GB649975A - Improvements in and relating to adhesive materials - Google Patents

Improvements in and relating to adhesive materials

Info

Publication number
GB649975A
GB649975A GB15562/47A GB1556247A GB649975A GB 649975 A GB649975 A GB 649975A GB 15562/47 A GB15562/47 A GB 15562/47A GB 1556247 A GB1556247 A GB 1556247A GB 649975 A GB649975 A GB 649975A
Authority
GB
United Kingdom
Prior art keywords
parts
lead
oxide
rosin
zinc
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB15562/47A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Johnson and Johnson Great Britain Ltd
Original Assignee
Johnson and Johnson Great Britain Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Johnson and Johnson Great Britain Ltd filed Critical Johnson and Johnson Great Britain Ltd
Publication of GB649975A publication Critical patent/GB649975A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08CTREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00Chemical modification of rubber

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

An adhesive material is made by chemically bonding a major proportion of a vulcanizable rubber with a minor proportion of a heat reactive "A" stage resin obtained by reacting a para-substituted hydroxy phenol with an aldehyde or ketone, the bonding being effected by treatment at such an elevated temperature for such time that the mass assumes a swelling volume, as defined in the Specification between 20 and 36, the reaction then being terminated so that the product is stabilized in a soft flexible and substantially non-stringy state. The rubber may be natural rubber, polyisoprene polychloroprene, or a copolymer of isobutylene such as butyl rubber, or a copolymer of butadiene with styrene, methacrylate, acrylate or acrylonitrile. The phenol is preferably substituted by an ethyl, propyl, butyl, amyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, phenyl, menthyl or ethyl benzene group. Specified resins are those known under the Registered Trade Marks "Durez" 202 and "Bakelite" BR 14634; and also "Amberol" St. 137. The nature of the product may be modified by the addition of fillers such as zinc oxide, aluminium oxide, titanium dioxide and calcium carbonate; by tackifying resins such as rosin, dehydrated rosin, hydrogenated rosin, their glycol, polyglycol and glycerol esters, their penta-erithritol esters and maleic alkyd modifications; polypinenes, coumarone-indene resins, hydrogenated coumarone indene resins and polyisobutylene; and also accelerators and modifiers such as metal compound acids, strong oxidizing agents, copper oleate and other copper compounds, lime and other calcium compounds, lead acetate, lead oxide, lead dioxide, and other lead compounds, magnesium oxide and other magnesium derivatives, zinc, zinc oxide and other zinc derivatives, lauryl peroxide, phosphoric pentoxide, lecithin or triethylamine; plasticizers such as petroleum oils, soft waxes and high boiling esters such as methyl abietate; and solvents such as naphtha, xylene, benzene or toluene. In example I, which is typical of many, 100 parts of GR-S and 100 parts of zinc oxide are mixed on a Banbury mixer and then 75 parts of the glyceride of hydrogenated rosin added and then the mixture steam heated on reaching 270 DEG F., 10 parts of para tertiary amyl phenol formaldehyde condensation product are added and heating continued until the required swelling volume is reached. 33 parts of a petroleum hydrocarbon oil and 2 parts of an antioxidant such as an alkylated polyhydroxy phenol are added and then the mixture thinned with an organic solvent.ALSO:An adhesive material is made by chemically bonding a major proportion of a vulcanizable rubber with a minor proportion of a heat reactive para-substituted hydroxy phenyl carbinol, the bonding being effected by treatment at such an elevated temperature for such time that the mass assumes a swelling volume, as defined in the Specification between 20 and 36, the reaction then being terminated so that the product is stabilized in a soft flexible and substantially non-stringy state. The rubber may be natural rubber, polyisoprene, polychloroprene, or a copolymer of isobutylene such as butyl rubber, or a copolymer of butadiene with styrene, methacrylate, acrylate or acrylonitrile. The phenol is preferably substituted by an ethyl, propyl, butyl, amyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, phenyl, menthyl or ethyl benzene group, and is then treated preferably with formaldehyde to produce an "A" stage resin. Specified resins are those known under the Registered Trade Marks "Durez" 202 and "Bakelite" BR 14634; and also "Amberol" St. 137. The nature of the product may be modified by the addition of fillers such as zinc oxide, aluminium oxide, titanium dioxide and calcium carbonate; by tackifying resins such as rosin, dehydrated rosin, hydrogenated rosin, their glycol, polyglycol and glycerol esters, their penta-erithritol esters and maleic alkyd modifications; polypinenes, coumarone - indene resins, hydrogenated coumarone indene resins and polyisobutylene; and also accelerators and modifiers such as metal compounds, acids, strong oxidizing agents, copper oleate and other copper compounds, lime and other calcium compounds, lead acetate, lead oxide, lead dioxide, and other lead compounds, magnesium oxide and other magnesium derivatives, zinc, zinc oxide and other zinc derivatives, lauryl peroxide, phosphoric pentoxide, lecithin or triethylamine; plasticizers such as petroleum oils, soft waxes and high boiling esters such as methyl abietate; and solvents such as naphtha, xylene, benzene or toluene. In example I, which is typical of many, 100 parts of GR-S and 100 parts of zinc oxide are mixed on a Banbury mixer and then 75 parts of the glyceride of hydrogenated rosin added and then the mixture steam heated, on reaching 270 DEG F., 10 parts of para tertiary amyl phenol formaldehyde condensation product are added and heating continued until the required swelling volume is reached. 33 parts of a petroleum hydrocarbon oil and 2 parts of an antioxidant such as an alkylated polyhydroxy phenol are added and then the mixture thinned with an organic solvent.
GB15562/47A 1946-08-01 1947-06-12 Improvements in and relating to adhesive materials Expired GB649975A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US649975XA 1946-08-01 1946-08-01

Publications (1)

Publication Number Publication Date
GB649975A true GB649975A (en) 1951-02-07

Family

ID=22059644

Family Applications (1)

Application Number Title Priority Date Filing Date
GB15562/47A Expired GB649975A (en) 1946-08-01 1947-06-12 Improvements in and relating to adhesive materials

Country Status (1)

Country Link
GB (1) GB649975A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2702286A (en) * 1952-08-09 1955-02-15 Us Rubber Co Rubber treatment
US2702287A (en) * 1952-01-12 1955-02-15 Us Rubber Co Rubber treatment
US2963387A (en) * 1957-12-24 1960-12-06 Johnson & Johnson Pressure-sensitive adhesive tape and method of manufacture
US3325430A (en) * 1965-10-22 1967-06-13 Shell Oil Co Calking and sealing composition containing block copolymers

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2702287A (en) * 1952-01-12 1955-02-15 Us Rubber Co Rubber treatment
US2702286A (en) * 1952-08-09 1955-02-15 Us Rubber Co Rubber treatment
US2963387A (en) * 1957-12-24 1960-12-06 Johnson & Johnson Pressure-sensitive adhesive tape and method of manufacture
US3325430A (en) * 1965-10-22 1967-06-13 Shell Oil Co Calking and sealing composition containing block copolymers

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