GB358508A - Improvements in or relating to disinfection and to destruction of insect pests - Google Patents

Improvements in or relating to disinfection and to destruction of insect pests

Info

Publication number
GB358508A
GB358508A GB2708230A GB2708230A GB358508A GB 358508 A GB358508 A GB 358508A GB 2708230 A GB2708230 A GB 2708230A GB 2708230 A GB2708230 A GB 2708230A GB 358508 A GB358508 A GB 358508A
Authority
GB
United Kingdom
Prior art keywords
bis
amine
hydroxy
hydroxyphenyl
oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2708230A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IG Farbenindustrie AG
Original Assignee
IG Farbenindustrie AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IG Farbenindustrie AG filed Critical IG Farbenindustrie AG
Priority to GB2708230A priority Critical patent/GB358508A/en
Publication of GB358508A publication Critical patent/GB358508A/en
Expired legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02Amines; Quaternary ammonium compounds
    • A01N33/08Amines; Quaternary ammonium compounds containing oxygen or sulfur
    • A01N33/10Amines; Quaternary ammonium compounds containing oxygen or sulfur having at least one oxygen or sulfur atom directly attached to an aromatic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N31/00Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
    • A01N31/08Oxygen or sulfur directly attached to an aromatic ring system
    • A01N31/16Oxygen or sulfur directly attached to an aromatic ring system with two or more oxygen or sulfur atoms directly attached to the same aromatic ring system
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09GPOLISHING COMPOSITIONS; SKI WAXES
    • C09G1/00Polishing compositions
    • C09G1/06Other polishing compositions
    • C09G1/08Other polishing compositions based on wax

