GB683405A - Improvements in and relating to fuels for internal combustion engines - Google Patents
Improvements in and relating to fuels for internal combustion enginesInfo
- Publication number
- GB683405A GB683405A GB929/50A GB92950A GB683405A GB 683405 A GB683405 A GB 683405A GB 929/50 A GB929/50 A GB 929/50A GB 92950 A GB92950 A GB 92950A GB 683405 A GB683405 A GB 683405A
- Authority
- GB
- United Kingdom
- Prior art keywords
- tri
- lead
- orthophosphate
- fuels
- naphthyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/04—Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L10/00—Use of additives to fuels or fires for particular purposes
- C10L10/10—Use of additives to fuels or fires for particular purposes for improving the octane number
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/26—Organic compounds containing phosphorus
- C10L1/2633—Organic compounds containing phosphorus phosphorus bond to oxygen (no P. C. bond)
- C10L1/2641—Organic compounds containing phosphorus phosphorus bond to oxygen (no P. C. bond) oxygen bonds only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/30—Organic compounds compounds not mentioned before (complexes)
- C10L1/301—Organic compounds compounds not mentioned before (complexes) derived from metals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/30—Organic compounds compounds not mentioned before (complexes)
- C10L1/305—Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond)
- C10L1/306—Organic compounds compounds not mentioned before (complexes) organo-metallic compounds (containing a metal to carbon bond) organo Pb compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
An internal-combustion engine fuel comprises hydrocarbons of the gasoline boiling range containing a minor proportion of a tetra-alkyl lead, a minor proportion of a completely esterified ester of an oxyacid of phosphorus or arsenic containing at least one carbocyclic radical and a minor proportion of a halohydrocarbon scavenger. Preferably the organic ester scavenger is derived from phosphorus oxyacids such as ortho-, pyro-or metaphosphoric acid. Suitable esters are the triphenyl-, tricresyl-, tri (4 - ethylphenyl) -, tri (4 - tertiary - butylphenyl)-, trixylenyl-, tri-2-naphthyl-, tri(4-isopropyl-1-naphthyl)-, tribenzyl-, triphenylethyl-, tricyclohexyl-, tri(trichlorophenyl)- and tri(4-chlorobenzyl)-orthophosphates, di-isoamyl cyclohexyl orthophosphate, dibutyl phenyl-orthophosphate, 2-naphthyl diphenyl orthophosphate, 2-naphthyl - 31 - methylphenyl - phenyl - orthophosphate and triphenyl-phosphite. Other compounds are tri-o-, -m- or -p-cresyl arsenite and diethyl phenyl arsonate. The preferred ester is tri-cresyl orthophosphate. Suitable halohydrocarbon scavengers are ethylene dibromide or dichloride, acetylene tetrabromide, 2,2,3-trichlorobutane, 2-chloro-2, 3-dibromobutane, and the dibromotoluenes. The halohydrocarbon scavenger should not comprise more than 90 per cent by weight of the combined scavengers. The preferred range of total scavenger content is from 0.9 to 1.2 theories. Anti-oxidants such as 2, 4-dimethyl-6-tertiary butyl phenol, hydroquinone, 2,6-ditertiary butyl-4-methyl phenol, N-phenol-x-naphthylamine and N, N1-dibutyl-p-phenylene diamine may also be present in the fuel. Any tetra alkyl lead anti-knock agent may be used, such as tetraethyl lead, ethyl trimethyl lead, diethyl-dimethyl lead, triethyl methyl lead and tetramethyl lead. The invention is not applicable to gasolines containing iron carbonyl. The fuels of the invention are compared in tests with fuels containing conventional halohydrocarbon scavengers, and fuels containing oxyacid esters of phosphorus containing no carbocyclic radical. The Provisional Specification refers also to fuels comprising hydrocarbons of the gasoline boiling range containing a small amount of tetraethyl lead and a small amount of an organic ester of an oxy-acid of phosphorus containing at least one carbocyclic radical. The results of tests comparing a gasoline containing 7.2 millilitres of tetraethyl lead and the theoretical equivalent of ethylene dibromide with the same leaded gasoline containing the theoretical equivalent of tri-cresyl-orthophosphate are reported.
