GB716126A - Process of producing compounds of metal alcoholate type - Google Patents
Process of producing compounds of metal alcoholate typeInfo
- Publication number
- GB716126A GB716126A GB17176/51A GB1717651A GB716126A GB 716126 A GB716126 A GB 716126A GB 17176/51 A GB17176/51 A GB 17176/51A GB 1717651 A GB1717651 A GB 1717651A GB 716126 A GB716126 A GB 716126A
- Authority
- GB
- United Kingdom
- Prior art keywords
- oxide
- solution
- ferric
- titanium
- carbon tetrachloride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F19/00—Metal compounds according to more than one of main groups C07F1/00 - C07F17/00
- C07F19/005—Metal compounds according to more than one of main groups C07F1/00 - C07F17/00 without metal-C linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Epoxy Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Compounds of metal alcoholate type of the metals titanium, iron, and aluminium are obtained by reacting a substituted or unsubstituted alkylene oxide with anhydrous titanic, ferric, or aluminium chloride or bromide in solution in ethyl alcohol or carbon tetrachloride. Suitable alkylene oxides include ethylene oxide, propylene oxide, epichlorhydrin, cyclohexene oxide and phenoxy propylene oxide. The process may be carried out by dissolving the metallic chloride in ethyl alcohol or carbon tetrachloride and gradually adding thereto the alkylene oxide which may also be dissolved in ethyl alcohol or carbon tetrachloride. The reaction of at least three mols. of alkylene oxide per mol. of ferric or aluminium chloride and the reaction of at least 4 mols. of alkylene oxide with 1 mol. of titanium tetrachloride yields neutral products but when smaller amounts of alkylene oxide are used the product still contains a chlorine atom attached to the metal atom, thus 3 mols. of ethylene oxide reacts with 1 mol. of titanium tetrachloride to yield the compound Ti(O.CH2.CH2.Cl)3Cl. The products may be treated with water to yield the corresponding metallic hydroxides (see Group III) and may find application as intermediates in the manufacture of organometallic compounds. In examples (1) anhydrous titanium tetrachloride is dissolved in carbon tetrachloride in a flask fitted with a reflux condenser and dry ethylene oxide introduced whilst cooling the reaction vessel to prevent the temperature exceeding 50 DEG C., the ethylene oxide being added until a sample shows a neutral reaction to wet titmus paper; (2) cyclohexene oxide is added to a solution of titanium tetrachloride in carbon tetrachloride and after distilling off the solvent a colourless viscous liquid is obtained which is soluble in acetic ester, benzene, gasoline and alcohol, and on adding water yields a precipitate of titanium hydroxide; (3) ethylene oxide is introduced into a solution of anhydrous ferric chloride in dry alcohol with cooling until a sample shows an almost neutral reaction to wet indicator paper. A deep brown solution is formed from which ferric hydroxide precipitated on adding a little water. Reference is also made to the reaction of ferric chloride with propylene oxide and aluminium chloride with epichlorhydrin.ALSO:Metal alcoholate type compounds of titanium, iron, and aluminium obtained by reacting a substituted or unsubstituted alkylene oxide with anhydrous titanic, ferric, or aluminium chloride or bromide in solution in ethyl alcohol or carbon tetrachloride (see Group IV (b)) are stated to yield the corresponding metallic hydroxides on admixture with water. Suitable alkylene oxides include ethylene oxide, propylene oxide, epichlorhydrin, cyclohexene oxide and phenoxy propylene oxide. In examples:-(1) cyclohexene oxide is added to a solution of titanium tetrachloride in carbon tetrachloride and after distilling off the solvent a colourless viscous liquid is obtained which on adding water yields a precipitate of titanium hydroxide; (2) ethylene oxide is introduced into a solution of anhydrous ferric chloride in dry alcohol, with cooling, until a sample shows an almost neutral reaction to wet indicator paper. A deep brown solution is formed from which ferric hydroxide precipitates on adding a little water. On adding a further quantity of water a colloidal solution is formed.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE716126X | 1950-08-19 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB716126A true GB716126A (en) | 1954-09-29 |
Family
ID=6626353
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB17176/51A Expired GB716126A (en) | 1950-08-19 | 1951-07-19 | Process of producing compounds of metal alcoholate type |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB716126A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1147938B (en) * | 1959-04-30 | 1963-05-02 | Roehm & Haas Gmbh | Production of AEthane-1, 2-diol and propane-1, 2-diol monoacrylate and monomethacrylate |
US3238237A (en) * | 1959-08-10 | 1966-03-01 | Jefferson Chem Co Inc | Method of producing trialkoxy aluminum compounds |
-
1951
- 1951-07-19 GB GB17176/51A patent/GB716126A/en not_active Expired
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1147938B (en) * | 1959-04-30 | 1963-05-02 | Roehm & Haas Gmbh | Production of AEthane-1, 2-diol and propane-1, 2-diol monoacrylate and monomethacrylate |
US3238237A (en) * | 1959-08-10 | 1966-03-01 | Jefferson Chem Co Inc | Method of producing trialkoxy aluminum compounds |
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