GB400272A - New artificial oil-soluble resinous compositions - Google Patents
New artificial oil-soluble resinous compositionsInfo
- Publication number
- GB400272A GB400272A GB1171432A GB1171432A GB400272A GB 400272 A GB400272 A GB 400272A GB 1171432 A GB1171432 A GB 1171432A GB 1171432 A GB1171432 A GB 1171432A GB 400272 A GB400272 A GB 400272A
- Authority
- GB
- United Kingdom
- Prior art keywords
- oils
- soluble
- xylenol
- ethyl
- methyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G16/00—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00
- C08G16/02—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes
- C08G16/0212—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes with acyclic or carbocyclic organic compounds
- C08G16/0218—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes with acyclic or carbocyclic organic compounds containing atoms other than carbon and hydrogen
- C08G16/0237—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes with acyclic or carbocyclic organic compounds containing atoms other than carbon and hydrogen containing sulfur
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Oil-soluble resinous compositions prepared by condensing the methyl or ethyl ethers of 1 : 3 : 5-xylenol with formaldehyde or other compounds containing a reactive methylene group in an acid medium in the presence or absence of a solvent are converted into coating compositions by mixing with drying oils, semidrying oils or nitrocellulose, In examples 1 : 3 : 5-xylenol methyl or ethyl ether is condensed with formaldehyde in the presence of hydrochloric acid and the product after heating with tung oil is dissolved in mineral spirits containing cobalt linoleate. The condensation product is soluble in linseed, tung, perilla, soya bean oils, stand and bodied oils and is compatible with nitrocellulose.ALSO:Oil-soluble resinous compositions are prepared by condensing the methyl or ethyl ether of 1 : 3 : 5-xylenol with formaldehyde or other compounds containing a reactive methylene group in an acid medium. The products may be converted into coating compositions by mixing with drying or semi-drying oils or nitro-cellulose. Suitable acids are hydrochloric, sulphuric, trichloracetic, acetic, oxalic, or citric acid or an acid-reacting substance such as potassium hydrogen sulphate. A solvent, such as methylated spirit, may be used. The resins are soluble in ethyl and butyl acetates, ethylene glycol monoethyl ether, cyclohexanol, diacetone alcohol, benzene and xylene. In examples: (1) 1 : 3 : 5-xylenol methyl ether is condensed with formaldehyde in the presence of hydrochloric acid. To obtain a varnish the product is heated with tung oil and dissolved in mineral spirits containing cobalt linoleate. (2) The raw materials of example (1) are condensed to give a resin soluble in linseed, tung, perilla, soya bean oils and stand and bodied oils. It is also soluble in acetone, diacetone alcohol, benzene, xylene, ethyl and butyl acetates, ethylene glycol, monoethyl ether, cyclohexanol, hot butyl alcohol, hot turpentine and hot mineral spirits and it is insoluble in methylated spirits. It forms clear films with nitrocellulose. By heating the resins its melting point may be raised. (3) 1 : 3 : 5-xylenol ethyl ether may replace the methyl ether in claim (1).
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1171432A GB400272A (en) | 1932-04-23 | 1932-04-23 | New artificial oil-soluble resinous compositions |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1171432A GB400272A (en) | 1932-04-23 | 1932-04-23 | New artificial oil-soluble resinous compositions |
Publications (1)
Publication Number | Publication Date |
---|---|
GB400272A true GB400272A (en) | 1933-10-23 |
Family
ID=9991333
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1171432A Expired GB400272A (en) | 1932-04-23 | 1932-04-23 | New artificial oil-soluble resinous compositions |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB400272A (en) |
-
1932
- 1932-04-23 GB GB1171432A patent/GB400272A/en not_active Expired
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