GB603967A - An improved lubricating grease composition - Google Patents
An improved lubricating grease compositionInfo
- Publication number
- GB603967A GB603967A GB31031/45A GB3103145A GB603967A GB 603967 A GB603967 A GB 603967A GB 31031/45 A GB31031/45 A GB 31031/45A GB 3103145 A GB3103145 A GB 3103145A GB 603967 A GB603967 A GB 603967A
- Authority
- GB
- United Kingdom
- Prior art keywords
- per cent
- sebacate
- soap
- ethyl hexyl
- secondary butyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M7/00—Solid or semi-solid compositions essentially based on lubricating components other than mineral lubricating oils or fatty oils and their use as lubricants; Use as lubricants of single solid or semi-solid substances
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/062—Oxides; Hydroxides; Carbonates or bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/063—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/129—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/16—Naphthenic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/282—Esters of (cyclo)aliphatic oolycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/34—Esters having a hydrocarbon substituent of thirty or more carbon atoms, e.g. substituted succinic acid derivatives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2211/04—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen, halogen, and oxygen
- C10M2211/044—Acids; Salts or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2211/06—Perfluorinated compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/08—Thiols; Sulfides; Polysulfides; Mercaptals
- C10M2219/082—Thiols; Sulfides; Polysulfides; Mercaptals containing sulfur atoms bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/02—Groups 1 or 11
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/04—Groups 2 or 12
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/06—Groups 3 or 13
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2010/00—Metal present as such or in compounds
- C10N2010/08—Groups 4 or 14
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/02—Bearings
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/08—Solids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/10—Semi-solids; greasy
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
Low temperature lubricating greases comprise one or more compounds having the formula COOR1(R)COOR2, where R is a bivalent aliphatic hydrocarbon radical and R1 and R2 are branched chain hydrocarbon radicals; an alkali or alkaline earth metal soap and a stabilizer, i.e. a material used to improve the mechanical or physical stability of the grease. R may be a polymethylene radical having 8 methylene groups, as in sebacic acid, and R1 and R2 may be 2-ethyl hexyl radicals or secondary butyl radicals. The esters may contain additional constituents or functional groups. The proportion of soap present may be 6-30 per cent and the lithium soap of hydrogenated fish oil acids is preferred. The proportion of stabilizer may be 0.5-5 per cent, e.g. 1 per cent of the soap of an amphoteric metal. The esters may be di-2-ethylhexyl sebacate or a mixture of this with di - secondary butyl sebacate, 1-isobutyl-2-ethyl hexyl sebacate, or a mixture of di-secondary butyl adipate and di-isopropyl sebacate. In an example, 12 per cent lithium soap of hydrogenated fish oil acids, 0.5 per cent aluminium stearate, 0.5 per cent zinc naphthenate and 87 per cent of 2-ethyl hexyl sebacate were mixed together, heated to 360-400 DEG F., rapidly cooled by running over a drum, chilled and worked to the desired penetration. The resultant lubricating grease shows considerably less evaporation at elevated temperatures and less resistance to torque at very low temperatures than conventional low temperature lithium soap greases made with low viscosity petroleum distillates.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US570784A US2436347A (en) | 1944-12-30 | 1944-12-30 | Grease compositions |
Publications (1)
Publication Number | Publication Date |
---|---|
GB603967A true GB603967A (en) | 1948-06-25 |
Family
ID=24281039
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB31031/45A Expired GB603967A (en) | 1944-12-30 | 1945-11-19 | An improved lubricating grease composition |
Country Status (5)
Country | Link |
---|---|
US (1) | US2436347A (en) |
BE (1) | BE461872A (en) |
CH (1) | CH251396A (en) |
DE (1) | DE833098C (en) |
