GB710513A - Polyester terpolymers - Google Patents
Polyester terpolymersInfo
- Publication number
- GB710513A GB710513A GB23747/51A GB2374751A GB710513A GB 710513 A GB710513 A GB 710513A GB 23747/51 A GB23747/51 A GB 23747/51A GB 2374751 A GB2374751 A GB 2374751A GB 710513 A GB710513 A GB 710513A
- Authority
- GB
- United Kingdom
- Prior art keywords
- anhydride
- methyl
- carbic
- diethyl
- acids
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/52—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
- C08G63/54—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation the acids or hydroxy compounds containing carbocyclic rings
- C08G63/553—Acids or hydroxy compounds containing cycloaliphatic rings, e.g. Diels-Alder adducts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/01—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to unsaturated polyesters
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Terpolymers of (1) an organic solvent soluble polyhydric alcohol polyester of cis-3, 6-endomethylene delta-4-tetrahydrophthalic anhydride containing not more than three diacyl residues of the dibasic adduct per average polyester molecule, (2) styrene or its derivatives, and (3) a mono-olefinic compound having in conjunction with the double bond either a carboxyl or cyano group, are prepared by heating in solution in the presence of a catalyst. Styrene derivatives mentioned are, p-chlorostyrene, 2, 5-dichlorostyrene, p-methyl, p-ethyl and p-isopropyl styrenes, p-dimethyl-amino vinyl benzene and p-benzyl styrene. The monoolefinic compounds (2) may be acrylonitrile, methacrylonitrile, methacrylamide, N, N1-dimethylacrylamide, acrylic or methacrylic acid or their methyl, ethyl, propyl, methoxy or propoxy esters, mono- and diesters of unsaturated dicarboxylic acids, such as monobutyl maleate, and ethyl and diethyl crotonates (a long list of suitable mono- and di-carboxylic acids and their esters is given), vinyl ketones such as methyl and phenyl vinyl ketones and monohydric half esters of D 1, 4-dihydro phthalic acid, or of "Carbic" (R.T.M.) acid or anhydride. Dicarboxylic acids, e.g. phthalic, succinic and adipic acids, and monocarboxylic acids, e.g. those derived from linseed and soya oils may partially replace the anhydride (1). Solvents used may be benzene, toluene, xylene, butyl acetate, or propionate, diethyl phthalate, diethylene glycol monobutyl ether acetate, methyl isobutyl and diisobutyl ketones, and n-butyl ether, together with diluents such as mineral spirits or petroleum naphtha. The catalysts, e.g. benzoyl, p-chlorobenzoyl, and methyl amyl ketone peroxides, t-butyl per benzoate and t-butyl and cumene hydroperoxides may be added portionwise. Examples describe the preparation of polyesters from "Carbic" anhydride modified with castor oil, alone or with glycerol or ethylene glycol or a mixture of these, lauric acid, coconut and soya bean oils or their fatty acids, with glycerol; "Carbic" anhydride mixed with phthalic anhydride and castor oil or 2-ethylhexandiol 1, 3; "Carbic" anhydride with castor oil, glycerol and hydrogenated rosin; or mixed "Carbic" anhydride-phthalic anhydride with castor oil, glycerol and hydrogenated rosin acids or hydroabietyl alcohol. The polyesters are then polymerised with styrene and ethyl acrylate, 3-ethoxy propyl acrylate, methyl methacrylate, dimethyl, diethyl or dioctyl maleate, dimethyl dichloromaleate, diethylmonochloromaleate, diethyl dihydrophthalate, diethyl itaconate or citraconate, methylacrylonitrile, methacrylamide and the diethyl ester of "Carbic" anhydride. Terpolymers including acrylonitrile require solvents such as methoxyacetamide, N-formyl morpholine and N-formyl hexamethylene imine in their preparation. The terpolymers may be used in coating compositions with nitrocellulose dissolved in butyl acetate, or a blend of phenyl methyl carbinol with acetophenone, with partially hydrolysed vinyl chloride-acetate copolymer dissolved in methyl isobutyl ketone, with cellulose acetate or ethyl cellulose. Plasticizers such as dibutyl or dioctyl phthalate or ester gum may be added, and the addition of driers yields air-drying compositions. The terpolymers may also be used as plasticisers for alkylated urea-or melamine-formaldehyde resins.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US710513XA | 1950-10-19 | 1950-10-19 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB710513A true GB710513A (en) | 1954-06-16 |
