GB636885A - Photographic emulsions - Google Patents

Photographic emulsions

Info

Publication number
GB636885A
GB636885A GB36167/46A GB3616746A GB636885A GB 636885 A GB636885 A GB 636885A GB 36167/46 A GB36167/46 A GB 36167/46A GB 3616746 A GB3616746 A GB 3616746A GB 636885 A GB636885 A GB 636885A
Authority
GB
United Kingdom
Prior art keywords
triethylamine
acetanilidovinyl
nucleus
ethiodide
substituent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB36167/46A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GAF Chemicals Corp
Original Assignee
General Aniline and Film Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by General Aniline and Film Corp filed Critical General Aniline and Film Corp
Publication of GB636885A publication Critical patent/GB636885A/en
Expired legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03CPHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00Photosensitive materials
    • G03C1/005Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
    • G03C1/06Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
    • G03C1/08Sensitivity-increasing substances
    • G03C1/10Organic substances
    • G03C1/12Methine and polymethine dyes
    • G03C1/22Methine and polymethine dyes with an even number of CH groups

Landscapes

  • Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Physics & Mathematics (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Thiazole And Isothizaole Compounds (AREA)
  • Silver Salt Photography Or Processing Solution Therefor (AREA)

Abstract

636,885. Sensitized photographic emulsions. GENERAL ANILINE & FILM CORPORATION. Dec. 6, 1946, No. 36167. Convention date, Dec. 7, 1945. [Class 98 (ii)] Photographic silver halide emulsions are sensitized with cyanine dyes containing the nucleus wherein Z represents the non-metallic atoms to complete a heterocyclic nucleus, e.g. a thiazoline, selenazoline, hexahydrobenzthiazoline, 3-phenylpyrazolone, pyridine, quinoline, or thiazine nucleus. The nucleus may be derived from 2 - aminothiazoline, 2 - aminoselenazoline, 2 - aminodihydrothiazine, 2 - amino- 5 - methylthiazoline, 2 - amino - 4 - phenylthiazoline, 2 - aminohexahydrobenzthiazole, 3 - phenyl - 5 - aminopyrazolone, and 2 - aminopyridine, and may be condensed with (a) a cyclammonium quaternary salt having in the 2- or 4-position, an iodo, cyano, or aryl- or alkyl-mercapto substituent ; (b) a heterocyclic compound having in the 2- or 4-position an acetanilidomethylene substituent, or (c) a cyclammonium quaternary salt having in the 2- or 4-position a #-anilinovinyl, #-acetanilidovinyl, a group having a #-aldehyde substituent, acetylmethylene, #-alkylmercaptovinyl, or #- alkylmercapto-#-alkylvinyl substituent. Alternatively, a reactive derivative, e.g. an acetanilidomethylene derivative of the nucleus may be condensed with a cyclammonium quaternary salt having a methyl group in the 2- or 4-position. A condensing agent such as acetic, propionic, or butyric anhydride ; triethyl, tributyl, or triethanol amine ; N- methylpiperidine ; pyridine ; sodium or potassium acetate ; or sodium ethylate or propionate may be used. In examples : dyes are formed by refluxing together (1) thiazolopyrimidinedione, 2 - (# - acetanilidovinyl) - 6- methylbenzthiazole ethiodide, isopropyl alcohol, and triethylamine ; (2) thiazolopyrimidinedione, 2 - (# - acetanilidovinyl) - benzthiazoleethiodide, isopropyl alcohol, and triethylamine; (3) phenylthiazolopyrimidinedione, 2 - (#- methylmercapto - # - ethylvinyl) - 6 - methoxybenzselenazole ethiodide, n-propyl alcohol, and triethylamine ; (4) thiazinopyrimidinedione, 2 - (# - acetanilidovinyl) - 6 - methoxybenzselenazole ethiodide, n-propylalcohol, and triethylamine ; (5) hexahydrobenzthiazolopyrimidinedione, 2 - (# - acetanilidovinyl) - benzthiazole ethiodide, isopropyl alcohol, and triethylamine ; (6) methylthiazolopyrimidinedione, 2 - (# . acetanilidovinyl) - benzoxazole ethiodide, isopropyl alcohol, and triethylamine ; and (7) thiazinopyrimidinedione, 2-thio-3-ethyl- 5-acetanilidomethylene dihydrothiazolidone-4, pyridine, and triethylamine.
GB36167/46A 1945-12-07 1946-12-06 Photographic emulsions Expired GB636885A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US633539A US2464780A (en) 1945-12-07 1945-12-07 Dye-sensitized photographic silver halide emulsion

Publications (1)

Publication Number Publication Date
GB636885A true GB636885A (en) 1950-05-10

Family

ID=24540037

Family Applications (1)

Application Number Title Priority Date Filing Date
GB36167/46A Expired GB636885A (en) 1945-12-07 1946-12-06 Photographic emulsions

Country Status (3)

Country Link
US (1) US2464780A (en)
FR (1) FR946452A (en)
GB (1) GB636885A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3249433A (en) * 1957-01-22 1966-05-03 Polaroid Corp Process for preparing a photosensitive element and process of using same in a diffusion transfer method

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE519979A (en) * 1952-05-15
US3033681A (en) * 1959-01-19 1962-05-08 Eastman Kodak Co Merocyanine sensitizing dyes and sensitized photographic emulsions
US3072485A (en) * 1960-08-24 1963-01-08 Eastman Kodak Co Optically sensitized azido polymers for photomechanical resist compositions
US3528811A (en) * 1967-05-17 1970-09-15 Eastman Kodak Co Photographic emulsions containing a pyrimidinedione and a desensitizing nucleus linked by a dimethine or a double bond
DE2833137A1 (en) * 1978-07-28 1980-02-07 Agfa Gevaert Ag LIGHT SENSITIVE PHOTOGRAPHIC RECORDING MATERIAL
US4529727A (en) * 1982-04-21 1985-07-16 Janssen Pharmaceutical, N.V. Pyrimido[2,1-b][1,3]-thiazines

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2170805A (en) * 1937-04-24 1939-08-29 Eastman Kodak Co Photographic emulsion containing dyes from benzoxazoles
US2170807A (en) * 1938-02-25 1939-08-29 Eastman Kodak Co Merocyanine dyes from barbituric acids

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3249433A (en) * 1957-01-22 1966-05-03 Polaroid Corp Process for preparing a photosensitive element and process of using same in a diffusion transfer method

Also Published As

Publication number Publication date
FR946452A (en) 1949-06-03
US2464780A (en) 1949-03-22

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