GB (1) | GB603967A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE951105C (en) * | 1950-08-24 | 1956-10-25 | Standard Oil Dev Co | lubricant |
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2735816A (en) * | 1956-02-21 | Fluid compositions containing an | ||
US2481372A (en) * | 1946-09-27 | 1949-09-06 | Shell Dev | Rust protective lubricants |
US2467147A (en) * | 1945-03-22 | 1949-04-12 | Standard Oil Dev Co | Low-temperature lubricant |
US2465961A (en) * | 1945-10-24 | 1949-03-29 | Shell Dev | Grease |
US2585182A (en) * | 1947-03-18 | 1952-02-12 | Union Carbide & Carbon Corp | Grease lubricant |
US2497133A (en) * | 1947-06-06 | 1950-02-14 | Standard Oil Dev Co | Lubricating grease compositions |
US2491028A (en) * | 1947-10-11 | 1949-12-13 | Standard Oil Dev Co | Lubricating grease compositions |
US2491054A (en) * | 1947-10-25 | 1949-12-13 | Standard Oil Dev Co | Lubricating grease |
US2521438A (en) * | 1947-12-06 | 1950-09-05 | Standard Oil Dev Co | Grease composition |
US2528373A (en) * | 1949-01-21 | 1950-10-31 | Texas Co | Alkenyl succinic acid grease |
NL73467C (en) * | 1949-11-01 | |||
US2653132A (en) * | 1949-12-17 | 1953-09-22 | Standard Oil Dev Co | Oxo-bottoms base lubricating grease |
US2588273A (en) * | 1950-08-02 | 1952-03-04 | Standard Oil Dev Co | Lubricating compositions |
NL93803C (en) * | 1950-12-22 | |||
US2639266A (en) * | 1951-04-07 | 1953-05-19 | Texas Co | Lubricating grease comprising a complex ester base and sodium myristate |
US2761844A (en) * | 1951-11-07 | 1956-09-04 | Gulf Research Development Co | High temperature lubricating compositions |
US2723957A (en) * | 1952-02-27 | 1955-11-15 | Exxon Research Engineering Co | Synthetic lubricating oils containing paraffinic resins |
US2690429A (en) * | 1952-04-07 | 1954-09-28 | Standard Oil Dev Co | Grease compositions containing an aryl oxy alkyl salt as a stabilizer |
US2758973A (en) * | 1952-05-29 | 1956-08-14 | Exxon Research Engineering Co | Process for preparing lubricating grease compositions |
US2739127A (en) * | 1952-07-02 | 1956-03-20 | Exxon Research Engineering Co | Lubricating grease containing organic carbonates |
US2751351A (en) * | 1952-07-05 | 1956-06-19 | Exxon Research Engineering Co | Complex ester base lubricating grease compositions |
NL181914B (en) * | 1952-11-29 | Toyo Seikan Kaisha Ltd | DEVICE FOR MANUFACTURE OF DRAWN OBJECTS. | |
US2796423A (en) * | 1952-12-01 | 1957-06-18 | Exxon Research Engineering Co | Formals of lubricating grade |
US2719123A (en) * | 1953-06-18 | 1955-09-27 | Robert L Merker | Fluid compositions containing a cyclopolysiloxane |
US3272745A (en) * | 1962-12-27 | 1966-09-13 | Texaco Inc | Grease composition |
US3539514A (en) * | 1967-08-01 | 1970-11-10 | Arthur Frank Strouse | Corrosion inhibitor and lubricant |
US8703678B2 (en) * | 2006-10-06 | 2014-04-22 | Idemitsu Kosan Co., Ltd. | Grease |
US10208269B2 (en) * | 2013-12-23 | 2019-02-19 | Exxonmobil Research And Engineering Company | Low viscosity ester lubricant and method for using |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2104408A (en) * | 1933-09-20 | 1938-01-04 | Standard Oil Dev Co | Lubricant |
US1993738A (en) * | 1934-08-31 | 1935-03-12 | Du Pont | Myristyl esters of polycarboxylic acids |
US2134736A (en) * | 1935-04-19 | 1938-11-01 | Atlantic Refining Co | Lubricant |
US2158096A (en) * | 1936-04-24 | 1939-05-16 | Du Pont | Lubricant |
US2204601A (en) * | 1937-02-23 | 1940-06-18 | Standard Oil Co | Compounded lubricant |
US2362767A (en) * | 1942-06-03 | 1944-11-14 | Cities Service Oil Co | Lubricants |
US2351280A (en) * | 1942-07-16 | 1944-06-13 | Cities Service Oil Co | Lubricant |
US2363513A (en) * | 1942-09-15 | 1944-11-28 | Standard Oil Co California | Lubricating composition and the like |
-
0
- BE BE461872D patent/BE461872A/xx unknown
-
1944
- 1944-12-30 US US570784A patent/US2436347A/en not_active Expired - Lifetime
-
1945
- 1945-11-19 GB GB31031/45A patent/GB603967A/en not_active Expired
- 1945-12-29 CH CH251396D patent/CH251396A/en unknown
-
1950
- 1950-09-30 DE DEST2486A patent/DE833098C/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE951105C (en) * | 1950-08-24 | 1956-10-25 | Standard Oil Dev Co | lubricant |
Also Published As
Publication number | Publication date |
---|---|
US2436347A (en) | 1948-02-17 |
DE833098C (en) | 1952-03-03 |
BE461872A (en) | |
CH251396A (en) | 1947-10-31 |
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