GB2595756A - Foamable composition - Google Patents

Abstract

A composition comprising (a) at least one disaccharide and (b) at least one amphoteric surfactant, wherein the composition is free from synthetic, film-forming polymers is provided. The at least one disaccharide is preferably saccharose. The composition may further comprise at least one alcohol, preferably selected from the group ethanol, n-propanol, isopropanol, n-butanol, tert-butanol, and iso-butanol. The composition may further comprise at least one modified and/or unmodified, natural protein hydrolysate. The use of the composition for temporary shaping and/or shape-retention of keratinous fibres, preferably human head hair is provided

Description

FOAMABLE COMPOSITION

TECHNICAL FIELD

100011 The present invention relates a foamable composition and its use for temporary shaping of keratinous fibers.

BACKGROUND

100021 Composition for temporary shaping of keratinous fibers, preferably of hair, are known under the designation Styling compound or products and are usually used in the form of gels, pomades, wax, foam, mousse and spray.

[0003] In particular, gels, pomades and waxes are mainly applied by hand to the keratinous fibers, bringing them directly into the desired shape. Keratinous fibers comprise all fibers containing keratin, such as wool, furs and feathers, especially human hair, with particular emphasis on human hair. During a temporary reshaping of keratinous fibers, no chemical (oxidation and reduction) process takes place. Instead, the fibers are shaped by applying styling products containing firming agents such as waxes and/or polymers.

100041 Styling foam and styling mousse are often packed in spray containers by using fuel gases. Furthermore, they often contain synthetic polymers to fix hair styles, while thereby not adversely affecting the shine and the healthy, natural appearance of the hair. Synthetic polymers are often manufactured from synthetic monomers, which are extracted by refining fossil raw materials, such as mineral oil, involving high energy consumption.

[0005] As part of a conscious respect for the nature and the finite availability of raw materials, the end consumers are increasingly asking for natural, sustainable products, produced using regenerative raw materials, which have been produced as little energy as possible.

[0006] Microplastic constituents are particularly in sharp focus for the end users. Contrary to the original definition of microplastics, even soluble synthetic materials are also being increasingly regarded as such. This term thus covers all non-biodegradable polymers.

100071 End users are also accepting the use of fuel gases less and less and the demand for alternative products from dispensers is increasing 100081 Current research therefore aims to develop styling foams and styling mousses that have the same foaming capacity as the known products, ensure a firmer and longer stay and fixing of the hairstyle and do not leave behind any visible film on the hair surface, which makes the hair look raw and dull.

BRIEF SUMMARY

[0009] The object of the present disclosure is solved by the subject-matter of the independent claims, wherein further embodiments are incorporated in the dependent claims.

DETAILED DESCRIPTION

[0010] The following detailed description is merely exemplary in nature and is not intended to limit the disclosure or the application and uses of the subject matter as described herein. Furthermore, there is no intention to be bound by any theory presented in the preceding background or the following detailed description.

[0011] The objective of the present invention, is, therefore, to provide a foamable compound for temporary shaping of keratinic fibers, which contains natural ingredients, thereby exhibiting the same foaming capacity and the same styling properties as those achieved with compounds formulated with fuel gases.

[0012] The objective is achieved by a composition comprising A) at least one disaccharide and B) at least one amphoteric surfactant, wherein the composition is free from synthetic. film-forming polymers.

Composition designates a cosmetic compound, which can be formulated in common forms of compounds, for example such as gel, wax, paste, foam, mousse, emulsions, lotion or clay, the preferred compound is a foam or mousse, the composition formulated as foam is even more preferred.

[0013] The compound can be aqueous or aqueous-alcoholic. The cosmetically compatible carrier component contained in the composition is water, preferably distilled water, specifically distilled water without H202. The proportion of water in the composition is preferably from about 60 to about 98% by weight, particularly preferably from about 75 to about 96% by weight, very preferably from about 83 to about 94% by weight, even more preferably from about 88 to about 93% by weight, based on the total proportion of the composition.

100141 In a particularly preferred embodiment of the invention, the composition comprises sufficient water to complete the remaining components contained in the composition to about 100% by weight, measured on the total weight of the composition, also referred to as "ad. 100". The sum of all components of the composition is about 100% by weight, based on the total proportion of the composition.

100151 In the sense of the invention, disaccharide designates double sugars that are built from two monosaccharides selected fromglucose, fructose, galactose, Rhamnose and xylose Preferred disaccharides are selected from saccharose, lactose, lactulose, trehalose, maltose, maltulose, cellobiose, gentobiose, isoma1tose, isomaltulose, laminaribiose, melibiose, neohesperi dose, neotrehalose, nigerose, rutinose, sambubiose, sophorose and mixtures thereof, particularly from saccharose, lactose, maltose, trehalose and mixtures thereof 100161 Preferably, the at least one disaccharide comprises saccharose (INCI: Sucrose). In a preferred embodiment, the at least one disaccharide is Saccharose (INCI: Sucrose).

