GB476387A - Improved process for electrolytic production of esters - Google Patents

Improved process for electrolytic production of esters

Info

Publication number
GB476387A
GB476387A GB15936/36A GB1593636A GB476387A GB 476387 A GB476387 A GB 476387A GB 15936/36 A GB15936/36 A GB 15936/36A GB 1593636 A GB1593636 A GB 1593636A GB 476387 A GB476387 A GB 476387A
Authority
GB
United Kingdom
Prior art keywords
esters
acid
production
nitric
nitric acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB15936/36A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
VALTER OEHMAN
Nitroglycerin AB
Original Assignee
VALTER OEHMAN
Nitroglycerin AB
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by VALTER OEHMAN, Nitroglycerin AB filed Critical VALTER OEHMAN
Priority to GB15936/36A priority Critical patent/GB476387A/en
Publication of GB476387A publication Critical patent/GB476387A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/20—Processes
    • C25B3/23—Oxidation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

476,387. Eiectrolytic production of esters. NITROGLYCERIN AKTIEBOLAGET, and OHMAN, V. June 8, 1936, No. 15936. Addition to 455,463. [Class 41] Nitric acid esters are produced by anodic oxidation of unsaturated carbon compounds other than olefinic hydrocarbons in the presence of a nitric acid and/or a nitrate. The anolyte should contain a solvent for the carbon compound such as acetic acid or acetone and a conducting salt such as calcium nitrate; the hydroxyl ion concentration is maintained below pH 4 by addition of nitric and/or acetic acid. Gaseous carbon compounds may be introduced under pressure. The anode should have a high over-voltage for oxygen and is preferably of smooth platinum. The reaction may be carried out in a substantially waterfree medium. The oxidation may be limited to production of the esters by providing in the anode compartment a liquid immiscible therewith which dissolves the ester as formed, as described in the parent Specification. Detailed examples are given for the production of nitric acid esters from vinyl bromide, allyl bromide, allyl alcohol, acrylic acid, crotonic acid (alpha), maleic acid, vinyl acetate, isoprene, butadiene, di-methyl butadiene, allene, chloroprene, phorone, cyclo-pentadiene, and pyromucic acid. Esters may also be produced from aromatic compounds having unsaturated side chains.
GB15936/36A 1936-06-08 1936-06-08 Improved process for electrolytic production of esters Expired GB476387A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB15936/36A GB476387A (en) 1936-06-08 1936-06-08 Improved process for electrolytic production of esters

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB15936/36A GB476387A (en) 1936-06-08 1936-06-08 Improved process for electrolytic production of esters

Publications (1)

Publication Number Publication Date
GB476387A true GB476387A (en) 1937-12-08

Family

ID=10068205

Family Applications (1)

Application Number Title Priority Date Filing Date
GB15936/36A Expired GB476387A (en) 1936-06-08 1936-06-08 Improved process for electrolytic production of esters

Country Status (1)

Country Link
GB (1) GB476387A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4193850A (en) * 1979-04-12 1980-03-18 Hoffmann-La Roche Inc. Alkanoyloxylation of beta-ionone

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4193850A (en) * 1979-04-12 1980-03-18 Hoffmann-La Roche Inc. Alkanoyloxylation of beta-ionone

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