GB425370A - Improvements in the manufacture and production of condensation products - Google Patents

Improvements in the manufacture and production of condensation products

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Publication number
GB425370A
GB425370A GB2705733A GB2705733A GB425370A GB 425370 A GB425370 A GB 425370A GB 2705733 A GB2705733 A GB 2705733A GB 2705733 A GB2705733 A GB 2705733A GB 425370 A GB425370 A GB 425370A
Authority
GB
United Kingdom
Prior art keywords
products
alcohols
aliphatic
esters
obtainable
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2705733A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Priority to GB2705733A priority Critical patent/GB425370A/en
Publication of GB425370A publication Critical patent/GB425370A/en
Expired legal-status Critical Current

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  • Treatment And Processing Of Natural Fur Or Leather (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)

Abstract

Albumen degradation products or synthetic polypeptides are condensed with chlorocarbonic esters of aliphatic, cycloaliphatic, aliphatic-cycloaliphatic or aliphatic-aromatic mono- or poly-hydric alcohols containing at least five carbon atoms. The term "albumen degradation products" covers only the products obtainable by degrading albumens to the di-or tri-peptide stage, the treatment of simple aminoacids being excluded. Albuminous materials of which the degradation products may be used are gelatin, leather glue, hide glue, bone glue, horn waste, flesh waste, herring sperm, soya bean meal, wool, sericin, casein, or hydroxyethylation products of casein; the degradation may be effected with acid or alkaline solutions or with enzymes. Synthetic polypeptides which may replace the albumen degradation products are those obtainable by the condensation of glycine, alanine, sarcosine and other aminoacids. Suitable chlorocarbonic esters are those of hexyl, octyl, dodecyl, myristyl, cetyl, octodecyl and oleyl alcohols, octodecanediol, montanol, cyclohexanol, methylcyclohexanol, benzyl alcohol, cinnamic alcohol, and phenylcetyl alcohol, or of mixtures of alcohols such as are obtainable by hydrogenating oils, fats and waxes or by oxidizing paraffinic hydrocarbons; chlorocarbonic esters of substituted alcohols, e.g. alcohols containing halogen atoms or ester, ether or nitro groups, may also be used; the esters may be prepared by the action of phosgene on the alcohols. The reaction of the esters with the albumen degradation products or polypeptides may be effected at 20--80 DEG C. in an aqueous medium in the presence of alkaline reagents, e.g. caustic soda or potash, ammonia, soda or pyridine; when albumen degradation products prepared under mild conditions are used in the reaction, the reaction products may be treated with ethylene oxide, to increase their solubility. The products are useful as wetting, washing and emulsifying agents in the treatment of textiles, leather and paper and in the foodstuff and pharmaceutical industries; in particular, they may be used (a) as levelling agents in dyeing animal or vegetable fibres with vat dyes; (b) for preventing precipitation when soaps are used in hard water; (c) for preventing precipitation of azo dyes when producing those dyes on the fibre; and (d) for making emulsions for dressing or waterproofing fabrics. The products may be used in admixture with other substances, the following being specified: sulphite cellulose waste liquor; soaps; turkey red oil; alkylnaphthalenesulphonic acids; condensation products of higher carboxylic acids with amino- or oxy-alkylsulphonic acids; sulphuric esters of higher aliphatic alcohols; reaction products of ethylene oxide and organic hydroxy or amino compounds or carboxylic acids; glue; dextrin; starch; vegetable mucilages; organic solvents such as trichlorethylene, carbon tetrachloride, benzyl alcohol and cyclohexanol; oxidizing agents such as perborates or hydrogen peroxide; and salts such as common salt, phosphates, silicates and sodium sulphate. In the examples, (1) gelatin is heated with dilute caustic soda solution, and the filtered product is treated with cetyl chlorocarbonate in the presence of soda or caustic soda; the product may be added to a bath in which bleached mercerized cotton satin is dyed with Indanthrene brilliant green B double paste; (2) gelatin degraded as in example 1 is treated with the chlorocarbonic esters of a mixture of alcohols obtainable by reducing coco-nut oil.ALSO:Albumen degradation products or synthetic polypeptides are condensed with chlorocarbonic esters of aliphatic, cycloaliphatic, aliphatic-cycloaliphatic or aliphatic-aromatic mono- or poly-hydric alcohols containing at least five carbon atoms. The term "albumen degradation products" covers only the products obtainable by degrading albumens to the di- or tri-peptide stage, the treatment of simple aminoacids being excluded. Albuminous materials of which the degradation products may be used are gelatin, leather glue, hide glue, bone glue, horn waste, flesh waste, herring sperm, soya bean meal, wool, sericin, casein, or hydroxyethylation products of casein; the degradation may be effected with acid or alkaline solutions or with enzymes. Synthetic polypeptides which may replace the albumen degradation products are those obtainable by the condensation of glycine, alanine, sarcosine and other amino-acids. Suitable chlorocarbonic esters are those of hexyl, octyl, dodecyl, myristyl, cetyl, octodecyl and oleyl alcohols, octodecanediol, montanol, cyclohexanol, methylcyclohexanol, benzyl alcohol, cinnamic alcohol, and phenylcetyl alcohol, or of mixtures of alcohols such as are obtainable by hydrogenating oils, fats and waxes or by oxidizing paraffinic hydrocarbons; chlorocarbonic esters of substituted alcohols, e.g. alcohols containing halogen atoms or ester, ether or nitro groups, may also be used. The reaction products may be treated with ethylene oxide, to increase their solubility. The products are useful as washing and emulsifying agents in the treatment of textiles, leather and paper and in the foodstuff and pharmaceutical industries; in particular, they may be used for preventing precipitation when soaps are used in hard water and for making emulsions for dressing or waterproofing fabrics. The products may be used in admixture with other substances, the following being specified:--sulphite cellulose waste liquor; soaps, turkey red oil; alkylnaphthalenesulphonic acids; condensation products of higher carboxylic acids with amino- or oxy-alkylsulphonic acids: sulphuric esters of higher aliphatic alcohols; reaction products of ethylene oxide and organic hydroxy or amino compounds or carboxylic acids; glue; dextrin; starch; vegetable mucilages; organic solvents such as trichlorethylene, carbon tetrachloride, benzyl alcohol and cyclohexanol; oxidizing agents such as perborates or hydrogen peroxide; and salts such as common salt, phosphates, silicates and sodium sulphate.ALSO:Albumen degradation products or synthetic polypeptides are condensed with chlorocarbonic esters of aliphatic, cyclo-aliphatic, aliphatic-cycloaliphatic or aliphatic - aromatic mono-or poly-hydric alcohols containing at least five carbon atoms. The term "albumen degradation products" covers only the products obtainable by degrading albumens to the di- or tri-peptide stage, the treatment of simple aminoacids being excluded. Albuminous materials of which the degradation products may be used are gelatin, leather glue, hide glue, bone glue, horn waste, flesh waste, herring sperm, soya bean meal, wool, sericin, casein, of hydroxyethylation products of casein; the degradation may be effected with acid or alkaline solutions or with enzymes. Synthetic polypeptides which may replace the albumen degradation products are those obtainable by the condensation of glycine, alanine, sarcosine and other aminoacids. Suitable chlorocarbonic esters are those of hexyl, octyl, dodecyl, myristyl, cetyl, octodecyl and oleyl alcohols, octodecanediol, montanol, cyclohexanol, methyl-cyclohexanol, benzyl alcohol, cinnamic alcohol, and phenylcetyl alcohol, or of mixtures of alcohols such as are obtainable by hydrogenating oils, fats and waxes or by oxidizing paraffinic hydrocarbons; chlorocarbonic esters of substituted alcohols, e.g. alcohols containing halogen atoms or ester, ether or nitro groups may also be used. The products may be treated with ethylene oxide, to increase their solubility. The products are useful in the pharmaceutical industry, as emulsifying agents in the preparation of emulsions and ointments, and may be used in admixture with other emulsifying agents.
GB2705733A 1933-10-02 1933-10-02 Improvements in the manufacture and production of condensation products Expired GB425370A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2705733A GB425370A (en) 1933-10-02 1933-10-02 Improvements in the manufacture and production of condensation products