100171 Preferably the at least one amphoteric surfactant is selected from alkylbetaines, alkyl am i dobetai n es, ami nopropi onates, ami noglycinates, imidazoliniumbetaines, sulfobetaines and mixtures thereof 100181 Amphoteric or also zwitterionic surfactants carry both a cationic and an anionic charge in the molecule. Preferably, amphoteric surfactants have at least one quaternary ammonium group and at least one -000(-) -or -S03(-) -group, in addition to a preferably C8-C24 alkyl or acyl group, in the molecule. They are also capable of forming inner salts. Particularly preferred amphoteric surfactants are betaines such as the N-alkyl-N,Ndimethylammonium glycinate, for example the cocoalkyl-dimethylammonium glycinate, Nacylaminopropyl-N,N-dimethylammonium glycinate, for example, cocoacylaminopropyl dimethyl ammonium glycinate, and 2-alkyl-3-carboxymethy1-3-hydroxyethyl imidazolines each having 8 to 18 C atoms in the alkyl or acyl group, and cocoacylaminoethyl hydroxyethyl carboxymethyl glycinate. A preferred amphoteric surfactant is the fatty acid amide derivative known under the INCI name cocamidopropyl betaine. With regard to the structure and manufacture of these substances, reference is made to relevant reviews, e.g. J.Falbe (ed.), "Surfactants in Consumer Products", Springer Verlag, Berlin, 1987, pp. 54424 or J.Falbe (ed.), "Katalysatoren, Tenside und Mineraloladditive/Catalysts, surfactants and mineral oil additives", Thieme Verlag, Stuttgart, 1978, pp. 123-217.

100191 The composition is free from synthetic, film-forming polymers. Synthetic film-forming polymers are all polymers that leave a continuous film when dried, especially on the hair. Furthermore, film-forming polymers are polymers which, when used in from about 0.01 to about 20% by weight aqueous, alcoholic or aqueous-alcoholic solution, are capable of depositing a transparent polymer film, particularly on the hair.

[0020] Preferably, the composition does not contain any synthetic, film-forming polymer, especially no homopolymer or copolymer, comprising monomer units, selected from siloxane, vinyl pyrrolidone, vinyl caprolactam, N-vinyl form amide vinyl ester, such as vinyl acetate, vinyl alcohol, acryl amide, methacryl amide, Cl to C7 alkyl acryl amide, Cl to C7 dialkyl Cl to C7 alkyl methacryl amide, Cl to C7 di alkyl methacryl amide, Cl to C7 alkyl acryl ate, acrylic acid, propylene glycol, maleic acid, styrol, itaconic acid and mixtures thereof [0021] The composition is particularly preferred to be free of synthetic, film-forming polymers selected from vinylpyrrilidon/vinylester-copolymers, polyvinylpyrrilidone, siloxane, glycosidic substituted silicones, homopolyacrylic acid and polyvinyl pyrrolidones, especially actylamide/ammonium acrylate copolymer, acrylamides/DMAPA acrylates/methoxy peg methacrylate copolymer, acrylamidopropyltrimonium chloride/acrylamide copolymer, acrylamidopropyltrimonium chloride/acrylates copolymer, acrylates/acetoacetoxyethyl methacrylate copolymer, acrylates/acrylamide copolymer, acrylates/ammonium methacrylate copolymer, acrylates/t-butyl acrylamide copolymer, acrylates/C1-2 succinates/hydroxyacrylates copolymer, acrylates/lauryl acrylate/stearyl acrylate/ethylamine oxide methacrylate copolymer, acrylates/octylacrylamide copolymer, actylates/octylacrylamide/diphenyl amodimethi cone copolymer, acrylates/stearyl acrylate/ethylamine oxide methacrOate copolymer, acrylates/VA copolymer, acrylates/VP copolymer, adipic acid/diethylenetriamine copolymer, adipic acid/dimethylaminohydroxypropyl di ethyl enetri amine copolymer, adipic acid/epoxypropyl diethyl enetriamine copolymer, adipic acid/isophthalic acid/neopentyl glycol/trimethylolpropane copolymer, ally! stearate/VA copolymer, aminoethylacrylate phosphate/acrylates copolymer, aminoethylpropanediol-acrylates/acrylamide copolymer, am i noethyl propanedi ol -A M PD-actyl ates/di acetoneacrylami de copolymer, ammonium VA/acrylates copolymer, AN/1PD -acryl ates/di acetoneacryl amide copolymer, AMPacrylates/allyl methacrylate copolymer, ANIP-acrylates/C1-18 alkyl acrylates/C1-8 alkyl acrylamide copolymer, AMP-acrylates/diacetoneacrylamide copolymer, AMPacrylates/dimethylaminoethylmethacrylate copolymer, bis-butyloxyamodimethicone/PEG-60 copolymer, butyl acrylate/ethylhexyl methacrylate copolymer, butyl acrylate/hydroxypropyl dimethicone acrylate copolymer, butylated PVP, butyl ester of ethylene/NIA copolymer, butyl ester of PVM/M A copolymer, calcium/sodium PV M/M A copolymer, diethyl ene glycolamine/epichlorohydrin/piperazine copolymer, dimethicone cross polymer, diphenyl amodimethi cone, ethyl ester von PVIVENIA copolymer, isobutylene/ethylmaleimide/hydroxyethylmaleimide copolymer, isobutylene/MA copolymer, isobutylmethacrylate/bis-hydroxypropyl dimethicone acrylate copolymer, isopropyl ester of PVM/MA copolymer, lauryl actyl ate crosspolymer, lauryl methacryl ate/glycol dimethacryl ate crosspolymer, MEA-sulfite, methacrylic acid/sodium acrylamidomethyl propane sulfonate copolymer, methacryloyl ethyl betaine/acrylates copolymer, octylacrylamide/ actylates/ butyl aminoethyl methacrylate copolymer, PEG/PPG-25/25 dimethicone/acrylates copolymer, PEG-8/SNIDI copolymer, polyacrylamide, polyacrylate-6, polybutylene terephthalate, polyester-1, polyethylacrylate, polyethylene terephthalate, polymethacryloyl ethyl betaine, polypentaerythrityl terephthalate, pol yperfluoroperhydroph en an thren e, polysili cone-9, polyurethane-1, polyurethane-6, polyurethane-10, polyvinyl acetate, polyvinyl butyral, polyvinylcaprolactam, polyvinylformamide, polyvinyl imidazolinium acetate, polyvinyl methyl ether, potassium butyl ester of PVM/MA copolymer, potassium ethyl ester of PVNITMA copolymer, PPG-70 polyglyceryl-10 ether, PPG-12/SWIDI copolymer, PPG-51/SMDI copolymer, PPG-10 sorbitol, PVM/MA copolymer, PVP, PVPNA/itaconic acid copolymer, PVP/VA/vinyl propionate copolymer, sodium butyl ester of PVM/MA copolymer, sodium ethyl ester of PVM/MA copolymer, sodium polyacrylate, terephthalic acid/isophthalic acid/sodium isophthalic acid sulfonate/glycol copolymer, trim ethyl ol propane triaciylate, tri m ethyl siloxysilyl carbamoyl pullul an, VA/crotonates copolymer, VA/crotonates/methacryloxybenzophenone-1 copolymer, VA/crotonates/vinyl neodecanoate copolymer, VA/crotonates/vinyl propionate copolymer, VA/DBM copolymer. VA/vinyl butyl benzoate/crotonates copolymer, vinyl amine/vinyl alcohol copolymer, vinyl caprolactam/VP/dimethylaminoethyl methacrylate copolymer, VP/acrylates/lauryl methacrylate copolymer, VP/dimethylaminoethylmethacrylate copolymer, VP/DMAPA acrylates copolymer, vp/hexadecene copolymer, VP/VA copolymer, VP/vinyl caprolactam/DMAPA acrylates copolymer and styrene/VP copolymer, polyimides, such as polyimide-1..

