GB644291A - Improvements in or relating to normally tacky and pressure-sensitive eucohesive adhesive and method of preparing the same, and the improved adhesive tape employing the improved adhesive - Google Patents
Improvements in or relating to normally tacky and pressure-sensitive eucohesive adhesive and method of preparing the same, and the improved adhesive tape employing the improved adhesiveInfo
- Publication number
- GB644291A GB644291A GB20138/46A GB2013846A GB644291A GB 644291 A GB644291 A GB 644291A GB 20138/46 A GB20138/46 A GB 20138/46A GB 2013846 A GB2013846 A GB 2013846A GB 644291 A GB644291 A GB 644291A
- Authority
- GB
- United Kingdom
- Prior art keywords
- parts
- resin
- phenol
- resinate
- tert
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J129/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Adhesives based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Adhesives based on derivatives of such polymers
- C09J129/10—Homopolymers or copolymers of unsaturated ethers
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L11/00—Machines for cleaning floors, carpets, furniture, walls, or wall coverings
- A47L11/02—Floor surfacing or polishing machines
- A47L11/10—Floor surfacing or polishing machines motor-driven
- A47L11/14—Floor surfacing or polishing machines motor-driven with rotating tools
- A47L11/16—Floor surfacing or polishing machines motor-driven with rotating tools the tools being disc brushes
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L11/00—Machines for cleaning floors, carpets, furniture, walls, or wall coverings
- A47L11/40—Parts or details of machines not provided for in groups A47L11/02 - A47L11/38, or not restricted to one of these groups, e.g. handles, arrangements of switches, skirts, buffers, levers
- A47L11/4036—Parts or details of the surface treating tools
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
- C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/14—Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Constituent Portions Of Griding Lathes, Driving, Sensing And Control (AREA)
- Brushes (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
Pressure sensitive tacky adhesive compositions comprise 100 parts of a synthetic rubbery polymer consisting of acrylate ester, vinyl ester and vinyl ether polymers having side chains of at least 4 carbon atoms linked to individual carbon atoms through an oxygen atom, and 2-15 parts of a compatible, oil-soluble heat-and-oil-reactive phenol-aldehyde resin. Up to 16 parts of a resinous tackifier, e.g. zinc resinate, rosin, ester gum, hydrogenated rosin terpene resin, may be added. Polymers specified are those obtained by polymerizing (1) 75 parts 2-ethylbutyl acrylate and 25 parts ethyl acrylate in aqueous solution and hardening with alum; (2) 425 parts vinyl butyrate and 2.13 parts di-isoamyl ethylene dimaleate in solution in 425 parts tert.-butyl alcohol with benzoyl peroxide as catalyst; (3) vinyl-n-butyl ether. The oil-soluble reactive phenol-aldehydes are obtained by reacting substituted phenols, e.g. p-tert.-amyl, p-tert.-butyl and p-phenyl phenols with formaldehyde, e.g. 1345 parts p-tert.-amyl-phenol are added to a cooled solution of 130 parts NaOH, 200 parts water and 1300 parts 37 per cent formaldehyde and the mixture reacted with gentle heating until the free formaldehyde is reduced to 1 per cent. The pH is then brought to 1-2 by addition of acid and the resin separated from the aqueous phase, washed and distilled under vacuum until a brittle resin is obtained. The following compositions are given: (1) 100 parts acrylate polymer, 5 parts TiO2, 5 parts phenol-aldehyde resin, 10 parts ester gum, 1 part Zn resinate, 300 parts heptane, 6 parts ethyl alcohol; (2) 84 parts cross-linked polyvinyl butyrate, 4.2 parts phenol resin, 2.5 parts Zn resinate; (3) 100 parts polyvinyl-n-butyl ether, 7.5 parts "Bakelite" (Registered Trade Mark) resin, 4 parts "Zitro" resin (pale Zn resinate), 450 parts toluol. The adhesives may be used for coating "Cellophane" (Registered Trade Mark) tape. The Specification as open to inspection under Sect. 91 included any synthetic rubbery polymer having active hydrogen groups, as shown by the following examples (Cancelled): (1) butadiene-styrene copolymer, ZnO, TiO2, and yellow pigment, ester gum, terpene resin, oil-soluble phenol-aldehyde resin, and heptane; (2) butadiene-isobutylene copolymer, terpene resin, hydrogenated methyl abietate, phenol resin and heptane; (5) as in (1) the terpene resin being replaced by a coumarone-indene resin; (7) and (8) polymerized chloroprene and polymerized methyl pentadiene, respectively, as the synthetic rubber. This subject-matter does not appear in the Specification as accepted.ALSO:Pressure-sensitive tacky adhesive compositions comprise 100 parts of a synthetic rubbery polymer consisting of acrylate ester, vinyl ester and vinyl ether polymers having side chains