GB584548A - Improvements in or relating to the spinning of filaments of acrylonitrile polymers - Google Patents
Improvements in or relating to the spinning of filaments of acrylonitrile polymersInfo
- Publication number
- GB584548A GB584548A GB????3/44D GB344D GB584548A GB 584548 A GB584548 A GB 584548A GB 344 D GB344 D GB 344D GB 584548 A GB584548 A GB 584548A
- Authority
- GB
- United Kingdom
- Prior art keywords
- filaments
- bath
- temperature
- spinning
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000009987 spinning Methods 0.000 title abstract 5
- 229920002239 polyacrylonitrile Polymers 0.000 title abstract 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 abstract 6
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 abstract 3
- 239000000243 solution Substances 0.000 abstract 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 2
- 229960002713 calcium chloride Drugs 0.000 abstract 2
- 229910001628 calcium chloride Inorganic materials 0.000 abstract 2
- 235000011148 calcium chloride Nutrition 0.000 abstract 2
- 239000001110 calcium chloride Substances 0.000 abstract 2
- LCEDQNDDFOCWGG-UHFFFAOYSA-N morpholine-4-carbaldehyde Chemical compound O=CN1CCOCC1 LCEDQNDDFOCWGG-UHFFFAOYSA-N 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 abstract 1
- DZLUPKIRNOCKJB-UHFFFAOYSA-N 2-methoxy-n,n-dimethylacetamide Chemical compound COCC(=O)N(C)C DZLUPKIRNOCKJB-UHFFFAOYSA-N 0.000 abstract 1
- BTJIUGUIPKRLHP-UHFFFAOYSA-N 4-nitrophenol Chemical class OC1=CC=C([N+]([O-])=O)C=C1 BTJIUGUIPKRLHP-UHFFFAOYSA-N 0.000 abstract 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 1
- 229920002367 Polyisobutene Polymers 0.000 abstract 1
- 239000004793 Polystyrene Substances 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical class C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- AIPVTTKYSPOWFO-UHFFFAOYSA-N azepane-1-carbaldehyde Chemical compound O=CN1CCCCCC1 AIPVTTKYSPOWFO-UHFFFAOYSA-N 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
- 229920000728 polyester Polymers 0.000 abstract 1
- 229920002223 polystyrene Polymers 0.000 abstract 1
- 229920002689 polyvinyl acetate Polymers 0.000 abstract 1
- 239000011118 polyvinyl acetate Substances 0.000 abstract 1
- 229920000915 polyvinyl chloride Polymers 0.000 abstract 1
- 239000004800 polyvinyl chloride Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/18—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S260/00—Chemistry of carbon compounds
- Y10S260/23—Fiber
Landscapes
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
Abstract
Artificial filaments of high tenacity, lustrous appearance and substantially free of voids are obtained by extruding a solution of polyacrylonitrile in a volatile organic solvent through orifices into a spinning bath consisting of an aqueous solution containing 30-50 per cent by weight of calcium chloride at a temperature of about 100 DEG C. and passing the filaments through the bath until they are substantially completely coagulated. The spinning solution preferably contains from 10 to 30 per cent of the polymer and is extruded preferably at a temperature of 100 DEG to 150 DEG C. Specified <PICT:0584548/IV/1> solvents are dimethyl formamide, dimethyl methoxy-acetamide, N-formyl-morpholine, N-formyl hexamethylene imine, butadiene cyclic sulphone, tetramethylene cyclic sulphone, p-phenylene diamine and the m- and p-nitrophenols. The filaments are preferably maintained under tension during at least part of their travel through the spinning bath and a two-bath system may be employed if desired, in which the first bath consists of aqueous calcium-chloride solution at a temperature of about 100 DEG C., and the second bath may have the same composition as the first or may comprise a different liquid incapable of dissolving the polymer, at a higher temperature, and the filaments may be subjected to a high stretching tension in the second bath. The filaments are finally collected, washed, finished, dried and, if desired, twisted and wound, and they may be heated in a relaxed state to a temperature of 130 DEG to 200 DEG C. to increase their elongation. Referring to Fig. 1, a solution of poly-acrylonitrile in dimethyl formamide is extruded at a temperature of 100 DEG C. through spinneret 1 into spinning trough 3 containing a 40 per cent aqueous solution of calcium chloride maintained at 90 DEG to 100 DEG C. by heating coils 4. The filaments 5 so formed are tensioned by snubbing pins 6, drawn off by roll 8 and collected on bobbin 9. The poly-acrylonitrile preferably has a molecular weight within the range 40,000 to 250,000. Interpolymers containing a major portion of polyacrylonitrile with, e.g. polyvinyl acetate, polyvinyl chloride, polyesters or other derivatives of acrylic or methacrylic acid, polystyrene and polyisobutylene may also be employed. Specifications 404,504, 459,596 and 461,675 are referred to.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US496376A US2426719A (en) | 1943-07-28 | 1943-07-28 | Wet spinning of acrylonitrile polymers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB584548A true GB584548A (en) | 1947-01-17 |