[0022] Free from synthetic, film-forming polymers, in the sense of the invention, means that the proportion of the synthetic, film-forming polymers in the composition amounts to maximum about 0.5% by weight, preferably maximum about 0.25% by weight, especially preferred maximum about 0.1% by weight, still more preferred maximum about 0.05% by weight, even more preferred about 0.0% by weight in relation to the total amount of the composition.

[0023] The composition preferably contains at least one alcohol, preferably at least one aliphatic, branched or unbranched, monohydric alcohol, with 1 to 9, preferably with 2 to 4 C-atoms, even more preferred selected from the ethanol, n-propanol, isopropanol, n-butanol, tertbutanol and isobutanol group.

[0024] The composition preferably contains the at least one alcohol in a proportion of from about 1.0 to about 30.0% by weight, preferably from about 2.0 to about 20.0% by weight, particularly preferably from about 3.0 to about 10.0% by weight, even more preferably from about 3.5 to about 7.0% by weight, based on the total proportion of the composition.

[0025] The composition preferably features a pH value ranging from about 3.0 to about 6.0, more preferably from about 3.5 to about 5.5, especially preferably from about 4.0 to about 5.0, even more specifically about 4.5.

[0026] The composition can contain a means for adjusting the pH value. Preferred agents are for example primary amino alcohols such as aminomethyl propanol (]NCI), which is commercially available under the name AMP-ULTRA© PC, for example AMP-ULTRA© PC 2000. Other pH adjusting agents may be selected from alkaline hydroxides, in particular sodium hydroxide and potassium hydroxide, organic acids such as lactic acid, citric acid, hydrochloric acid, sulphuric acid, phosphoric acid, adipic acid, malic acid, succinic acid, succinic acid, tartaric acid or malic acid, in particular tetrahydroxypropyl ethylenediamine known under the trade names Neutrol lE and triethylamine (TEA).

[0027] Preferably, the composition contains at least one organic acid for adjusting the pH value, preferably at least one mono-, di-or tri-carboxylic acid with 2 to 10 C atoms, preferably with 2 to 8 C atoms, especially preferably with 3 to 6 C atoms, quite specifically preferably selected from citric acid, maleic acid, lactic acid, glyoxylic acid, glyceric acid, salicylic acid, gluconic acid and mixtures thereof [0028] The proportion of the agent for adjustment in the pH value in the composition is preferably from about 0.01 to about 3.5% by weight, particularly preferably from about 0.03 to about 2.5% by weight, quite particularly preferably from about 0.05 to about 2.0% by weight, even more preferably from about 0.07 to about 1.7% by weight, based on the total proportion of the composition.

[0029] The composition preferably contains the at least one disaccharide in a proportion of from about 1.0 to about 15.0% by weight, preferably from about 1.5 to about 10.0% by weight, even more preferably from about 2.0 to about 7.0% by weight, specifically from about 2.5 to about 5.0% by weight, based on the total proportion of the composition.

[0030] The composition preferably contains the at least one amphoteric surfactant in a proportion of from about 0.01 to about 2.0% by weight, preferably from about 0.05 to about 1.0% by weight, even more preferably from about 01 to about 0.8% by weight, specifically preferably from about 0.2 to about 0.6% by weight, based on the total proportion of the composition.

[0031] The composition preferably contains at least one modified and/or unmodified, natural protein hydrolysate.

[0032] The composition preferably contains at least one protein hydrolysate and/or one protein hydrolysate derivative.

[0033] Protein hydrolysates are product mixtures obtained by acidic, basic or enzymatic catalysed degradation of proteins. According to the invention, the term protein hydrolysates also includes total hydrolysates as well as individual amino acids and their derivatives and mixtures of different amino acids. The molecular weight of the protein hydrolysates that can be used according to the invention is between about 75, the molecular weight for glycine, and about 200,000 Dalton, the molecular weight is preferably from about 75 to about 50,000 and most preferably from about 75 to about 20,000 Dalton.

