GB421332A - Improvements in or relating to the plastication of cellulose esters or ethers - Google Patents

Improvements in or relating to the plastication of cellulose esters or ethers

Info

Publication number
GB421332A
GB421332A GB34813/34A GB3481334A GB421332A GB 421332 A GB421332 A GB 421332A GB 34813/34 A GB34813/34 A GB 34813/34A GB 3481334 A GB3481334 A GB 3481334A GB 421332 A GB421332 A GB 421332A
Authority
GB
United Kingdom
Prior art keywords
cellulose derivative
plasticizer
solvent
substances
added
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB34813/34A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Acordis UK Ltd
Original Assignee
British Celanese Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by British Celanese Ltd filed Critical British Celanese Ltd
Publication of GB421332A publication Critical patent/GB421332A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/0008Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0016Plasticisers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Moulding-powders are made by agitating a cellulose ester or ether and a plasticizer in suspension in an aqueous medium in the presence of a water-soluble swelling agent for the cellulose derivative, said swelling agent having a boiling point not substantially above 170 DEG C. Suitable swelling agents are alcohols and ketones such as acetone, cyclohexanol, and cyclohexanone. Preferably, the cellulose derivative is treated in finely divided form obtained by grinding or precipitation, and the amount of aqueous medium is large, e.g. of the order of 4--25 times the weight of the cellulose derivative. In a modification, the cellulose derivative is dissolved in a solvent, for example, acetone, and water is added until incipient precipitation takes place, whereupon the solvent is evaporated until the liquid has little or no solvent action for either the cellulose derivative or the plasticizer. The plasticizer is then added and the whole stirred. If the plasticizer is solid it may be added in molten condition. In all cases the mixture is agitated for some time, e.g. for 20 minutes to one hour, preferably at a temperature of 35 to 100 DEG C. Additions may be made of other substances such as natural or synthetic resins, stabilizers, dyes, lakes, pigments, filling substances such as silica gel and wood flour, and substances reducing inflammability. The product may be moulded into sheets, slabs, rods, tubes, or other articles. Specification 319,073, [Class 2 (ii)], is referred to.ALSO:Moulding-powders are made by agitating a cellulose ester or ether and a plasticizer in suspension in an aqueous medium in the presence of a water-soluble swelling agent for the cellulose derivative, said swelling agent having a boiling point not substantially above 170 DEG C. Suitable swelling agents are alcohols and ketones such as acetone, cyclohexanol, and cyclohexanone. Preferably, the cellulose derivative is treated in finely divided form obtained by grinding or precipitation, and the amount of aqueous medium is large, e.g. of the order of 4-25 times the weight of the cellulose derivative. In a modification, the cellulose derivative is dissolved in a solvent, e.g. acetone, and water is added until incipient precipitation takes place, whereupon the solvent is evaporated until the liquid has little or no solvent action for either the cellulose derivative or the plasticizer. The plasticizer is then added and the whole stirred. If the plasticizer is solid it may be added in molten condition. In all cases the mixture is agitated for some time, e.g. for 20 minutes to one hour, preferably at a temperature of 35 to 100 DEG C. Additions may be made of other substances such as natural or synthetic resins, stabilizers, dyes, lakes, pigments, filling substances such as silica gel and wood flour, and substances reducing inflammability. The product may be moulded into sheets, slabs, rods, tubes, or other articles. Specification 319,073, [Class 70], is referred to.
GB34813/34A 1932-04-13 1933-04-13 Improvements in or relating to the plastication of cellulose esters or ethers Expired GB421332A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US421332XA 1932-04-13 1932-04-13

Publications (1)

Publication Number Publication Date
GB421332A true GB421332A (en) 1934-12-13

Family

ID=21920215

Family Applications (1)

Application Number Title Priority Date Filing Date
GB34813/34A Expired GB421332A (en) 1932-04-13 1933-04-13 Improvements in or relating to the plastication of cellulose esters or ethers

Country Status (1)

Country Link
GB (1) GB421332A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE898680C (en) * 1940-07-21 1953-12-03 Kurt Dr Bratring Method and device for the production of molding and injection molding compounds

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE898680C (en) * 1940-07-21 1953-12-03 Kurt Dr Bratring Method and device for the production of molding and injection molding compounds

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