GB551434A - Dyes and dyeing - Google Patents
Dyes and dyeingInfo
- Publication number
- GB551434A GB551434A GB929941A GB929941A GB551434A GB 551434 A GB551434 A GB 551434A GB 929941 A GB929941 A GB 929941A GB 929941 A GB929941 A GB 929941A GB 551434 A GB551434 A GB 551434A
- Authority
- GB
- United Kingdom
- Prior art keywords
- amino
- diethyl
- acetanilide
- benzthiazole
- hydroxyethyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B29/00—Monoazo dyes prepared by diazotising and coupling
- C09B29/06—Monoazo dyes prepared by diazotising and coupling from coupling components containing amino as the only directing group
- C09B29/08—Amino benzenes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Abstract
551,434. Dyes and dyeing ; artificial silk : cellulose derivative compositions. ARGYLE, C. S. July 23, 1941, No. 9299. [Classes 2 (ii), (iii) and 15 (ii)] Azo dyes are obtained by coupling a diazotized 2-aminothiazole with . a mono-acidvl-mphenylenediamine. Specified diazo components are 4-methyl-2-aminothiazole, 2-amino-benzthiazole and its 6-methyl, 6-methoxy, 6- ethoxy, 6-chloro, 6-acetylamino and 6-benzoylamino derivatives and 2-amino-4:5-benzobenzthiazole, and specified coupling components are m-amino-acetamilide and its N- diethyl, N-di-(#-hydroxyethyl) and N-ethyl-N- #-hydroxyethyl derivatives, N-dimethyl-maminopropionanilide, 3-dietliylamino-4-methylacetanilide, 3-diethylamino-4-methoxy-acetanilide, N-diethyl-m-amino-stearanilide and N- diethyl-m-amino-benzanilide. The products give dischargable brilliant red shades on cellulose ester or ether materials and are applicable also for colouring synthetic linear superpolyamide materials. They may also be incorporated in cellulose ester or ether lacquers or spinning solutions. The dyestuffs containing diazotizable amino groups may be diazotized upon the materials and developed, e.g. with N-diethylaniline, N-di-(#-hydroxyethyl)-m-toluidine, N-diethyl-m-amino acetanilide or N-ethyl-1-naphthylamine. Examples relate to the production of the dyestuffs, (1) 2-amino-benzthiazole # N-diethyl-mamino-acetanilide or N-diethyl-m-amino-stearanilide, (2) 6-ethoxy-2-amino-benzthiazole - m-amino-acetanilide, which gives on cellulose acetate yarn, from an aqueous dispersion, bright bluish red dyeings capable of diazotization on the fibre and development with N-diethylaniline, N-di-(#-hydroxyethyl)-m-toluidine or N-diethyl-m-amino-acetanilide, (3) 6-acetylamino-2-amino-benzthiazole # N-di-(#- hydroxylethyl)-m-amino-acetanilide. An example is also given of the dyeing of a cellulose acetate knitted fabric with the azo dye of (1) above. Specification 440,113 is referred to. 6- Acetylamino-2-aminobenzthiazole and 6- benzoylamino-2-aminobenzthiazole are obtained by adding bromine to solutions of p-aminoacetanilide and p-aminobenzanilide respectively in glacial acetic acid containing ammonium thiocyanate. N-diethyl-m-amino-stearanilide and N-diethyl-m-amino-benzanilide are obtained by the action of stearic acid chloride and benzoyl chloride respectively on 3-diethylaminoaniline.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB929941A GB551434A (en) | 1941-07-23 | 1941-07-23 | Dyes and dyeing |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB929941A GB551434A (en) | 1941-07-23 | 1941-07-23 | Dyes and dyeing |
Publications (1)
Publication Number | Publication Date |
---|---|
GB551434A true GB551434A (en) | 1943-02-22 |
Family
ID=9869283
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB929941A Expired GB551434A (en) | 1941-07-23 | 1941-07-23 | Dyes and dyeing |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB551434A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2683709A (en) * | 1951-12-21 | 1954-07-13 | Eastman Kodak Co | 5-nitrothiazoleazo-nu, nu-substituted aniline-compounds |
US2683708A (en) * | 1951-12-21 | 1954-07-13 | Eastman Kodak Co | Azo compounds prepared from a 2-amino-5-nitrothiazole and an nu-monosubstituted aniline compound |
US2746953A (en) * | 1951-12-21 | 1956-05-22 | Eastman Kodak Co | 5-nitrothiazoleazoaniline compounds |
-
1941
- 1941-07-23 GB GB929941A patent/GB551434A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2683709A (en) * | 1951-12-21 | 1954-07-13 | Eastman Kodak Co | 5-nitrothiazoleazo-nu, nu-substituted aniline-compounds |
US2683708A (en) * | 1951-12-21 | 1954-07-13 | Eastman Kodak Co | Azo compounds prepared from a 2-amino-5-nitrothiazole and an nu-monosubstituted aniline compound |
US2746953A (en) * | 1951-12-21 | 1956-05-22 | Eastman Kodak Co | 5-nitrothiazoleazoaniline compounds |
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