[0034] Furthermore, the used protein hydrolysates can be of plant, animal or marine origin.

Animal protein hydrolysates include elastin, collagen, keratin, silk and milk protein hydrolysates, which may also be in the form of salts. Such products are marketed under the trademarks Dehylan® (Cognis), Promois® (Interorgana), Collapuron® (Cognis), Nutrilan® (Cognis), Gelita-Sol® (Deutsche Gelatine Fabriken Stoess & Co), Lexein0 (Inolex) and Kerasol® (Croda). Protein hydrolysates of plant origin are preferred, such as soya, almond, rice, peas, potato and wheat protein hydrolysates, preferably wheat protein, almond protein and their mixtures. Such products are available under the trademarks Gluadin® (Cognis), DiaMin® (Diamalt), Lexein® (Inolex) and Crotein® (Croda).

[0035] Cationized protein hydrolysates can also be used, whereby the underlying protein hydrolysate can be derived from animals, for example from collagen, milk or keratin, from plants, for example from wheat, corn, rice, potatoes, soy or almonds, from marine life forms, for example from fish collagen or algae, or from biotechnologically produced protein hydrolysates. The protein hydrolysates underlying the cationic derivatives can be obtained from the corresponding proteins by chemical, especially alkaline or acid hydrolysis, by enzymatic hydrolysis and/or a combination of both types of hydrolysis. The hydrolysis of proteins usually results in a protein hydrolysate with a molecular weight distribution of about 100 Dalton up to several thousand Dalton. Preferred are those cationic protein hydrolysates whose underlying protein fraction has a molecular weight of from about 100 to about 25000 Dalton, preferably from about 250 to about 5000 Dalton. Furthermore, cationic protein hydrolysates are quatemized amino acids and mixtures thereof Quatemization of the protein hydrolysates or amino acids is often carried out using quaternary ammonium salts such as N,Ndi m ethyl -N-(n-alkyl)-N-(2-hydroxy-3 -chl oro-n-propy1)-amm oni um halides. Furthermore, the cationic protein hydrolysates can also be further derivatised. Typical examples of the cationic protein hydrolysates and derivatives are the products known under the INCI designations and commercially available: Cocodimonium Hydroxypropyl Hydrolyzed Collagen, Cocodim opni um Hydroxypropyl Hydrolyzed Casein, Cocodimonium Hydroxypropyl Hydrolyzed Collagen, Cocodimonium Hydroxypropyl Hydrolyzed Hair Keratin, Cocodimonium Hydroxypropyl Hydrolyzed Keratin, Cocodimonium Hydroxypropyl Hydrolyzed Rice Protein, Cocodimonium Hydroxypropyl Hydrolyzed Silk, Cocodimonium Hydroxypropyl Hydrolyzed Soy Protein, Cocodimonium Hydroxypropyl Hydrolyzed Wheat Protein, Cocodimonium Hydroxypropyl Silk Amino Acids, Hydroxypropyl Arginine Lauryl/Myristyl Ether HC1, Hydroxypropyltrimonium Gelatin, Hydroxypropyltrimonium Hydrolyzed Casein, Hydroxypropyltrimonium Hydrolyzed Collagen, Hydroxypropyltrimonium Hydrolyzed Conchiolin Protein, Hydroxypropyltrimonium Hydrolyzed keratin, Hydroxypropyltrimonium Hydrolyzed Rice Bran Protein, Hydroxyproypltrimonium Hydrolyzed Silk, Hydroxypropyltrimonium Hydrolyzed Soy Protein, Hydroxypropyl Hydrolyzed Vegetable Protein, Hydroxypropyltrimonium Hydrolyzed Wheat Protein, Hydroxypropyltrimonium Hydrolyzed Wheat Protein/Siloxysilicate, Laurdimonium Hydroxypropyl Hydrolyzed Soy Protein, Laurdimonium Hydroxypropyl Hydrolyzed Wheat Protein, Laurdimonium Hydroxypropyl Hydrolyzed Wheat Protein/Siloxysilicate, Lauryldimonium Hydroxypropyl Hydrolyzed Casein, Lauryldimonium Hydroxypropyl Hydrolyzed Collagen, Lauryldimonium Hydroxypropyl Hydrolyzed Keratin, Lauryldimonium Hydroxypropyl Hydrolyzed Silk, Lauryldimonium Hydroxypropyl Hydrolyzed Soy Protein, Steardimonium Hydroxypropyl Hydrolyzed Casein, Steardimonium Hydroxypropyl Hydrolyzed Collagen, Steardimonium Hydroxypropyl Hydrolyzed Keratin, Steardimonium Hydroxypropyl Hydrolyzed Rice Protein, Steardimonium Hydroxypropyl Hydrolyzed Silk, Steardimonium Hydroxypropyl Hydrolyzed Soy Protein, Steardimonium Hydroxypropyl Hydrolyzed Vegetable Protein, Steardimonium Hydroxypropyl Hydrolyzed Wheat Protein, Steartrimoni um Hy droxy ethyl Hydrolyzed Collagen, Quatemi um -76 Hydrolyzed Collagen, Quaternium-79 Hydrolyzed Collagen, Quaternium-79 Hydrolyzed Keratin, Quaternium-79 Hydrolyzed Milk Protein, Quaternium-79 Hydrolyzed Silk, Quaternium-79 Hydrolyzed Soy Protein, Quaternium-79 Hydrolyzed Wheat Protein.