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL89156D NL89156C (en) | 1950-01-13 | ||
BE500535D BE500535A (en) | 1950-01-13 | ||
GB929/50A GB683405A (en) | 1950-01-13 | 1950-01-13 | Improvements in and relating to fuels for internal combustion engines |
FR1031830D FR1031830A (en) | 1950-01-13 | 1951-01-11 | Fuels for internal combustion engines |
CY10654A CY106A (en) | 1950-01-13 | 1954-01-07 | Improvements in and relating to fuels for internal combustion engines |
MY1/54A MY5400001A (en) | 1950-01-13 | 1954-12-30 | Improvements in and relating to fuels for internal combustion engines |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB929/50A GB683405A (en) | 1950-01-13 | 1950-01-13 | Improvements in and relating to fuels for internal combustion engines |
Publications (1)
Publication Number | Publication Date |
---|---|
GB683405A true GB683405A (en) | 1952-11-26 |
Family
ID=9712995
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB929/50A Expired GB683405A (en) | 1950-01-13 | 1950-01-13 | Improvements in and relating to fuels for internal combustion engines |
Country Status (6)
Country | Link |
---|---|
BE (1) | BE500535A (en) |
CY (1) | CY106A (en) |
FR (1) | FR1031830A (en) |
GB (1) | GB683405A (en) |
MY (1) | MY5400001A (en) |
NL (1) | NL89156C (en) |
Cited By (37)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2765220A (en) * | 1952-07-22 | 1956-10-02 | Shell Dev | Lead scavenger compositions |
US2764866A (en) * | 1953-01-02 | 1956-10-02 | Exxon Research Engineering Co | Use of phosphorus compounds in leaded gasoline |
US2794715A (en) * | 1953-08-13 | 1957-06-04 | Ethyl Corp | Fuel antiknock |
US2794722A (en) * | 1953-08-13 | 1957-06-04 | Ethyl Corp | Fuel antiknock |
US2794719A (en) * | 1953-08-13 | 1957-06-04 | Ethyl Corp | Fuel antiknock |
US2794716A (en) * | 1953-08-13 | 1957-06-04 | Ethyl Corp | Fuel antiknock |
US2794721A (en) * | 1953-08-13 | 1957-06-04 | Ethyl Corp | Fuel antiknock |
US2794714A (en) * | 1953-08-13 | 1957-06-04 | Ethyl Corp | Fuel antiknock |
US2794718A (en) * | 1953-08-13 | 1957-06-04 | Ethyl Corp | Fuel antiknock |
US2794713A (en) * | 1953-08-13 | 1957-06-04 | Ethyl Corp | Fuel antiknock |
US2794720A (en) * | 1953-08-13 | 1957-06-04 | Ethyl Corp | Fuel antiknock |
US2794723A (en) * | 1953-08-13 | 1957-06-04 | Ethyl Corp | Fuel antiknock |
US2833635A (en) * | 1954-04-29 | 1958-05-06 | Ethyl Corp | Gasoline fuel |
US2857255A (en) * | 1954-02-19 | 1958-10-21 | Socony Mobil Oil Co Inc | Gasoline composition |
US2860958A (en) * | 1956-08-10 | 1958-11-18 | Ethyl Corp | Antiknock compositions |
US2862801A (en) * | 1953-11-05 | 1958-12-02 | Ethyl Corp | Gasoline fuels |
US2863743A (en) * | 1953-11-27 | 1958-12-09 | Gulf Research Development Co | Motor fuel |
US2866695A (en) * | 1953-08-27 | 1958-12-30 | Ethyl Corp | Gasoline fuel |
US2890947A (en) * | 1956-11-14 | 1959-06-16 | Pure Oil Co | Gasoline motor fuel |
US2897071A (en) * | 1953-06-30 | 1959-07-28 | Ethyl Corp | Gasoline fuels |
