GB561104A - Manufacture of ester-amide polymers - Google Patents

Manufacture of ester-amide polymers

Info

Publication number
GB561104A
GB561104A GB574542A GB574542A GB561104A GB 561104 A GB561104 A GB 561104A GB 574542 A GB574542 A GB 574542A GB 574542 A GB574542 A GB 574542A GB 561104 A GB561104 A GB 561104A
Authority
GB
United Kingdom
Prior art keywords
ethanolamine
sebacic acid
acid
reactants
amino
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB574542A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Priority to GB574542A priority Critical patent/GB561104A/en
Publication of GB561104A publication Critical patent/GB561104A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/44Polyester-amides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyamides (AREA)

Abstract

A process of preparing ester-amide polymers comprises heating in two stages, firstly to 150 DEG -180 DEG C., and subsequently to 180 DEG -250 DEG C., a mixture comprising bifunctional polyamide-forming and bifunctional polyester-forming reactants which consists at least of a monoamino-monohydric alcohol and a dibasic carboxylic acid. In addition to these reactants, the mixture may contain other bifunctional reactants, e.g. diamines, amino acids and hydroxy acids. The complementary reacting groups should be present in substantially equimolecular proportions, and not less than 5.0 molar per cent of the amino alcohol, based on the other reactants, should be used. The preferred amino alcohols are those having a chain of less than 4 carbon atoms separating the amino and hydroxyl groups, and the preferred dibasic carboxylic acids are those having a radical length of at least 6. Examples are given of the preparation of ester-amide polymers from: (1) ethanolamine, sebacic acid and hexamethylenediammonium sebacate; (2) ethanolamine, o -hydroxymyristic acid and sebacic acid; (3) ethanolamine and sebacic acid; (4) ethanolamine, sebacic acid and hexamethylene - diamine - sebacic acid salt; (5) 6-aminocaproic acid, ethanolamine and sebacic acid, and (6) ethanolamine and adipic acid. Specifications 461,237, 535,335 and 561,108 are referred to.
GB574542A 1942-04-29 1942-04-29 Manufacture of ester-amide polymers Expired GB561104A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB574542A GB561104A (en) 1942-04-29 1942-04-29 Manufacture of ester-amide polymers

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB574542A GB561104A (en) 1942-04-29 1942-04-29 Manufacture of ester-amide polymers

Publications (1)

Publication Number Publication Date
GB561104A true GB561104A (en) 1944-05-05

Family

ID=9801849

Family Applications (1)

Application Number Title Priority Date Filing Date
GB574542A Expired GB561104A (en) 1942-04-29 1942-04-29 Manufacture of ester-amide polymers

Country Status (1)

Country Link
GB (1) GB561104A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115044035A (en) * 2022-06-08 2022-09-13 东华大学 Sequence-regular polyesteramide and one-pot preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115044035A (en) * 2022-06-08 2022-09-13 东华大学 Sequence-regular polyesteramide and one-pot preparation method thereof

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