100361 In a special embodiment of the invention, the composition comprises at least two different protein hydrolysates and/or protein hydrolysate derivatives; vegetable protein hydrolysates and/or vegetable protein hydrolysate derivatives are preferred, specifically preferred is hydrolyzed wheat protein and hydrolyzed rice protein.

[0037] Preferably the at least one protein hydrolysate and/or one protein hydrolysate derivative with a proportion of from about 0.005 to about 1.0% by weight, preferably from about 0.007 to about 0.75% by weight, especially preferably from about 0.01 to about 0.5% by weight, even more preferably from about 0.01 to about 0.35 % by weight, based on the total proportion of the composition, is contained in the composition.

10038] In a special embodiment of the invention, wherein the composition features at least two different protein hydrolysates and/or protein hydrolysate derivatives, a first protein hydrolysate or protein hydrolysate derivative with a proportion of from about 0.005 to about 1.0% by weight, preferably from about 0.007 to about 0.75% by weight, especially preferably from about 0.009 to about 0.5 (1)) by weight, even more preferably from about 0.009 to about 0.35% by weight, and a second protein hydrolysate or protein hydrolysate derivative with a proportion of from about 0.004 to about 0.1% by weight, preferably with from about 0.005 to about 0.9% by weight, specifically preferred from about 0.007 to about 0.06% by weight, even more preferably with from about 0.009 to about 0.04% by weight, based on the total proportion of the composition, is contained in the composition.

100391 The composition preferably contains further components selected from surfactants, preservatives, humectants, care products, dyes, conditioning agents, perfume and mixtures thereof [0040] In a special configuration of the invention, the composition can additionally contain nonionic, anionic and/or cationic surfactants. Examples of anionic surfactants are soaps, alkylbenzene sulphonates, alkane sulphonates, olefin sulphonates, alkyl ether sulphonates, glycerol ether sulphonates, -methyl ester sulphonates, sulfo fatty acids, alkyl sulphates, fatty alcohol ether sulphates, glycerol ether sulphates, hydroxy mixed ether sulphates, monoglyceride (ether) sulphates, fatty acid amide (ether) sulphates, mono-and dialkyl sulphosuccinates, Mono-and dialkylsulfosuccinamates, sulfotriglyceride, amide soaps, ether carboxylic acids and their salts, fatty acid isethionates, fatty acid sarcosinates, fatty acid taurides, N-acyl amino acids, such as acyl lactylates, acyl tartrates, acyl glutamates and acyl acyl spartates, alkyl oligoglucoside sulphates, protein fatty acid condensates (in particular wheat-based vegetable products) and alkyl (ether) phosphates. If the anionic surfactants contain polyglycol ether chains, they may have a conventional, but preferably a narrowed homologue distribution. Examples of non-ionic surfactants are fatty alcohol polyglycol ethers, alkylphenol polyglycol ethers, fatty acid polyglycol esters, fatty acid amide polyglycol ethers, fatty amine polyglycol ethers, alkoxylated triglyceri des, mixed ethers or mixed-formal, optionally partially oxidised alk(en)yl oligoglycosides or glucoronic acid derivatives, fatty acid-N-alkyl glucamides, protein hydrolysates On particular wheat-based vegetable products), polyol fatty acid esters, sugar esters, sorbitan esters, polysorbates and amine oxides. If the non-ionic surfactants contain polyglycol ether chains, they may have a conventional, but preferably a narrowed homologue distribution. Examples of cationic surfactants are quaternary ammonium compounds and esterquats, especially quaternised fatty acid trialkanolamine ester salts. The proportion of surfactants in the composition is preferably from about 0.05 to about 5.5% by weight, particularly preferably from about 0.1 to about 3.5% by weight, very particularly preferably from about 0.2 to about 3.5% by weight, based on the total proportion of the composition.

100411 The composition may additionally contain a conditioning agent such as a natural oil selected from, for example, jojoba oil, almond oil, olive oil, grape seed oil, hemp oil, soybean oil, cotton seed oil, sunflower oil, palm oil, palm kernel oil, linseed oil, castor oil, corn oil, rapeseed oil, sesame oil, safflower oil, wheat germ oil, peach kernel oil, the liquid portions of coconut oil and mixtures thereof 100421 The proportion of conditioning agents in the composition is preferably from about 0.01 to about 5.0% by weight, particularly preferably from about 0.05 to about 3.0% by weight, very particularly preferably from about 0.1 to about 1.0% by weight, based on the total proportion of the composition.

[0043] Furthermore, the composition may contain a preservative, in particular those listed in the Cosmetic Products Regulation in Annex V (Regulation (EC) No 122+3/2009 of the European Parliament and of the Council of 30 November 2009 on cosmetic products), particularly preferably benzoic acid and benzoates and mixtures thereof [0044] The proportion of preservatives in the composition is preferably from about 0.05 to about 1.0% by weight, particularly preferably from about 0.075 to about 0.6% by weight, particularly preferably from about 0.1 to about 0.4% by weight, based on the total proportion of the composition.

[0045] Preferably, the at least one care component comprises one care oil and/or at least one care oil ingredient, wherein a care oil comprises a triglyceride of natural origin. Especially preferred are vegetable care oils selected from amaranth seed oil, argan oil, rice germ oil, baobab oil, manetti oil, manila seed oil yangu seed oil, rambutan oil, buckhoirn oil, manoi de Tahiti, tiger nut oil, Inca Inchi oil, avocado oil, cotton seed oil, cupuagu butter, cashew oil, safflower oil, groundnut oil, jojoba oil, chamomile oil, coconut oil, pumpkin seed oil, linseed oil, macademia oil, corn oil, almond oil, apricot kernel oil, poppy seed oil, evening primrose oil, olive oil, rapeseed oil, soya oil, sunflower oil and wheat germ oil, especially (-)-a bisabolol, hydrated jojoba oil and/or coconut oil.