US2935390A (en) * | 1954-01-29 | 1960-05-03 | Ethyl Corp | Fuel additives |
US2948600A (en) * | 1956-10-24 | 1960-08-09 | Ethyl Corp | Antiknock compositions |
US2948599A (en) * | 1954-07-26 | 1960-08-09 | Ethyl Corp | Gasoline fuel compositions |
US2999740A (en) * | 1956-11-27 | 1961-09-12 | Tidewater Oil Company | Surface ignition suppression |
US3000709A (en) * | 1956-10-24 | 1961-09-19 | Ethyl Corp | Antiknock gasoline compositions |
US3004838A (en) * | 1956-10-24 | 1961-10-17 | Ethyl Corp | Antiknock compositions |
US3007783A (en) * | 1958-11-18 | 1961-11-07 | Atlantic Refining Co | Motor fuel compositions |
US3009790A (en) * | 1957-04-05 | 1961-11-21 | Gulf Research Development Co | Fuel for spark ignition engines |
US3034877A (en) * | 1957-08-05 | 1962-05-15 | Exxon Research Engineering Co | Leaded gasolines |
US3038791A (en) * | 1959-07-16 | 1962-06-12 | Ethyl Corp | Phenyl phosphate compositions |
US3047372A (en) * | 1957-11-29 | 1962-07-31 | Exxon Research Engineering Co | Anti-knock gasoline |
US3052531A (en) * | 1957-02-01 | 1962-09-04 | Shell Oil Co | Fuel composition |
US3055747A (en) * | 1954-12-22 | 1962-09-25 | Ethyl Corp | Dimethyl-(monochlorotolyl)-phosphate as a gasoline additive |
US3056667A (en) * | 1959-09-02 | 1962-10-02 | Sinclair Research Inc | Leaded gasoline containing phosphorus and phosphate |
US3095285A (en) * | 1956-03-06 | 1963-06-25 | Gulf Oil Corp | Phosphorus-containing gasoline motor fuels |
US3113005A (en) * | 1953-11-05 | 1963-12-03 | Ethyl Corp | Gasoline fuels |
US3356471A (en) * | 1963-08-09 | 1967-12-05 | Du Pont | Triaryl phosphate mixtures |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL83051C (en) * | 1952-04-28 | |||
US2843465A (en) * | 1953-03-10 | 1958-07-15 | Shell Dev | Anti-fouling compositions |
US2841480A (en) * | 1953-04-24 | 1958-07-01 | Shell Dev | Lead scavenger compositions |
US2999739A (en) * | 1956-03-28 | 1961-09-12 | Ethyl Corp | Antiknock fluids |
-
0
- BE BE500535D patent/BE500535A/xx unknown
- NL NL89156D patent/NL89156C/xx active
-
1950
- 1950-01-13 GB GB929/50A patent/GB683405A/en not_active Expired
-
1951
- 1951-01-11 FR FR1031830D patent/FR1031830A/en not_active Expired
-
1954
- 1954-01-07 CY CY10654A patent/CY106A/en unknown
- 1954-12-30 MY MY1/54A patent/MY5400001A/en unknown
Cited By (37)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2765220A (en) * | 1952-07-22 | 1956-10-02 | Shell Dev | Lead scavenger compositions |
US2764866A (en) * | 1953-01-02 | 1956-10-02 | Exxon Research Engineering Co | Use of phosphorus compounds in leaded gasoline |
US2897071A (en) * | 1953-06-30 | 1959-07-28 | Ethyl Corp | Gasoline fuels |
US2794721A (en) * | 1953-08-13 | 1957-06-04 | Ethyl Corp | Fuel antiknock |
US2794715A (en) * | 1953-08-13 | 1957-06-04 | Ethyl Corp | Fuel antiknock |
US2794716A (en) * | 1953-08-13 | 1957-06-04 | Ethyl Corp | Fuel antiknock |
US2794719A (en) * | 1953-08-13 | 1957-06-04 | Ethyl Corp | Fuel antiknock |
