GB659395A - Manufacture of new three-phase emulsions of artificial resins - Google Patents

Manufacture of new three-phase emulsions of artificial resins

Info

Publication number
GB659395A
GB659395A GB31135/48A GB3113548A GB659395A GB 659395 A GB659395 A GB 659395A GB 31135/48 A GB31135/48 A GB 31135/48A GB 3113548 A GB3113548 A GB 3113548A GB 659395 A GB659395 A GB 659395A
Authority
GB
United Kingdom
Prior art keywords
phase
formaldehyde
urea
water
forming
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB31135/48A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
Original Assignee
Ciba AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba AG filed Critical Ciba AG
Publication of GB659395A publication Critical patent/GB659395A/en
Expired legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Phenolic Resins Or Amino Resins (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Three phase emulsions of artificial resins suitable for improving textiles are formed by incorporating a second internal oily phase consisting of a water immiscible organic liquid having a boiling point between 100 DEG and 200 DEG C., in a two-phase emulsion such as is described in Specification 645,023, wherein the external aqueous phase consists of a solution which contains in addition to at least one protein, urea, thiourea or a mixture thereof, and the internal oily phase consists of a solution in a water immiscible organic solvent of a water-insoluble hardenable condensate of formaldehyde with a substance of amide character capable of forming a hardenable aminoplast with formaldehyde and a water-immiscible alcohol. Organic liquids forming the second internal oily phase may be extraction benzine or heavy benzine, lacquer benzine or "Sangajol" (Registered Trade Mark), which have no solvent action on carbamide resins of the urea series, and also benzene, chlorobenzene, toluene, xylene, solvent naphtha, dipentene, turpentine, trichlorethylene or "Tetralin" (Registered Trade Mark). These liquids are preferably added gradually to the diluted two-phase emulsion. Substances suitable for improving textile materials such as pigments, matting, emulsifying, antifoaming, softening or hardening agents or polymeric compounds may be added to the aqueous protein solution forming the external phase or to the artificial resin lacquer forming the primary disperse phase ligments specified in examples are titanium white, iron oxide, gas black, copper phthalocyanine, Indanthrene blue, and the reaction product of diazotized 2,5-dichloraniline with 2,3-oxynaphthoic acid-21-anisidide and that of diazotized 2-amino-5-chlorotoluene with 2,3-oxynaphthoic acid-41-chloro-21-methyl anisidide. Additional ingredients to the casein or gelatine of the aqueous phase may be borax, ammonium formate and carbonate, ammonia, sodium hydroxide, sulphonated castor oil, triethanolamine, ethylene glycol, glycerine and sodium lauryl sulphate. Urea formaldehyde butanol, urea thiourea formaldehyde cyclohexanol and melamine resin etherified with butanol are specified. Specifications 544,157 and 597,390 are referred to.ALSO:Three-phase emulsions of artificial resins suitable for dyeing and improving textiles are formed by incorporating a second internal oily phase consisting of a water-immiscible organic liquid having a boiling point between 100 DEG and 200 DEG C. in a two-phase emulsion such as is described in Specification 645,023, wherein the external aqueous phase consists of a solution which contains in addition to at least one protein, urea, thiourea or a mixture thereof, and the internal oily phase consits of a solution in a water-immiscible organic solvent of a water-insoluble hardenable condensate of formaldehyde with a substance of amide character capable of forming a hardenable aminoplast with formaldehyde and a water-immiscible alcohol. Organic liquids forming the second internal oily phase may be extraction-, lacquer-, or heavy benzine, or "Sangajol" (Registered Trade Mark), which have no solvent action on carbamide resins of the urea series, and also benzene, chlorobenzene, toluene, xylene, solvent naphtha, dipentene, turpentine, trichlorethylene or "Tetralin" (Registered Trade Mark). These liquids are preferably added gradually to the diluted two-phase emulsion. Substances suitable for improving textiles such as pigments, matting, emulsifying, anti-foaming, softening or hardening agents or polymeric compounds may be added to the aqueous protein solution forming the external phase or to the artificial resin lacquer forming the primary disperse phase. Pigments specified are titanium white, iron oxide, gas black, copper phthalocyanine, Indanthrene blue, and the reaction product of diazotized 2,5-dichloraniline with 2,3-oxynaphthoic acid-21-anisidide and that of diazotized 2-amino-5-chlorotoluene with 2,3-oxynaphthoic acid - 41 - chloro - 21 - methyl anisidide. Additional ingredients to the casein or gelatine of the aqueous phase may be borax, ammonium formate and carbonate, ammonia, sodium hydroxide, sulphonated castor oil, triethanolamine, ethylene glycol, glycerine and sodium lauryl sulphate. Urea-formaldehyde-butanols, urea-thiourea-formaldehyde-cyclohexanol and melamine resin etherified with butanol are specified. Specifications 544,157 and 597,390 are referred to.ALSO:Three-phase emulsions of artificial resins suitable for dyeing and improving textiles are formed by incorporating a second internal oily phase consisting of a water-immiscible organic liquid having a boiling-point between 100 DEG and 200 DEG C. in a two-phase emulsion such as described in Specification 645,023, wherein the external aqueous phase consists of a solution which contains in addition to one protein, urea, thiourea or a mixture thereof, and the internal oily phase consists of a solution in a water-immiscible organic solvent of a water-insoluble hardenable condensate of formaldehyde with a substance of amide character capable of forming a hardenable aminoplast with formaldehyde and a water-immiscible alcohol. Organic liquids forming the second internal oily phase may be extraction benzine, heavy benzine, lacquer benzine or "Sangajol" (Registered Trade Mark) which have no solvent action on carbamide resins of the urea series, and also benzene, chlorobenzene, toluene, xylene, solvent naphtha, dipentene, turpentine, trichlorethylene or "Tetralin" (Registered Trade Mark). These liquids are preferably added gradually to the diluted two-phase emulsion. Pigments, matting, emulsifying, antifoaming, softening or hardening agents or polymeric compounds may be added to the aqueous protein solution forming the external aqueous phase or to the artificial resin lacquer forming the primary disperse phase. Pigments specified in examples are titanium white, iron oxide, gas black, copper phthalocyanine, indanthrene blue, and the reaction product of diazotized 2,5-dichloraniline with 2,3-oxynaphthoic acid-21-anisidide and that of diazotized 2-amino-5-chlorotoluene with 2,3 - oxynaphthoic acid - 41 - chloro - 21 - methyl anisidide. Additional ingredients to the casein or gelatine of the aqueous phase may be borax, ammonium formate and carbonate, ammonia, sodium hydroxide, sulphonated castor oil, triethanolamine, ethylene glycol, glycerine and sodium lauryl sulphate. Urea-formaldehyde butanol, urea-thiourea-formaldehyde cyclohexanol and melamine resin etherified with butanol are specified. Specifications 544,157 and 597,390, [Group IV], are also referred to.
GB31135/48A 1947-12-24 1948-12-01 Manufacture of new three-phase emulsions of artificial resins Expired GB659395A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CH659395X 1947-12-24

