GB635645A - Production of organohalosilanes - Google Patents
Production of organohalosilanesInfo
- Publication number
- GB635645A GB635645A GB3207347A GB3207347A GB635645A GB 635645 A GB635645 A GB 635645A GB 3207347 A GB3207347 A GB 3207347A GB 3207347 A GB3207347 A GB 3207347A GB 635645 A GB635645 A GB 635645A
- Authority
- GB
- United Kingdom
- Prior art keywords
- halogen
- mixture
- bonded
- trichlorosilyl
- trichlorosilane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 abstract 4
- 125000004432 carbon atom Chemical group C* 0.000 abstract 3
- 229910052736 halogen Inorganic materials 0.000 abstract 3
- 125000005843 halogen group Chemical group 0.000 abstract 3
- GBDZXPJXOMHESU-UHFFFAOYSA-N 1,2,3,4-tetrachlorobenzene Chemical class ClC1=CC=C(Cl)C(Cl)=C1Cl GBDZXPJXOMHESU-UHFFFAOYSA-N 0.000 abstract 2
- -1 aromatic halohydrocarbon Chemical class 0.000 abstract 2
- 229910052799 carbon Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical class 0.000 abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 2
- 125000001424 substituent group Chemical group 0.000 abstract 2
- ZDHXKXAHOVTTAH-UHFFFAOYSA-N trichlorosilane Chemical compound Cl[SiH](Cl)Cl ZDHXKXAHOVTTAH-UHFFFAOYSA-N 0.000 abstract 2
- 239000005052 trichlorosilane Substances 0.000 abstract 2
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 abstract 1
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 abstract 1
- CVGAWKYSRYXQOI-UHFFFAOYSA-N 1-chloro-2-ethylbenzene Chemical class CCC1=CC=CC=C1Cl CVGAWKYSRYXQOI-UHFFFAOYSA-N 0.000 abstract 1
- RNEMUWDQJSRDMQ-UHFFFAOYSA-N 1-chloro-2-propan-2-ylbenzene Chemical class CC(C)C1=CC=CC=C1Cl RNEMUWDQJSRDMQ-UHFFFAOYSA-N 0.000 abstract 1
- JTPNRXUCIXHOKM-UHFFFAOYSA-N 1-chloronaphthalene Chemical class C1=CC=C2C(Cl)=CC=CC2=C1 JTPNRXUCIXHOKM-UHFFFAOYSA-N 0.000 abstract 1
- LAXBNTIAOJWAOP-UHFFFAOYSA-N 2-chlorobiphenyl Chemical group ClC1=CC=CC=C1C1=CC=CC=C1 LAXBNTIAOJWAOP-UHFFFAOYSA-N 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 150000001555 benzenes Chemical class 0.000 abstract 1
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- KTQYJQFGNYHXMB-UHFFFAOYSA-N dichloro(methyl)silicon Chemical compound C[Si](Cl)Cl KTQYJQFGNYHXMB-UHFFFAOYSA-N 0.000 abstract 1
- VIRVTHOOZABTPR-UHFFFAOYSA-N dichloro(phenyl)silane Chemical compound Cl[SiH](Cl)C1=CC=CC=C1 VIRVTHOOZABTPR-UHFFFAOYSA-N 0.000 abstract 1
- GNEPOXWQWFSSOU-UHFFFAOYSA-N dichloro-methyl-phenylsilane Chemical compound C[Si](Cl)(Cl)C1=CC=CC=C1 GNEPOXWQWFSSOU-UHFFFAOYSA-N 0.000 abstract 1
- 150000003961 organosilicon compounds Chemical class 0.000 abstract 1
- 239000005054 phenyltrichlorosilane Substances 0.000 abstract 1
- 239000000376 reactant Substances 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- BWDBLAMROGJFCZ-UHFFFAOYSA-N trichloro(naphthalen-2-yl)silane Chemical compound C1=CC=CC2=CC([Si](Cl)(Cl)Cl)=CC=C21 BWDBLAMROGJFCZ-UHFFFAOYSA-N 0.000 abstract 1
- ORVMIVQULIKXCP-UHFFFAOYSA-N trichloro(phenyl)silane Chemical compound Cl[Si](Cl)(Cl)C1=CC=CC=C1 ORVMIVQULIKXCP-UHFFFAOYSA-N 0.000 abstract 1
- RWYIWQMTXDOSMW-UHFFFAOYSA-N trichloro-(1-trichlorosilylnaphthalen-2-yl)silane Chemical class Cl[Si](Cl)(Cl)c1ccc2ccccc2c1[Si](Cl)(Cl)Cl RWYIWQMTXDOSMW-UHFFFAOYSA-N 0.000 abstract 1
- DYQGNYIZMOCOFA-UHFFFAOYSA-N trichloro-(2-trichlorosilylphenyl)silane Chemical class Cl[Si](Cl)(Cl)C1=CC=CC=C1[Si](Cl)(Cl)Cl DYQGNYIZMOCOFA-UHFFFAOYSA-N 0.000 abstract 1
- ABADVTXFGWCNBV-UHFFFAOYSA-N trichloro-(4-chlorophenyl)silane Chemical class ClC1=CC=C([Si](Cl)(Cl)Cl)C=C1 ABADVTXFGWCNBV-UHFFFAOYSA-N 0.000 abstract 1
