GB597564A - Method for purifying the electrolytes used in the electrolysis of alkali metal chlorides employing a mercury cathode - Google Patents

Method for purifying the electrolytes used in the electrolysis of alkali metal chlorides employing a mercury cathode

Info

Publication number
GB597564A
GB597564A GB23105/45A GB2310545A GB597564A GB 597564 A GB597564 A GB 597564A GB 23105/45 A GB23105/45 A GB 23105/45A GB 2310545 A GB2310545 A GB 2310545A GB 597564 A GB597564 A GB 597564A
Authority
GB
United Kingdom
Prior art keywords
liquor
carbon
hcl
free chlorine
metal chlorides
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB23105/45A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Krebs & Cie SA
Original Assignee
Krebs & Cie SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Krebs & Cie SA filed Critical Krebs & Cie SA
Publication of GB597564A publication Critical patent/GB597564A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01DCOMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D3/00Halides of sodium, potassium or alkali metals in general
    • C01D3/14Purification
    • C01D3/16Purification by precipitation or adsorption

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

Electrolytic cell liquor containing alkali-metal chlorides is purified by passing at 10 DEG -100 DEG C. through a layer of porous carbon such as active carbon, charcoal or coke to eliminate free chlorine and hypochlorites. To remove the chlorates present oxidisable substances such as ferrous chloride may be added to the liquor together with hydrochloric acid. Catalysts such as oxides or hydrates of iron may be added to the liquor or carbon to accelerate the reactions. Partial dechlorination may be effected by passing finely divided air or other inert gas through the liquor which may be first acidified with HCl the liquor being then treated as above. The chlorinated gases from the partial dechlorination may be passed upwardly through porous carbon as water streams down to produce HCl. This latter contains free chlorine and is passed through further carbon to transform completely the free chlorine into HCl.
GB23105/45A 1944-05-17 1945-09-07 Method for purifying the electrolytes used in the electrolysis of alkali metal chlorides employing a mercury cathode Expired GB597564A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR597564X 1944-05-17

Publications (1)

Publication Number Publication Date
GB597564A true GB597564A (en) 1948-01-28

Family

ID=8968321

Family Applications (1)

Application Number Title Priority Date Filing Date
GB23105/45A Expired GB597564A (en) 1944-05-17 1945-09-07 Method for purifying the electrolytes used in the electrolysis of alkali metal chlorides employing a mercury cathode

Country Status (1)

Country Link
GB (1) GB597564A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2081024A1 (en) * 1970-02-20 1971-11-26 Ici Ltd

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2081024A1 (en) * 1970-02-20 1971-11-26 Ici Ltd

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