Publications (1)

Publication Number Publication Date
GB659395A true GB659395A (en) 1951-10-24

Family

ID=4526759

Family Applications (1)

Application Number Title Priority Date Filing Date
GB31135/48A Expired GB659395A (en) 1947-12-24 1948-12-01 Manufacture of new three-phase emulsions of artificial resins

Country Status (1)

Country Link
GB (1) GB659395A (en)

Similar Documents

Publication Publication Date Title
US3310416A (en) Aqueous dispersions
GB1065961A (en) A new reactive coloring matter,processes for producing the same and processes for coloring articles with the same
JPS565358A (en) Manufacture of colored fog-resistent product
US2494810A (en) Pigment emulsions and the manufacture thereof
US3320197A (en) Process of producing concentrated aqueous emulsions of water-insoluble substances and emulsions produced by such process
US2473798A (en) Nonionic surface active agent
GB659395A (en) Manufacture of new three-phase emulsions of artificial resins
GB645023A (en) New stable emulsions of artificial resins and processes for making them
US2680101A (en) Stable artificial resin emulsions and process of making same utilizing reaction product of a protein
US2986542A (en) Pigmented artificial resin lacquers dispersible in aqueous media and process for their manufacture
GB1067666A (en) Fine particle production
US2334107A (en) Textile finishing
US2585967A (en) Water dispersible dry preparations of hardenable binding agents
US3565846A (en) Agent for making textiles crease proof and textiles treated by such agent
US2500122A (en) Emulsions
US1871087A (en) Production of effects on textiles
US3017377A (en) Extender composition for textile printing pastes containing reaction product of monoethanolamine solution and the co-polymer of unhydrolyzed methyl vinyl ether and maleic anhydride
US2498454A (en) Hardenable emulsion serving as binding agent and process of making same
CA1177592A (en) Mixtures of reaction products based on epoxides, primary amines and fatty acids and of aminoplast precondensates, their preparation and their use as leather dressings
GB809504A (en) Process for the manufacture of emulsions of hardenable artificial resins and emulsions so obtained
US2413755A (en) Condensation product of ammelines with alkylene oxides
GB364104A (en) Improvements in the manufacture and production of wetting, cleansing and dispersing agents
US3472605A (en) Process for dyeing or printing leather
US2376595A (en) Textile finishing composition
GB602886A (en) Improvements in and relating to pigment emulsions, the manufacture thereof and the dyeing of fabrics therewith