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Preparations serving as preservatives, fungicides, disinfectants and insecticides, comprise a bis-(hydroxyaryl)-oxide, or -amine, or -alkylamine mixed with a solid, semi-solid, or liquid diluent or carrier. The active compounds may contain further substituents such as halogen, alkyl, aralkyl, aryl, or additional hydroxy or alkoxy groups and may be used in the form of salts. The preparations may be used in the manufacture of antiseptic wax or like polishes. Specified diluents are talcum, soap, glycerol, wool fat, petroleum jelly, liquid paraffin, yellow and other waxes, alcohol, alkalies, ammonia, water, and isobutylnaphthalene sulphonic acid. Specification 349,004 is referred to. According to an example a disinfectant polish is prepared by adding a mixture of bis-(dichloro-4-hydroxyphenyl) oxide and yellow wax to an ordinary polish base. The yellow wax may be replaced by other waxes or solvents such as liquid paraffin. Numerous other specific active compounds of the general classes referred to are mentioned.ALSO:Compounds of the general formula (HO.Ar)2X, where Ar is an aryl residue such as phenyl or naphthyl and X is oxygen or a nitrogen atom attached to hydrogen or an alkyl group are used as disinfectants, insecticides, and fungicides. The compounds may contain further substituents such as halogen, alkyl, aralkyl, aryl, or additional hydroxy or alkoxy groups and may be used in the form of salts. The bis-(hydroxyaryl)-oxides are obtainable by condensing an alkali salt of a hydroxy-alkoxy-aryl compound with an alkoxy-aryl halogenide and splitting off the alkyl groups in the customary manner from the bis-(alkoxyaryl)-oxides obtained. Further substituents may be introduced before or after the alkyl groups have been split off. The bis-(hydroxyaryl)-amines are obtainable by condensing an alkoxyaryl-amine, preferably in the form of its acetyl derivative, with an alkoxyaryl-halogenide and then splitting off the alkyl groups from the product. Substituents may be introduced as before. Of the specific compounds referred to: bis-(dichloro-4-hydroxyphenyl)-oxide is obtained by reacting upon 1 mol. of bis-(4-hydroxyphenyl)-oxide with 8 gram atoms of chlorine; bis-(4-hydroxy-dichlorophenyl)-amine and the corresponding methylamine are prepared by reacting on 1 mol. of bis-(4-hydroxyphenyl)-amine or -methylamine with 8 gram atoms of chlorine; bis - (4 - hydroxy - 3.5 - dibromophenyl) - amine or -ethylamine are obtained by brominating the corresponding unsubstituted compounds; bis-(2-hydroxy-bromophenyl)-amine is prepared by condensation of ortho-bromo-anisol with ortho-N-acyl-anisidine, brominating the bis-(2-methoxyphenyl)-acyl-amine obtained to form bis-(2-methoxy-bromophenyl)-acyl-amine, and subsequently splitting off the acyl and methyl groups. Other compounds definitely referred to are bis-(2-hydroxy-5-bromophenyl)-oxide, bis-(4-hydroxyphenyl)-amine, bis - (2 - hydroxy - 5 - chlorophenyl) - oxide, bis-(2 -hydroxy - 3 : 5-dichlorophenyl) - oxide, the corresponding 3 : 5-dibromo compound, bis-(2-hydroxyphenyl)-oxide, bis-(3-hydroxyphenyl)-oxide, bis-(4-hydroxyphenyl)-oxide, bis-(2-hydroxyphenyl)-amine, bis - (3 - hydroxyphenyl) - amine, bis - (2 - hydroxynaphthyl)-1-amine, 2-hydroxy-41-hydroxydiphenyl-amine and corresponding N-alkyl compounds, 41 - hydroxy - 4 - hydroxy - 3 : 5 - dibromo - diphenyl - N - methylamine, 4 : 41 - dihydroxy - 3 : 6-dimethyl-diphenylamine, 4:41-dihydroxy-21-methyldiphenylamine, 4 : 41 - dihydroxy - 3 : 5 - dichloro - di - phenylamine, and alkali compounds of some of these.ALSO:Preparations serving as preservatives, fungicides, disinfectants and insecticides, comprise a bis-(hydroxyaryl)-oxide, or -amine, or -alkylamine mixed with a solid, semisolid, or liquid diluent or carrier. The active compounds may contain further substituents such as halogen, alkyl, aralkyl, aryl, or additional hydroxy or alkoxy groups and may be used in the form of salts. The preparations may be used for treating plants, seeds, fabrics wood, skins and catgut, for combating pests on domestic animals, and in the manufacture of cosmetic ointments or powders, tooth-washes, and antiseptic wax or like polishes. Specified diluents are talcum, soap, glycerol, wool fat, petroleum jelly, liquid paraffin, yellow and other waxes, alcohol, alkalies, ammonia, water, and isobutyl-naphthalene sulphonic acid. Numerous examples giving proportions are given in the Specification. Specification 349,004 is referred to. The bis-(hydroxyaryl)-oxides are obtainable by condensing an alkali salt of a hydroxy-alkoxy-aryl compound with an alkoxy-aryl halogenide and splitting off the alkyl groups in the customary manner from the bis-(alkoxyaryl)-oxides obtained. Further substituents may be introduced before or after the alkyl groups have been split off. The bis-(hydroxyaryl)-amines are obtainable by condensing an alkoxyaryl-amine, preferably in the form of its acetyl derivative, with an alkoxyaryl halogenide and then splitting off the alkyl groups from the product. Substituents may be introduced as before. Of the specific compounds referred to-bis-(dichloro-4-hydroxyphenyl)-oxide is obtained by reacting upon 1 mol. of bis-(4-hydroxyphenyl)-oxide with 8 gram atoms of chlorine; bis-(4-hydroxy-dichlorophenyl)-amine and the corresponding methylamine are prepared by reacting on 1 mol. of bis-(4-hydroxyphenyl)-amine or -methylamine with 8 gram atoms of chlorine; bis-(4-hydroxy-3.5-dibromophenyl)-amine or -ethylamine are obtained by brominating the corresponding unsubstituted compounds; bis-(2-hydroxy-bromophenyl)-amine is prepared by condensation of ortho-bromo-anisol with ortho-N-acyl-anisidine, brominating the bis-(2-methoxyphenyl)-acyl-amine obtained to form bis-(2 methoxy-bromophenyl)-acyl-amine, and subsequently splitting off the acyl and methyl groups. Other compounds definitely referred to are bis-(2 - hydroxy-5-bromo-phenyl) oxide, bis-(4-hydroxyphenyl)-amine, bis-(2-hydroxy-5-chlorophenyl)-oxide, bis-(2-hydroxy-3 : 5 dichlorophenyl) oxide, the corresponding 3 : 5 dibromo compound, bis-(2 hydroxyphenyl) oxide, bis (3 hydroxyphenyl) oxide, bis - (4 - hydroxyphenyl) oxide, bis-(2-hydroxyphenyl) amine, bis-(3-hydroxyphenyl) amine, bis-(2 hydroxynaphthyl)-1-amine, 2-hydroxy-41-hydroxy-diphenyl-amine and corresponding N-alkyl compounds, 41-hydroxy-4-hydroxy-3.5-dibromo-diphenyl-N-methylamine, 4-41-dihydroxy-3 : 6-dimethyl-diphenylamine, 4-41 - dihydroxy-21-methyl-diphenylamine, 4-41dihydroxy-3 : 5-dichlorodiphenylamine, and alkali compounds of some of these.
GB2708230A 1930-06-24 1930-06-24 Improvements in or relating to disinfection and to destruction of insect pests Expired GB358508A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2708230A GB358508A (en) 1930-06-24 1930-06-24 Improvements in or relating to disinfection and to destruction of insect pests

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2708230A GB358508A (en) 1930-06-24 1930-06-24 Improvements in or relating to disinfection and to destruction of insect pests

Publications (1)

Publication Number Publication Date
GB358508A true GB358508A (en) 1931-09-24

Family

ID=10253872

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2708230A Expired GB358508A (en) 1930-06-24 1930-06-24 Improvements in or relating to disinfection and to destruction of insect pests

Country Status (1)

Country Link
GB (1) GB358508A (en)

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