- FHQLGFOMDWZFNR-UHFFFAOYSA-N trichloro-(4-ethylphenyl)silane Chemical class CCC1=CC=C([Si](Cl)(Cl)Cl)C=C1 FHQLGFOMDWZFNR-UHFFFAOYSA-N 0.000 abstract 1
- WOMUGKOOLXQCTQ-UHFFFAOYSA-N trichloro-(4-methylphenyl)silane Chemical class CC1=CC=C([Si](Cl)(Cl)Cl)C=C1 WOMUGKOOLXQCTQ-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/02—Silicon compounds
- C07F7/08—Compounds having one or more C—Si linkages
- C07F7/12—Organo silicon halides
- C07F7/121—Preparation or treatment not provided for in C07F7/14, C07F7/16 or C07F7/20
- C07F7/122—Preparation or treatment not provided for in C07F7/14, C07F7/16 or C07F7/20 by reactions involving the formation of Si-C linkages
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
Abstract
Organohalosilones are prepared by reacting an aromatic halohydrocarbon which contains at least one halogen atom bonded to a carbon atom in an aromatic ring with a halomonohydrosilane at a temperature of from 250 DEG to 460 DEG C., at least a portion of the reactants being in condensed phase, e.g. by carrying out the reaction under pressure. Suitable halomonohydrosilanes contain at least one and preferably more than one halogen atom bonded to the silicon atom, e.g. trichlorosilane, monomethyldichlorosilane and monophenyldichlorosilane. The aromatic halohydrocarbon may be a benzene derivative containing at least one halogen bonded to a carbon atom in the ring, and may have attached thereto substituents other than halogen and hydrogen atoms, e.g. ethylchlorobenzenes, isopropylchlorobenzenes, 2 - chlorodiphenyl and chloronaphthalenes. Halogen and hydrogen atoms may constitute the only substituents bonded to the carbon atoms as illustrated by monochlorobenzene, o- and p-dichlorobenzene and tetrachlorobenzenes. In examples the following compounds are prepared: phenyltrichlorosilane, o-, m and p-tolyltrichlorosilanes, o-, m and p-ethylphenyltrichlorosilanes, a mixture of isomeric cumyltrichlorosilanes, o-, m and p-chlorophenyltrichlorosilanes, a mixture of bis-(trichlorosilyl)-benzenes, m- and p-xenyltrichlorosilanes, phenylmethyldichlorosilane, betanaphthyltrichlorosilane, a mixture of bis-(trichlorosilyl)-naphthalenes and o-, m and p-(chlorophenyl)-methyldichlorosilanes. A mixture of organosilicon compounds is obtained by reacting tetrachlorobenzene and trichlorosilane in accordance with the above process.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US635645XA | 1946-06-06 | 1946-06-06 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB635645A true GB635645A (en) | 1950-04-12 |
Family
ID=10332774
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3207347A Expired GB635645A (en) | 1946-06-06 | 1947-12-04 | Production of organohalosilanes |
Country Status (2)
| Country | Link |
|---|---|
| DE (1) | DE890504C (en) |
| GB (1) | GB635645A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2715060A (en) * | 1951-10-31 | 1955-08-09 | Dow Corning | Process of making silica |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1046619B (en) * | 1954-12-07 | 1958-12-18 | Wacker Chemie Gmbh | Process for the preparation of arylchlorosilanes |
-
1947
- 1947-12-04 GB GB3207347A patent/GB635645A/en not_active Expired
-
1950
- 1950-09-21 DE DE1950D0005793 patent/DE890504C/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2715060A (en) * | 1951-10-31 | 1955-08-09 | Dow Corning | Process of making silica |
Also Published As
| Publication number | Publication date |
|---|---|
| DE890504C (en) | 1953-09-21 |
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