[0046] Furthermore, care ingredients selected from vitamins, pro vitamins, vitamin precursors and/or their derivatives are preferred. In doing so, those vitamins, provitamins and vitamin precursors which are usually assigned to the groups A, B, C, E, F and H are preferred. A, especially preferred care ingredient is D-Panthenol.

[0047] The proportion of the at least one care component in the composition is preferably from about 0.01 to about 2.0% by weight, particularly preferably from about 0.04 to about 1.5% by weight, quite particularly preferably from about 0.07 to about 1.0% by weight, even more preferably from about 0.1 to about 0.5% by weight, based on the total proportion of the composition.

10048] In another configuration of the invention, the composition contains at least one cosmetically compatible perfume and/or at least one plant extract. The at least one more plant extract, selected from bamboo extract (Bambusa Vulgaris), birch sap, coconut milk, hops extract, avocado extract, chamomile extract and mixtures thereof, is preferred. Furthermore, the extracts and/or exsudates from plants or parts of plants of green tea, hemp (INCI: Cannabis Sativa seed oil), oak bark, nettle, witch hazel, burdock root, horse tail, hawthorn, linden blossom, lychee, almond, aloe vera, spruce needle, horse chestnut, sandalwood, juniper, coconut, mango, apricot, lime, wheat, kiwi, melon, orange, grapefruit, sage, rosemary, mallow, meadow foam, quender, yarrow, thyme, melissa, hauhechel, Coltsfoot, marshmallow, Ginseng, ginger root, Echinacea purpurea, olea europea, Boerhavia Diffusa Roots, Foeniculum vulgaris and Apim graveolens, algae, especially brown algae (INCI: Laminari a saccharina extract), blue algae.

[0049] Preferably the at least one more plant extract with a proportion of from about 0.001 to about 1.0% by weight, preferably from about 0.002 to about 0.5 % by weight, particularly preferably from about 0 002 to about 001% by weight, even more preferably from about 0 003 to about 6.5% by weight, based on the total proportion of the composition, is contained in the composition.

10050] Furthermore, the invention comprises the application of a composition as invented for temporary shaping and/or shape retention of keratinous fibers, preferably hair on the human head.

10051] Moreover, the invention comprises a procedure for temporary shaping of keratinous fibers, preferably men's hair on the head, wherein a composition as invented is applied on the keratinous fibers, preferably on human head hair. I.3

Worked example

Some further preferred compositions can be found in the following tables (data in weight % based on the total weight of the composition unless otherwise stated).