US2794714A (en) * | 1953-08-13 | 1957-06-04 | Ethyl Corp | Fuel antiknock |
US2794718A (en) * | 1953-08-13 | 1957-06-04 | Ethyl Corp | Fuel antiknock |
US2794713A (en) * | 1953-08-13 | 1957-06-04 | Ethyl Corp | Fuel antiknock |
US2794720A (en) * | 1953-08-13 | 1957-06-04 | Ethyl Corp | Fuel antiknock |
US2794723A (en) * | 1953-08-13 | 1957-06-04 | Ethyl Corp | Fuel antiknock |
US2794722A (en) * | 1953-08-13 | 1957-06-04 | Ethyl Corp | Fuel antiknock |
US2866695A (en) * | 1953-08-27 | 1958-12-30 | Ethyl Corp | Gasoline fuel |
US3113005A (en) * | 1953-11-05 | 1963-12-03 | Ethyl Corp | Gasoline fuels |
US2862801A (en) * | 1953-11-05 | 1958-12-02 | Ethyl Corp | Gasoline fuels |
US2863743A (en) * | 1953-11-27 | 1958-12-09 | Gulf Research Development Co | Motor fuel |
US2935390A (en) * | 1954-01-29 | 1960-05-03 | Ethyl Corp | Fuel additives |
US2857255A (en) * | 1954-02-19 | 1958-10-21 | Socony Mobil Oil Co Inc | Gasoline composition |
US2833635A (en) * | 1954-04-29 | 1958-05-06 | Ethyl Corp | Gasoline fuel |
US2948599A (en) * | 1954-07-26 | 1960-08-09 | Ethyl Corp | Gasoline fuel compositions |
US3055747A (en) * | 1954-12-22 | 1962-09-25 | Ethyl Corp | Dimethyl-(monochlorotolyl)-phosphate as a gasoline additive |
US3095285A (en) * | 1956-03-06 | 1963-06-25 | Gulf Oil Corp | Phosphorus-containing gasoline motor fuels |
US2860958A (en) * | 1956-08-10 | 1958-11-18 | Ethyl Corp | Antiknock compositions |
US2948600A (en) * | 1956-10-24 | 1960-08-09 | Ethyl Corp | Antiknock compositions |
US3000709A (en) * | 1956-10-24 | 1961-09-19 | Ethyl Corp | Antiknock gasoline compositions |
US3004838A (en) * | 1956-10-24 | 1961-10-17 | Ethyl Corp | Antiknock compositions |
US2890947A (en) * | 1956-11-14 | 1959-06-16 | Pure Oil Co | Gasoline motor fuel |
US2999740A (en) * | 1956-11-27 | 1961-09-12 | Tidewater Oil Company | Surface ignition suppression |
US3052531A (en) * | 1957-02-01 | 1962-09-04 | Shell Oil Co | Fuel composition |
US3009790A (en) * | 1957-04-05 | 1961-11-21 | Gulf Research Development Co | Fuel for spark ignition engines |
US3034877A (en) * | 1957-08-05 | 1962-05-15 | Exxon Research Engineering Co | Leaded gasolines |
US3047372A (en) * | 1957-11-29 | 1962-07-31 | Exxon Research Engineering Co | Anti-knock gasoline |
US3007783A (en) * | 1958-11-18 | 1961-11-07 | Atlantic Refining Co | Motor fuel compositions |
US3038791A (en) * | 1959-07-16 | 1962-06-12 | Ethyl Corp | Phenyl phosphate compositions |
US3056667A (en) * | 1959-09-02 | 1962-10-02 | Sinclair Research Inc | Leaded gasoline containing phosphorus and phosphate |
US3356471A (en) * | 1963-08-09 | 1967-12-05 | Du Pont | Triaryl phosphate mixtures |
Also Published As
Publication number | Publication date |
---|---|
BE500535A (en) | 1900-01-01 |
CY106A (en) | 1954-01-07 |
NL89156C (en) | 1900-01-01 |
MY5400001A (en) | 1954-12-31 |
FR1031830A (en) | 1953-06-26 |
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