of at least 4 carbon atoms linked to individual carbon atoms through an oxygen atom, and 2-15 parts of a compatible, oil soluble heat-and-oil-reactive phenol-aldehyde resin. Up to 16 parts of a resinous tackifier, e.g. zinc resinate, rosin, estergum, hydrogenated rosin, terpene resin, may be added. Polymers specified are those obtained by copolymerizing (1) 75 parts 2-ethylbutyl acrylate and 25 parts ethyl acrylate in aqueous solution and hardening with alum; (2) 425 parts vinyl butyrate and 2.13 parts di-isoamyl ethylene dimaleate in solution in 425 parts tert-butyl alcohol with benzoyl peroxide as catalyst, and (3) vinyl-n-butyl ether. The oil soluble reactive phenol-aldehydes are obtained by reacting substituted phenols, e.g. p-tertamyl, p-tert-butyl and p-phenyl phenols with formaldehyde, e.g. 1345 parts p-tert-amylphenol are added to a cooled solution of 130 parts NaOH, 200 parts water and 1300 parts 37 per cent formaldehyde and the mixture reacted with gentle heating until the free formaldehyde is reduced to 1 per cent. The pH is then brought to 1-2 by addition of acid and the resin separated from the aqueous phase, washed and distilled under vacuum until a brittle resin is obtained. The following compositions are given: (1) 100 parts acrylate polymer, 5 parts TiO2, 5 parts phenolaldehyde resin, 10 parts ester gum, 1 part Zn resinate, 300 parts heptane, 6 parts ethyl alcohol; (2) 84 parts cross-linked polyvinyl butyrate, 4.2 parts phenol resin, 2.5 parts Zn resinate; (3) 100 parts polyvinyl-n-butyl ether, 7.5 parts "Bakelite" (Registered Trade Mark) resin, 4 parts "Zitro" (Registered Trade Mark) resin (pale Zn resinate), 450 parts toluol; the adhesives may be used for coating "Cellophane" (Registered Trade Mark) tape. The Specification as open to inspection under Sect. 91 included any synthetic rubbery polymer having active hydrogen groups as shown in the following examples (Cancelled): (1) butadiene-styrene, copolymer, ZnO, TiO2, and yellow pigment, ester gum, terpene resin, oil soluble phenol-aldehyde resin, and heptane; (2) butadiene-isobutylene copolymer, terpene resin, hydrogenated methyl abietate, phenol resin and heptane; (5) as in (1), the terpene resin being replaced by a coumarone-indene resin; (7 and 8) specify polymerized chloroprene and polymerized methyl pentadiene respectively as the synthetic rubber. This subject-matter does not appear in the Specification as accepted.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US644291XA | 1945-04-19 | 1945-04-19 | |
GB5591/62A GB938316A (en) | 1945-04-19 | 1962-02-14 | Improvements in or relating to floor treating machines |
Publications (1)
Publication Number | Publication Date |
---|---|
GB644291A true GB644291A (en) | 1950-10-11 |
Family
ID=26240009
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB20138/46A Expired GB644291A (en) | 1945-04-19 | 1946-07-05 | Improvements in or relating to normally tacky and pressure-sensitive eucohesive adhesive and method of preparing the same, and the improved adhesive tape employing the improved adhesive |
GB5591/62A Expired GB938316A (en) | 1945-04-19 | 1962-02-14 | Improvements in or relating to floor treating machines |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB5591/62A Expired GB938316A (en) | 1945-04-19 | 1962-02-14 | Improvements in or relating to floor treating machines |
Country Status (1)
Country | Link |
---|---|
GB (2) | GB644291A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2965592A (en) * | 1958-03-10 | 1960-12-20 | Minnesota Mining & Mfg | Pressure-sensitive tape adhesives |
EP1090971A1 (en) * | 1999-10-08 | 2001-04-11 | Dai Nippon Printing Co., Ltd. | Pressure-sensitive adhesive |
US7750105B2 (en) | 2003-09-04 | 2010-07-06 | Arizona Chemical Company | Resins and adhesive formulations therewith |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4542551A (en) * | 1983-09-30 | 1985-09-24 | Mcgraw-Edison Company | Rotary floor maintenance device |
ES1024815Y (en) * | 1993-05-04 | 1994-06-01 | Cortes Vicente Martinez | MULTIPURPOSE MACHINE FOR TREATMENT OF FLOORS, WALLS AND CEILINGS. |
-
1946
- 1946-07-05 GB GB20138/46A patent/GB644291A/en not_active Expired
-
1962
- 1962-02-14 GB GB5591/62A patent/GB938316A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2965592A (en) * | 1958-03-10 | 1960-12-20 | Minnesota Mining & Mfg | Pressure-sensitive tape adhesives |
EP1090971A1 (en) * | 1999-10-08 | 2001-04-11 | Dai Nippon Printing Co., Ltd. | Pressure-sensitive adhesive |
US6509076B1 (en) | 1999-10-08 | 2003-01-21 | Dai Nippon Printing Co., Ltd. | Pressure-sensitive adhesive for pressure-sensitive adhesive layer in volume hologram laminate |
US7750105B2 (en) | 2003-09-04 | 2010-07-06 | Arizona Chemical Company | Resins and adhesive formulations therewith |
Also Published As
Publication number | Publication date |
---|---|
GB938316A (en) | 1963-10-02 |
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