Components Formula 1 Formula 2 Formula 3 Formula 4 Formula 5 Disaccharide 0.5 15.0 1.0 12.0 2.0 10.0 3.0 6.0 2.5 5.0 amphoteric surfactant 0.01 -2.0 0.05 -1.0 0.09 -0.8 0.1 -0.7 0.2 -0.6 Synthetic, film-forming 0.0 0.0 0.0 0.0 0.0 polymer optional components and water ad. 100 ad. 100 ad. 100 ad. 100 ad. 100 Components Formula 6 Formula 7 Formula 8 Formula 9 Formula 10 Saccharose 0.5 15.0 1.0 12.0 2.0 10.0 3.0-6.0 2,5-5.0 amphoteric surfactant 0.01 -2.0 0.05 -1.0 0.09 -0.8 0.1 -0.7 0.2 -0.6 Synthetic, film-forming 0.0 0.0 0.0 0.0 0.0 polymer optional components and water ad. 100 ad. 100 ad. 100 ad. 100 ad. 100 Components Formula 11 Formula 12 Formula 13 Formula 14 Formula 15 Saccharose 0.5 15.0 1.0 12.0 2.0 10.0 3.0-6.0 2.5-5.0 Cocoamidopropylbetaine 0.01 -2.0 0.05 -1.0 0.09 -0.8 0.1 -0.7 0.2 -0.6 Synthetic, film-forming 0.0 0.0 0.0 0.0 0.0 polymer optional components and water ad. 100 ad. 100 ad. 100 ad. 100 ad. 100 Components Formula Formula Formula Formula Formula 16 17 18 19 20 Disaccharide 0.5 -15.0 1.0 -12.0 2.0- 10.0 3.0 -6.0 2.5 -5.0 amphoteric surfactant 0.01 -2.0 0.05 -1.0 0.09 -0.8 0.1 -0.7 0.2 -0.6 Synthetic, film-forming 0.0 0.0 0.0 0.0 0.0 polymer Aliphatic, branched or 1.0 -30.0 2.0 -20.0 3.0-10.0 3.5 -7.0 4.0 -6.0 unbranched, monohydric alcohol optional components and water ad. 100 ad. 100 ad. 100 ad. 100 ad. 100 Components Formula 21 Formula 22 Formula 23 Formula 24 Formula 25 Saccharose 0.5 -15.0 1.0 -12.0 2.0-10.0 3.0-6.0 2.5 5.0 amphoteric surfactant 0.01 2.0 0.05 1.0 0.09 -0.8 0.1 0.7 0.2-0.6 Synthetic, film-forming 0.0 0.0 0.0 0.0 0.0 polymer Aliphatic, branched or 1.0 -30.0 2.0 -20.0 3.0-10.0 3.5 -7.0 4.0 -6.0 unbranched, monohydric alcohol optional components and water ad. 100 ad. 100 ad. 100 ad. 100 ad. 100 Components Formula 26 Formula 27 Formula 28 Formula 29 Formula 30 Saccharose 0.5 -15.0 1.0-12.0 2.0-10.0 3.0 -6.0 2.5 -5.0 Cocoam dopropylbeta ne 0.01 -2.0 0.05 -1.0 0.09 -0.8 0.1 -0.7 0.2 -0.6 Synthetic, film-forming 0.0 0.0 0.0 0.0 0.0 polymer Aliphatic, branched or 1.0 -30.0 2.0 -20.0 3.0-10.0 3.5 -7.0 4.0 -6.0 unbranched, monohydric alcohol optional components and water ad. 100 ad. 100 ad. 100 ad. 100 ad. 100 Components Formula 31 Formula 32 Formula 33 Formula 34 Formula 35 Saccharose 0.5 -15.0 1.0-12.0 2.0-10.0 3.0 -6.0 2.5 -5.0 Cocoamidopropylbetaine 0.01 2.0 0.05 1.0 0.09 -0.8 0.1 0.7 0.2-0.6 Synthetic, film-forming 0.0 0.0 0.0 0.0 0.0 polymer Ethanol 1.0 -30.0 2.0 -20.0 3.0-10.0 3.5 -7.0 4.0 -6.0 optional components and water ad. 100 ad. 100 ad. 100 ad. 100 ad. 100 Components Formula 36 Formula 37 Formula 38 Formula 39 Formula 40 Disaccharide 0.5 15.0 1.0 12.0 2.0 10.0 3,0-6.0 2,5-5.0 Amphoteric surfactant 0.01 -2.0 0.05 -1.0 0.09 -0.8 0.1 -0.7 0.2 -0.6 Synthetic, film-forming 0.0 0.0 0.0 0.0 0.0 polymer Aliphatic, branched or 1.0 30.0 2.0-20.0 3.0-10.0 3.5 7.0 4 0 6.0 unbranched, monohydric alcohol Organic acid 0.01 3.5 0.03 -2.5 0.05 2.0 0.06 1.7 0.07 -1.0 optional components and water ad. 100 ad. 100 ad. 100 ad. 100 ad. 100 Components Formula 41 Formula 42 Formula 43 Formula 44 Formula 45 Saccharose 0.5 -15.0 1.0 -12.0 2.0-10.0 3.0 -6.0 2.5 -5.0 amphoteric surfactant 0.01 2.0 0.05 1.0 0.09 -0.8 0.1 0.7 0.2-0.6 Synthetic, film-forming 0.0 0.0 0.0 0.0 0.0 polymer Aliphatic, branched or 1.0 -30.0 2.0 -20.0 3.0-10.0 3.5 -7.0 4.0 -6.0 unbranched, monohydric alcohol Organic acid 0.01 -3.5 0.03 -2.5 0.05 -2.0 0.06-1.7 0.07 -1.0 optional components and ad. 100 ad. 100 ad. 100 ad. 100 ad. 100 water Components Formula 46 Formula 47 Formula 48 Formula 49 Formula 50 Saccharose 0.5 -15.0 1.0-12.0 2.0-10.0 3.0 -6.0 2.5 -5.0 Cocoamidopropylbetaine 0.01 -2.0 0.05 -1.0 0.09 -0.8 0.1 -0.7 0.2 -0.6 Synthetic, film-forming 0.0 0.0 0.0 0.0 0.0 polymer Aliphatic, branched or 1.0 30.0 2.0 -20.0 3.0-10.0 3.5 7.0 4.0 6.0 unbranched, monohydric alcohol with 1 to 9 C atoms Organic acid 0.01 3.5 0.03-2.5 0.05-2.0 0.06 1.7 0.07-1.0 optional components and water ad. 100 ad. 100 ad. 100 ad. 100 ad. 100 Components Formula 51 Formula 52 Formula 53 Formula 54 Formula 55 Saccharose 0.5 -15.0 1.0-12.0 2.0-10.0 3.0 -6.0 2.5 -5.0 Cocoamidopropylbetaine 0.01 -2.0 0.05 -1.0 0.09 -0.8 0.1 -0.7 0.2 -0.6 Synthetic, film-forming 0.0 0.0 0.0 0.0 0.0 polymer Ethanol 1.0 -30.0 2.0 -20.0 3.0-10.0 3.5 -7.0 4.0 -6.0 Organic