GB430596A - The manufacture of substantive dyestuffs - Google Patents

The manufacture of substantive dyestuffs

Info

Publication number
GB430596A
GB430596A GB11240/34A GB1124034A GB430596A GB 430596 A GB430596 A GB 430596A GB 11240/34 A GB11240/34 A GB 11240/34A GB 1124034 A GB1124034 A GB 1124034A GB 430596 A GB430596 A GB 430596A
Authority
GB
United Kingdom
Prior art keywords
aminostilbene
nitro
acid
arylazo
dinitrostilbene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB11240/34A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Publication of GB430596A publication Critical patent/GB430596A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B56/00Azo dyes containing other chromophoric systems
    • C09B56/04Stilbene-azo dyes
    • C09B56/06Bis- or polystilbene azo dyes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
  • Measuring Or Testing Involving Enzymes Or Micro-Organisms (AREA)

Abstract

Substantive stilbene dyes are made by condensing in the presence of alkali a nitrostilbene compound of the general formula <FORM:0430596/IV/1> with an aminostilbene compound of the general formula <FORM:0430596/IV/2> (in which formulae X and Y = nitro or arylazo groups or one stands for an arylazo and the other for an arylazoxy group, with the exception that X and Y must not both be arylazo groups). They may be after-treated by methods customary in the manufacture of azo and stilbene dyes, e.g. oxidation, reduction, alkylation and formation of metallic complexes and yield clear fast reddish yellow to reddish orange shades. In examples (1)--(3)4 - nitro - 4<1> - aminostilbene - 2 : 2<1> - disulphoacid is condensed in aqueous caustic soda with 4 : 4<1> - dinitrostilbene - 2 : 2<1> - disulphoacid, dinitroazodistilbenetetrasulphonic acid (formula given) or the methylated azo dye 4 - nitro - 4<1> - aminostilbene - 2 : 2<1> - disulpho acid --> phenol; the first compound may be after-treated with hypochlorite; (4) the methylated and reduced dyestuff 4 - nitro - 4<1> - aminostilbene - 2 : 2<1> - disulphonic acid --> phenol is condensed with 4 : 4<1> - dinitrostilbene-2 : 2<1> - disulphonic acid. The Specification as open to inspection under Sect. 91 states that X and Y in the above formulae must not be the same arylazo group and gives an example in which 4-nitro-4<1>-aminostilbene - 2 : 2<1> - disulpho acid is condensed with the dyestuff obtained by reduction of 4 : 4<1> - dinitrostilbene - 2 : 2<1> - disulpho acid with glucose or formaldehyde. This subject-matter does not appear in the Specification as accepted. A sample has been furnished under Sect. 2 (5) of the dyestuff obtained by condensing 4-nitro-4<1> - aminostilbene - 2 : 2<1> - disulphonic acid with not more than equimolecular proportions of aniline and condensing the intermediate product with the methylated azo dye 4 - nitro - 4<1> - aminostilbene - 2 : 2<1> - disulphonic acid --> phenol (formula given).
GB11240/34A 1933-04-13 1934-04-13 The manufacture of substantive dyestuffs Expired GB430596A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE430596X 1933-04-13

Publications (1)

Publication Number Publication Date
GB430596A true GB430596A (en) 1935-06-21

Family

ID=6481402

Family Applications (1)

Application Number Title Priority Date Filing Date
GB11240/34A Expired GB430596A (en) 1933-04-13 1934-04-13 The manufacture of substantive dyestuffs

Country Status (1)

Country Link
GB (1) GB430596A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2931853A (en) * 1956-11-13 1960-04-05 Dare Products Inc Armored insulator

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2931853A (en) * 1956-11-13 1960-04-05 Dare Products Inc Armored insulator

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