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2705733A GB425370A (en) 1933-10-02 1933-10-02 Improvements in the manufacture and production of condensation products

Publications (1)

Publication Number Publication Date
GB425370A true GB425370A (en) 1935-03-13

Family

ID=10253455

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2705733A Expired GB425370A (en) 1933-10-02 1933-10-02 Improvements in the manufacture and production of condensation products

Country Status (1)

Country Link
GB (1) GB425370A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2713575A (en) * 1952-04-01 1955-07-19 Eastman Kodak Co Process of reacting gelatin and oxidized casein with amyl chloroformate
US2972582A (en) * 1955-04-04 1961-02-21 Donald H Powers Cosmetic detergent composition
CN107558253A (en) * 2017-08-23 2018-01-09 四川省宜宾惠美线业有限责任公司 A kind of method that people's cotton fiber is dyed with reducing dye

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2713575A (en) * 1952-04-01 1955-07-19 Eastman Kodak Co Process of reacting gelatin and oxidized casein with amyl chloroformate
US2972582A (en) * 1955-04-04 1961-02-21 Donald H Powers Cosmetic detergent composition
CN107558253A (en) * 2017-08-23 2018-01-09 四川省宜宾惠美线业有限责任公司 A kind of method that people's cotton fiber is dyed with reducing dye
CN107558253B (en) * 2017-08-23 2020-01-10 四川省宜宾惠美线业有限责任公司 Method for dyeing rayon fibers by vat dyes

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