing naphthenic hydrocarbons. The oil may be solvent extracted with furfural, sulphur dioxide or like solvent and the raffinate purified by sulphuric acid treatment. The raffinate is then sulphonated with fuming sulphuric acid, diluted with water, the resulting aqueous sludge removed and the oil phase containing sulphonic acids neutralized with a basic alkali-metal compound. The preferred embodiment of the invention comprises simultaneously converting the alkali-metal sulphonates in the oil solution into the neutral alkaline-earth metal sulphonates and washing the solution and thereafter converting the neutral alkaline-earth metal salt into the basic salt. Thus, the sodium sulphonate-oil solution may be contacted at about 200 DEG F. with the wash water and with at least a molar equivalent of calcium chloride, sufficient to convert the sodium sulphonate and sodium sulphate present into the corresponding neutral calcium salts, for a period of time sufficient for at least 70 per cent conversion to occur, an aqueous phase of pH not greater than 8 is separated and the oil phase treated at about 200 DEG F. with a minor amount of water plus at least a molar equivalent of calcium hydroxide based on the calcium sulphonate in the oil phase and preferably with 0.4 to 0.8 molar equivalent of calcium chloride based on the amount of sodium sulphonate present originally in the oil solution. The resulting oil solution of basic calcium sulphonate may be clarified by settling or drying to remove water and filtered. Graphs (not shown) illustrate the ease of this filtration compared with that in prior processes wherein the washing step is omitted. The calcium hydroxide and chloride may be replaced by other basic alkaline-earth metal compounds and water-soluble alkaline-earth metal salts including those of barium, strontium and magnesium. An example is given using an initial oil solution of sodium sulphonates derived from a lubricating oil of viscosity 400 S.S.U. at 100 DEG F. and containing 13 per cent sodium sulphonates, 5 per cent water, 2 per cent inorganic salts and the remainder of unsulphonated oil. Specification 603,238 is referred to.
GB30480/51A 1950-12-29 1951-12-31 Processes for the preparation of basic alkaline earth metal petroleum sulphonates Expired GB721886A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US721886XA 1950-12-29 1950-12-29

Publications (1)

Publication Number Publication Date
GB721886A true GB721886A (en) 1955-01-12

Family

ID=22106114

Family Applications (1)

Application Number Title Priority Date Filing Date
GB30480/51A Expired GB721886A (en) 1950-12-29 1951-12-31 Processes for the preparation of basic alkaline earth metal petroleum sulphonates

Country Status (3)

Country Link
DE (1) DE881653C (en)
GB (1) GB721886A (en)
NL (1) NL79653C (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2902511A (en) * 1956-09-17 1959-09-01 Hall Stewart Oil additive and process for its preparation

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1102139B (en) * 1957-12-06 1961-03-16 Exxon Standard Sa Process for the production of oil-soluble alkaline earth sulfonates of high alkalinity
BE594276A (en) * 1958-10-13

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2902511A (en) * 1956-09-17 1959-09-01 Hall Stewart Oil additive and process for its preparation

Also Published As

Publication number Publication date
NL79653C (en)
DE881653C (en) 1953-07-02

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