GB614966A - Improvements in and relating to the treatment of wool - Google Patents
Improvements in and relating to the treatment of woolInfo
- Publication number
- GB614966A GB614966A GB22039/46A GB2203946A GB614966A GB 614966 A GB614966 A GB 614966A GB 22039/46 A GB22039/46 A GB 22039/46A GB 2203946 A GB2203946 A GB 2203946A GB 614966 A GB614966 A GB 614966A
- Authority
- GB
- United Kingdom
- Prior art keywords
- compound
- sodium
- wool
- treatment
- nickel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 210000002268 wool Anatomy 0.000 title abstract 6
- -1 peroxy compound Chemical class 0.000 abstract 5
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 abstract 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 4
- 239000000463 material Substances 0.000 abstract 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 3
- 229910052802 copper Inorganic materials 0.000 abstract 3
- 239000010949 copper Substances 0.000 abstract 3
- 239000004744 fabric Substances 0.000 abstract 3
- 150000002736 metal compounds Chemical class 0.000 abstract 3
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 abstract 2
- 229910052783 alkali metal Inorganic materials 0.000 abstract 2
- 150000001340 alkali metals Chemical class 0.000 abstract 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 abstract 2
- 229910052753 mercury Inorganic materials 0.000 abstract 2
- 229910052759 nickel Inorganic materials 0.000 abstract 2
- 150000002816 nickel compounds Chemical class 0.000 abstract 2
- 150000002978 peroxides Chemical class 0.000 abstract 2
- 229910052709 silver Inorganic materials 0.000 abstract 2
- 239000004332 silver Substances 0.000 abstract 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 abstract 2
- 239000004289 sodium hydrogen sulphite Substances 0.000 abstract 2
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 abstract 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 abstract 1
- 239000004115 Sodium Silicate Substances 0.000 abstract 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 abstract 1
- 150000001342 alkaline earth metals Chemical class 0.000 abstract 1
- 238000004061 bleaching Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 abstract 1
- OPQARKPSCNTWTJ-UHFFFAOYSA-L copper(ii) acetate Chemical compound [Cu+2].CC([O-])=O.CC([O-])=O OPQARKPSCNTWTJ-UHFFFAOYSA-L 0.000 abstract 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 abstract 1
- 238000009950 felting Methods 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- BRMYZIKAHFEUFJ-UHFFFAOYSA-L mercury diacetate Chemical compound CC(=O)O[Hg]OC(C)=O BRMYZIKAHFEUFJ-UHFFFAOYSA-L 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 abstract 1
- 238000002203 pretreatment Methods 0.000 abstract 1
- 238000009991 scouring Methods 0.000 abstract 1
- 229910001961 silver nitrate Inorganic materials 0.000 abstract 1
- 239000001632 sodium acetate Substances 0.000 abstract 1
- 235000017281 sodium acetate Nutrition 0.000 abstract 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 abstract 1
- 229960001922 sodium perborate Drugs 0.000 abstract 1
- 229940045872 sodium percarbonate Drugs 0.000 abstract 1
- 239000001488 sodium phosphate Substances 0.000 abstract 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 abstract 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 abstract 1
- 239000001117 sulphuric acid Substances 0.000 abstract 1
- 235000011149 sulphuric acid Nutrition 0.000 abstract 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 abstract 1
- 239000004753 textile Substances 0.000 abstract 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 abstract 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 abstract 1
- 235000019801 trisodium phosphate Nutrition 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 239000002759 woven fabric Substances 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with hydrogen peroxide or peroxides of metals; with persulfuric, permanganic, pernitric, percarbonic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
- D06L4/10—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/13—Ammonium halides or halides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/155—Halides of elements of Groups 2 or 12 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/28—Halides of elements of Groups 8, 9, 10 or 18 of the Periodic Table
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Textile material, composed wholly or partly of wool or of other animal fibres, is rendered resistant to felting and shrinking, when washed in aqueous liquids, by impregnating it with a compound of copper, nickel, silver, or mercury, and subsequently impregnating it with a solution of a peroxide or peroxy compound, e.g. a peroxide of hydrogen, alkali-metal, or alkaline earth metal, or a perborate or percarbonate of an alkali metal. The wool material may be in the form of loose fibres, slubbings, tops, roving, yarn, knitted or woven fabric, or garments. It may be treated in oily state or after scouring. The metal compound greatly increases the shrink-proofing effect of the peroxy compound. When cellulosic fibres are present with the wool, it is preferred to use a nickel compound. The proportion of metal compound required is very small and may be as low as 0.001 per cent for copper or nickel, 0.03 per cent for silver, and 0.05 per cent for mercury based on the weight of wool. The solution of peroxy compound may be used at a pH of 3 to 10.5. The treatment may be used to effect a bleaching of the materials as well as shrink-proofing, and it is then preferred to use a copper or nickel compound and to carry out the treatment with the peroxy compound under alkaline conditions. A final treatment with acidified sodium bisulphite solution may be given to assist in removal of the metal compound from the fibres and to enhance whiteness of the material. In an example, wool fabric is impregnated with a very dilute solution of copper sulphate at 75 DEG C. The fabric is removed and a mixture of hydrogen peroxide and sodium silicate is added to the liquor which has been cooled to 50 DEG C. The fabric is again entered in the liquor and treated for an hour. It is then placed in water containing a small proportion of sodium bisulphite and sulphuric acid, and then washed and dried. In other examples, nickel sulphate, copper acetate, silver nitrate and mercuric acetate are used for the pre-treatment, and sodium perborate and sodium percarbonate are used for the peroxy compound treatment. When using hydrogen peroxide, the pH may be adjusted by means of tri-sodium phosphate, sodium acetate, or tetra-sodium pyrophosphate.
