GB352956A - Process for the manufacture of substantive dyeing disazo dyestuffs containing copper - Google Patents
Process for the manufacture of substantive dyeing disazo dyestuffs containing copperInfo
- Publication number
- GB352956A GB352956A GB1182930A GB1182930A GB352956A GB 352956 A GB352956 A GB 352956A GB 1182930 A GB1182930 A GB 1182930A GB 1182930 A GB1182930 A GB 1182930A GB 352956 A GB352956 A GB 352956A
- Authority
- GB
- United Kingdom
- Prior art keywords
- acid
- naphthol
- copper
- manufacture
- dianisidine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B45/00—Complex metal compounds of azo dyes
- C09B45/02—Preparation from dyes containing in o-position a hydroxy group and in o'-position hydroxy, alkoxy, carboxyl, amino or keto groups
- C09B45/24—Disazo or polyazo compounds
- C09B45/28—Disazo or polyazo compounds containing copper
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Abstract
Disazo dyes, soluble copper compounds of.-Disazo dyestuffs from a tetrazotized 4 : 41-diaminodiphenyl containing an alkoxy group in o-position to each amino group coupled with J. acid or a derivative thereof (1 mol.) and with a naphthol disulphonic acid or nuclear substituted alkoxy or halogen derivative thereof (1 mol.) are treated with copper or an agent yeilding copper at elevated temperature until the o-alkyloxy groups are split up. The end-point is determined when the shade no longer changes. The products dye cotton, silk, and viscose blue. In examples (1) the dyestuff 1-naphthol-3 : 6-disulpho acid \sM dianisidine --> N-(p-methoxyphenyl)-J acid is autoclaved with aqueous copper sulphate, (2) the dyestuff 8-ethoxy-1-naphthol-3 : 6-disulpho acid \sM dianisidine --> N-phenyl-J acid is refluxed with aqueous copper sulphate.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1182930A GB352956A (en) | 1930-04-14 | 1930-04-14 | Process for the manufacture of substantive dyeing disazo dyestuffs containing copper |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1182930A GB352956A (en) | 1930-04-14 | 1930-04-14 | Process for the manufacture of substantive dyeing disazo dyestuffs containing copper |
Publications (1)
Publication Number | Publication Date |
---|---|
GB352956A true GB352956A (en) | 1931-07-14 |
Family
ID=9993460
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB1182930A Expired GB352956A (en) | 1930-04-14 | 1930-04-14 | Process for the manufacture of substantive dyeing disazo dyestuffs containing copper |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB352956A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2424066A (en) * | 1941-02-18 | 1947-07-15 | Chem Ind Basel | Disazo dyes from dihydroxy benzidine |
DE889662C (en) * | 1949-08-05 | 1953-09-14 | Ciba Geigy | Process for the preparation of copper-containing disazo dyes |
DE1544464B1 (en) * | 1963-11-08 | 1970-10-22 | Sandoz Ag | Process for the production of water-soluble, metallizable disazo and trisazo dyes and their heavy metal complexes |
EP0110076A1 (en) * | 1982-10-26 | 1984-06-13 | Bayer Ag | Use of disazo copper complex dyestuffs in the dyeing of synthetic and natural materials |
WO2002053650A2 (en) * | 2000-12-28 | 2002-07-11 | Ciba Specialty Chemicals Holding Inc. | Use of copper complexes of disazo dyes for dyeing natural and synthetic material |
-
1930
- 1930-04-14 GB GB1182930A patent/GB352956A/en not_active Expired
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2424066A (en) * | 1941-02-18 | 1947-07-15 | Chem Ind Basel | Disazo dyes from dihydroxy benzidine |
US2426977A (en) * | 1941-02-18 | 1947-09-09 | Chem Ind Basel | Disazo dyes from dihydroxy benzidines |
DE889662C (en) * | 1949-08-05 | 1953-09-14 | Ciba Geigy | Process for the preparation of copper-containing disazo dyes |
DE1544464B1 (en) * | 1963-11-08 | 1970-10-22 | Sandoz Ag | Process for the production of water-soluble, metallizable disazo and trisazo dyes and their heavy metal complexes |
EP0110076A1 (en) * | 1982-10-26 | 1984-06-13 | Bayer Ag | Use of disazo copper complex dyestuffs in the dyeing of synthetic and natural materials |
US4514188A (en) * | 1982-10-26 | 1985-04-30 | Bayer Aktiengesellschaft | Use of disazo-copper complex dyestuffs for dyeing natural and synthetic materials |
WO2002053650A2 (en) * | 2000-12-28 | 2002-07-11 | Ciba Specialty Chemicals Holding Inc. | Use of copper complexes of disazo dyes for dyeing natural and synthetic material |
WO2002053650A3 (en) * | 2000-12-28 | 2002-09-26 | Ciba Sc Holding Ag | Use of copper complexes of disazo dyes for dyeing natural and synthetic material |
US6984723B2 (en) | 2000-12-28 | 2006-01-10 | Ciba Specialty Chemicals Corporation | Use of copper complexes of disazo dyes for dyeing natural and synthetic material |
CN1309789C (en) * | 2000-12-28 | 2007-04-11 | 西巴特殊化学品控股有限公司 | Use of copper complexes of disazo dyes for dyeing natural and synthetic material |
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