GB719627A - Improvements relating to desulphurisation catalysts - Google Patents

Improvements relating to desulphurisation catalysts

Info

Publication number
GB719627A
GB719627A GB2284451A GB2284451A GB719627A GB 719627 A GB719627 A GB 719627A GB 2284451 A GB2284451 A GB 2284451A GB 2284451 A GB2284451 A GB 2284451A GB 719627 A GB719627 A GB 719627A
Authority
GB
United Kingdom
Prior art keywords
cobalt
catalysts
fluoride
hydrogen
molybdenum
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2284451A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FREDERICK WILLIAM BERTRAM PORT
Anglo Iranian Oil Co Ltd
Original Assignee
FREDERICK WILLIAM BERTRAM PORT
Anglo Iranian Oil Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FREDERICK WILLIAM BERTRAM PORT, Anglo Iranian Oil Co Ltd filed Critical FREDERICK WILLIAM BERTRAM PORT
Priority to GB2284451A priority Critical patent/GB719627A/en
Publication of GB719627A publication Critical patent/GB719627A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
    • C10G29/06—Metal salts, or metal salts deposited on a carrier
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/24—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing with hydrogen-generating compounds
    • C10G45/28—Organic compounds; Autofining

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

A catalyst for use in the desulphurization of hydrocarbons consists of a mixture of the oxides of cobalt and molybdenum, or a chemical compound of cobalt, molybdenum and oxygen or a mixture of one or both of said oxides with said compound, dispersed on a support consisting essentially of alumina, the catalyst containing fluorine in an amount from about 0.1-6 per cent. by weight. A support of activated alumina or bauxite may be impregnated with an aqueous solution containing all three catalytic elements, or with separate solutions containing the elements in any order. The support may be dried and roasted (e.g. at 550 DEG C.) after each impregnation. Alternatively solid components of the catalyst may be mixed together. Substances used in the preparation of the catalysts are cobalt nitrate, ammonium molybdate, cobalt fluoride, aluminium fluoride, molybdenum, trioxide, cobalt oxide, hydrogen fluoride, and ammonium fluoride. The catalysts may be reduced in hydrogen or hydrogen sulphide, and are used for the refining of hydrocarbons containing sulphur compounds at 600 DEG -900 DEG F. in the presence of added hydrogen for example as described in Specifications 654,152, 663,038, 669,536, 669,552, 669,553, 697,222, 697,226, and 697,724. Examples describe the preparation of catalysts using alumina gel as the carrier, and processes for the treatment of gas oil in which the gaseous reaction products are recycled.
GB2284451A 1951-10-01 1951-10-01 Improvements relating to desulphurisation catalysts Expired GB719627A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2284451A GB719627A (en) 1951-10-01 1951-10-01 Improvements relating to desulphurisation catalysts

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2284451A GB719627A (en) 1951-10-01 1951-10-01 Improvements relating to desulphurisation catalysts

Publications (1)

Publication Number Publication Date
GB719627A true GB719627A (en) 1954-12-08

Family

ID=10185957

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2284451A Expired GB719627A (en) 1951-10-01 1951-10-01 Improvements relating to desulphurisation catalysts

Country Status (1)

Country Link
GB (1) GB719627A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2963446A (en) * 1954-06-24 1960-12-06 British Petroleum Co Redistribution of fluorine in a hydrodesulphurization catalyst
US2983689A (en) * 1954-06-24 1961-05-09 British Petroleum Co Redistribution of fluorine in a hydrodesulphurization catalyst
CN112517051A (en) * 2021-01-18 2021-03-19 陕西延长石油（集团）有限责任公司 Catalyst for preparing ethylamine by ethanol amination and preparation method and application thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2963446A (en) * 1954-06-24 1960-12-06 British Petroleum Co Redistribution of fluorine in a hydrodesulphurization catalyst
US2983689A (en) * 1954-06-24 1961-05-09 British Petroleum Co Redistribution of fluorine in a hydrodesulphurization catalyst
CN112517051A (en) * 2021-01-18 2021-03-19 陕西延长石油（集团）有限责任公司 Catalyst for preparing ethylamine by ethanol amination and preparation method and application thereof

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