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE473751D BE473751A (en) | 1946-07-24 | ||
NL67693D NL67693C (en) | 1946-07-24 | ||
GB22039/46A GB614966A (en) | 1946-07-24 | 1946-07-24 | Improvements in and relating to the treatment of wool |
FR947387D FR947387A (en) | 1946-07-24 | 1947-05-30 | Wool processing |
US136666A US2599977A (en) | 1946-07-24 | 1950-01-03 | Treatment of wool |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB22039/46A GB614966A (en) | 1946-07-24 | 1946-07-24 | Improvements in and relating to the treatment of wool |
Publications (1)
Publication Number | Publication Date |
---|---|
GB614966A true GB614966A (en) | 1948-12-30 |
Family
ID=10172904
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB22039/46A Expired GB614966A (en) | 1946-07-24 | 1946-07-24 | Improvements in and relating to the treatment of wool |
Country Status (5)
Country | Link |
---|---|
US (1) | US2599977A (en) |
BE (1) | BE473751A (en) |
FR (1) | FR947387A (en) |
GB (1) | GB614966A (en) |
NL (1) | NL67693C (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2739034A (en) * | 1952-01-04 | 1956-03-20 | Stevensons Dyers Ltd | Permonosulfuric acid and sulphite treatment of wool and resulting product |
US3351419A (en) * | 1963-02-25 | 1967-11-07 | Prec Processes Textiles Ltd | Permonosulfuric acid-hydrogen peroxide wool shrinkproofing combined with dyeing |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2529921A1 (en) * | 1982-07-07 | 1984-01-13 | Rech Participation Ste Norm | PROCESS FOR ANTI-FELT TREATMENT OF KERATIN FIBERS, COMPRISING BASIC OXIDATION CATALYZED BY A METALLIC SALT, AND FIBERS THUS OBTAINED |
JP3338975B2 (en) * | 1994-06-07 | 2002-10-28 | 博史 北條 | Keratin fiber modification method |
RU172214U1 (en) * | 2017-03-28 | 2017-06-30 | Александр Павлович Тюрин | GAME DEVICE |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB317133A (en) * | 1929-05-08 | 1929-08-15 | Samuel Wright Wilkinson | Improvements in the treatment of wool and other animal fibres or textiles containing them |
FR692981A (en) * | 1929-07-06 | 1930-11-13 | Bleaching process | |
BE407008A (en) * | 1933-12-29 | |||
GB553923A (en) * | 1942-01-16 | 1943-06-10 | Bleachers Ass Ltd | Improvements in the treatment of textile materials consisting of or containing animal fibres to reduce their tendency to felt and shrink |
US2406412A (en) * | 1942-08-21 | 1946-08-27 | Ici Ltd | Treatment of wool fibers |
GB579584A (en) * | 1944-07-25 | 1946-08-08 | Bleachers Ass Ltd | Improvements in the treatment of textile materials consisting of or containing animal fibres to reduce their tendency to felt and shrink |
-
0
- NL NL67693D patent/NL67693C/xx active
- BE BE473751D patent/BE473751A/xx unknown
-
1946
- 1946-07-24 GB GB22039/46A patent/GB614966A/en not_active Expired
-
1947
- 1947-05-30 FR FR947387D patent/FR947387A/en not_active Expired
-
1950
- 1950-01-03 US US136666A patent/US2599977A/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2739034A (en) * | 1952-01-04 | 1956-03-20 | Stevensons Dyers Ltd | Permonosulfuric acid and sulphite treatment of wool and resulting product |
US3351419A (en) * | 1963-02-25 | 1967-11-07 | Prec Processes Textiles Ltd | Permonosulfuric acid-hydrogen peroxide wool shrinkproofing combined with dyeing |
Also Published As
Publication number | Publication date |
---|---|
US2599977A (en) | 1952-06-10 |
FR947387A (en) | 1949-06-30 |
BE473751A (en) | |
NL67693C (en) |
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