Family
ID=22098937
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB23747/51A Expired GB710513A (en) | 1950-10-19 | 1951-10-11 | Polyester terpolymers |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB710513A (en) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3225117A (en) * | 1962-06-15 | 1965-12-21 | Cincinnati Milling Machine Co | Weather-resistant plastics |
DE1237245B (en) * | 1964-02-13 | 1967-03-23 | Basf Ag | Lacquers |
DE1238141B (en) * | 1964-02-12 | 1967-04-06 | Basf Ag | Lacquers |
US3347806A (en) * | 1951-01-28 | 1967-10-17 | Albert Ag Chem Werke | New dicyclopentadiene modified unsaturated polyesters and process for preparing them |
EP0008216A1 (en) * | 1978-08-08 | 1980-02-20 | Scott Bader Company Limited | Improvements in unsaturated polyester resins and methods of making them |
WO2010108941A1 (en) * | 2009-03-25 | 2010-09-30 | Dsm Ip Assets B.V. | Resin composition |
-
1951
- 1951-10-11 GB GB23747/51A patent/GB710513A/en not_active Expired
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3347806A (en) * | 1951-01-28 | 1967-10-17 | Albert Ag Chem Werke | New dicyclopentadiene modified unsaturated polyesters and process for preparing them |
US3225117A (en) * | 1962-06-15 | 1965-12-21 | Cincinnati Milling Machine Co | Weather-resistant plastics |
DE1238141B (en) * | 1964-02-12 | 1967-04-06 | Basf Ag | Lacquers |
DE1237245B (en) * | 1964-02-13 | 1967-03-23 | Basf Ag | Lacquers |
EP0008216A1 (en) * | 1978-08-08 | 1980-02-20 | Scott Bader Company Limited | Improvements in unsaturated polyester resins and methods of making them |
WO2010108941A1 (en) * | 2009-03-25 | 2010-09-30 | Dsm Ip Assets B.V. | Resin composition |
US9221973B2 (en) | 2009-03-25 | 2015-12-29 | Dsm Ip Assets B.V. | Resin composition |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP1194493B1 (en) | Fast-dry, high solids coatings based on modified alkyd resins | |
GB573809A (en) | Improvements in or relating to the manufacture of interpolymers of aromatic vinyl hydrocarbons with other polymerisable organic compounds and of coating compositions obtained therefrom | |
GB702675A (en) | Copolymers of fatty oil modified polyesters and vinyl monomers | |
GB708123A (en) | Alkyd resins modified with substituted carbocyclic acids, and compositions containing the same | |
GB710513A (en) | Polyester terpolymers | |
US2627508A (en) | Long oil alkyd resins | |
US2590910A (en) | Rosin acid esters | |
US2320724A (en) | Method of treating styrene-unsaturated dicarboxylic acid resins | |
US3249653A (en) | Unsaturated polyesters prepared from glycidyl esters of mixed branched monocarboxylic acids | |
GB556113A (en) | Interpolymers of vinyl esters | |
US4072642A (en) | Alkyd resins | |
EP1495064A1 (en) | Fast-dry, high solids coating compositions based on acetoacetate-functionalizedalkyd resins | |
GB585496A (en) | New alkyd resins | |
GB738096A (en) | Improvements relating to the preparation of modified alkyd resins | |
US2234958A (en) | Esters and method of producing the same | |
US2044747A (en) | Resinous bodies and varnishes obtained therewith | |
US3333977A (en) | Water-dispersible coating compositions and phenolic wood bases coated therewith | |
GB419373A (en) | Improvements in or relating to the manufacture of resinous products | |
GB1013933A (en) | Improvements in or relating to the manufacture of alkyd resins | |
GB642414A (en) | Improvements in and relating to modified rosin esters and compositions containing them | |
US3109827A (en) | New reaction products of epoxidized oils and an antimony halide | |
US3444113A (en) | Low temperature curable wood coating composition | |
GB685649A (en) | A process for the preparation of polyesters, the polyesters so prepared and plastic compositions containing the polyesters | |
US3776868A (en) | Modified ester resins | |
GB574681A (en) | New synthetic drying oils and coating compositions |