Family
ID=23972361
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB14432/44A Expired GB583939A (en) | 1943-07-28 | 1944-07-28 | Improvements in or relating to the spinning of filaments of acrylonitrile polymers |
| GB????3/44D Expired GB584548A (en) | 1943-07-28 | 1944-07-28 | Improvements in or relating to the spinning of filaments of acrylonitrile polymers |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB14432/44A Expired GB583939A (en) | 1943-07-28 | 1944-07-28 | Improvements in or relating to the spinning of filaments of acrylonitrile polymers |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US2426719A (en) |
| FR (1) | FR961382A (en) |
| GB (2) | GB583939A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1016893B (en) * | 1952-11-05 | 1957-10-03 | Textile And Chemical Res Compa | Process for the production of crimped threads from polymers or copolymers of acrylonitrile |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR961050A (en) * | 1947-02-13 | 1950-04-28 | ||
| US2467553A (en) * | 1947-05-08 | 1949-04-19 | Du Pont | Wet-spinning acrylonitrile polymers |
| US2543994A (en) * | 1947-08-29 | 1951-03-06 | Du Pont | Vat dyeing of acrylonitrile polymers |
| US2527863A (en) * | 1947-08-29 | 1950-10-31 | Du Pont | Modification and dyeing of acrylonitrile polymers |
| US2656341A (en) * | 1948-09-28 | 1953-10-20 | Koppers Co Inc | Catalytic polymerization process |
| US2579451A (en) * | 1948-12-31 | 1951-12-18 | Du Pont | Polymeric materials |
| US2601252A (en) * | 1949-03-25 | 1952-06-24 | Ind Rayon Corp | Polymeric compositions |
| NL74683C (en) * | 1949-06-13 | |||
| US2601253A (en) * | 1949-06-13 | 1952-06-24 | Ind Rayon Corp | Polymeric compositions and method of shaping same |
| NL74688C (en) * | 1949-07-09 | |||
| US2601255A (en) * | 1949-08-13 | 1952-06-24 | Ind Rayon Corp | Acrylonitrile polymer solutions in a cyclic carbonate solvent containing a ketone as a discoloration inhibitor |
| FR1017358A (en) * | 1949-11-03 | 1952-12-09 | Glanzstoff Ag | Process for spinning polyacrylnitrile |
| BE514101A (en) * | 1951-10-09 | |||
| US2920992A (en) * | 1954-09-22 | 1960-01-12 | Du Pont | Article of commerce |
| NL99693C (en) * | 1957-01-17 | |||
| US3098060A (en) * | 1960-05-27 | 1963-07-16 | American Cyanamid Co | Preparation of high molecular weight polyacrylonitrile with n-butyl lithium as catalyst |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2123599A (en) * | 1930-01-28 | 1938-07-12 | Ig Farbenindustrie Ag | Production of polymerization products |
| US2140048A (en) * | 1931-01-17 | 1938-12-13 | Ig Farbenindustrie Ag | Production of polymerization products |
| GB401160A (en) * | 1933-02-27 | 1933-11-09 | Kalle & Co Ag | Manufacture of threads |
| NL40975C (en) * | 1934-08-21 | |||
| GB482216A (en) * | 1936-09-30 | 1938-03-25 | William Alexander Dickie | Improvements in the manufacture of artificial filaments, films and similar materials |
| FR837392A (en) * | 1937-05-08 | 1939-02-08 | Bataafsche Petroleum | Process for the manufacture of films, tapes, sheets, threads and fibers capable of being used as textiles or the like |
| GB502191A (en) * | 1937-10-11 | 1939-03-14 | Distillers Co Yeast Ltd | Improvements relating to the manufacture of threads, films and like articles from polymerisation products of high molecular weight |
| GB511054A (en) * | 1938-02-11 | 1939-08-11 | James Robertson Myles | Improvements in and relating to the manufacture of threads, films, ribbons, tubes and like forms of polymerised ethylene |
| NL48858C (en) * | 1938-04-07 | 1900-01-01 | ||
| US2254740A (en) * | 1940-03-13 | 1941-09-02 | Us Rubber Co | Heat resisting yarn and cord |
| US2366495A (en) * | 1942-07-03 | 1945-01-02 | Gen Electric | Synthetic products having molecularly oriented structure |
-
0
- FR FR961382D patent/FR961382A/fr not_active Expired
-
1943
- 1943-07-28 US US496376A patent/US2426719A/en not_active Expired - Lifetime
-
1944
- 1944-07-28 GB GB14432/44A patent/GB583939A/en not_active Expired
- 1944-07-28 GB GB????3/44D patent/GB584548A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1016893B (en) * | 1952-11-05 | 1957-10-03 | Textile And Chemical Res Compa | Process for the production of crimped threads from polymers or copolymers of acrylonitrile |
Also Published As
| Publication number | Publication date |
|---|---|
| GB583939A (en) | 1947-01-02 |
| FR961382A (en) | 1950-05-11 |
| US2426719A (en) | 1947-09-02 |
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