acid 0.01 -3.5 0.03 -2.5 0.05 -2.0 0.06-1.7 0.07-1.0 optional components and water ad. 100 ad. 100 ad. 100 ad. 100 ad. 100 Components Formula Formula Formula Formula Formula 56 57 58 59 60 Saccharose 0.5 15.0 1.0 12.0 2.0 10.0 3.0-6.0 2.5-5.0 Cocoamidopropylbetaine 0.01 -2.0 0.05-1.0 0.09 -0.8 0.1 -0.7 0.2 -0.6 Synthetic, film-forming 0.0 0.0 0.0 0.0 0.0 polymer Ethanol 1.0 -30.0 2.0 -20.0 3.0-10.0 3.5 -7.0 4.0 -6.0 Lactic acid 0.01 3.5 0.03-2.5 0.05-2.0 0.06 1.7 0.07-1.0 optional components and water ad. 100 ad. 100 ad. 100 ad. 100 ad. 100 Components Formula 61 Formula 62 Formula 63 Formula 64 Formula 65 Disaccharide 0.5 -15.0 1.0 -12.0 2.0-10.0 3.0-6.0 2.5 5.0 Amphoteric surfactant 0.01 -2.0 0.05 -1.0 0.09 -0.8 0.1 -0.7 0.2 -0.6 Synthetic, film-forming 0.0 0.0 0.0 0.0 0.0 polymer Aliphatic, branched or 1.0 -30.0 2.0 -20.0 3.0-10.0 3.5 -7.0 4.0 -6.0 unbranched, monohydric alcohol Organic acid 0.01 -3.5 0.03 -2.5 0.05 -2.0 0.06-1.7 0.07 -1.0 Care component 0.01 -2.0 0.04-1.5 0.07-1.0 0.9 -0.5 0.1 -0.5 optional components and water ad. 100 ad. 100 ad. 100 ad. 100 ad. 100 Components Formula 66 Formula 67 Formula 68 Formula 69 Formula 70 Saccharose 0.5 -15.0 1.0-12.0 2.0 -10.0 3.0-6.0 2.5 5.0 amphoteric surfactant 0.01 -2.0 0.05-1.0 0.09 -0.8 0.1 -0.7 0.2 -0.6 Synthetic, film-forming 0.0 0.0 0.0 0.0 0.0 polymer Aliphatic, branched or 1.0 30.0 2.0-20.0 3.0 10.0 3.5 7.0 4.0-6.0 unbranched, monohydric alcohol with 1 to 9 C atoms Organic acid 0.01 -3.5 0.03 -2.5 0.05 -2.0 0.06-1.7 0.07 -1.0 Care component 0.01 -2.0 0.04-1.5 0.07-1.0 0.9 -0.5 0.1 -0.5 optional components and ad. 100 ad. 100 ad. 100 ad. 100 ad. 100 water Components Formula 71 Formula 72 Formula 73 Formula 74 Formula 75 Saccharose 0.5 -15.0 1.0-12.0 2.0 -10.0 3.0 -6.0 2.5 -5.0 Cocoamidopropylbe ame 0.01 -2.0 0.05 -1.0 0.09 -0.8 0.1 -0.7 0.2 -0.6 Synthetic, film-forming 0.0 0.0 0.0 0.0 0.0 polymer Aliphatic, branched or 1.0 30.0 2.0 -20.0 3.0 -10.0 3.5 -7.0 4.0 6.0 unbranched, monohydric alcohol with 1 to 9 C atoms Organic acid 0.01 3.5 0.03 2.5 0.05 2.0 0.06-1.7 0.07 -1.0 Care component 0.01 -2.0 0.04-1.5 0.07-1.0 0.9 -0.5 0.1 -0.5 optional components and water ad. 100 ad. 100 ad. 100 ad. 100 ad. 100 Components Formula 76 Formula 77 Formula 78 Formula 79 Formula 80 Saccharose 0.5 -15.0 1.0-12.0 2.0 -10.0 3.0 -6.0 2.5 -5.0 Cocoam dopropylbetaine 0.01 -2.0 0.05 -1.0 0.09 -0.8 0.1 -0.7 0.2 -0.6 Synthetic, film-forming 0.0 0.0 0.0 0.0 0.0 polymer Ethanol 1.0 -30.0 2.0 -20.0 3.0-10.0 3.5 -7.0 4.0 -6.0 Organic acid 0.01 -3.5 0.03 -2.5 0.05 -2.0 0.06-1.7 0.07 -1.0 Care component 0.01 2.0 0.04 1.5 0.07-1.0 0.9-0.5 01 0.5 optional components and water ad. 100 ad. 100 ad. 100 ad. 100 ad. 100 Components Formula Formula Formula Formula Formula 81 82 83 84 85 Saccharose 0.5 -15.0 1.0- 12.0 2.0 -10.0 3.0-6.0 2.5 5.0 Cocoamidopropylbetaine 0.01 2.0 0.05 1.0 0.09-0.8 0.1 0.7 0.2-0.6 Synthetic, film-forming 0.0 0.0 0.0 0.0 0.0 polymer Ethanol 1.0 30.0 2.0-20.0 3.0 10.0 3.5 7.0 4.0-6.0 Lactic acid 0.01 -3.5 0.03 -2.5 0.05 -2.0 0.06-1.7 0.07 -1.0 Care component 0.01 2.0 0.04 1.5 0.07-1.0 0.9-0.5 OA 0.5 optional components and water ad. 100 ad. 100 ad. 100 ad. 100 ad. 100 Components Formula 86 Formula 87 Formula 88 Formula 89 Formula 90 Saccharose 0.5 -15.0 1.0-12.0 2.0 -10.0 3.0 -6.0 2.5 -5.0 Cocoam dopropylbetaine 0.01 -2.0 0.05 -1.0 0.09 -0.8 0.1 -0.7 0.2 -0.6 Synthetic, film-forming 0.0 0.0 0.0 0.0 0.0 polymer Ethanol 1.0 -30.0 2.0 -20.0 3.0 -10.0 3.5 -7.0 4.0 -6.0 Lactic acid 0.01 -3.5 0.03 -2.5 0.05 2.0 0.06-1.7 0.07 -1.0 D-Panthenol 0.01 -2.0 0.04-1.5 0.07-1.0 0.9 -0.5 0.1 -0.5 optional components and water ad. 100 ad. 100 ad. 100 ad. 100 ad. 100 100521 While at least one exemplary embodiment has been presented in the foregoing detailed description, it should be appreciated that a vast number of variations exist. It should also be appreciated that the exemplary embodiment or exemplary embodiments are only examples, and are not intended to limit the scope, applicability, or configuration of the various embodiments in any way. Rather, the foregoing detailed description will provide those skilled in the art with a convenient road map for implementing an exemplary embodiment as contemplated herein. It being understood that various changes may be made in the function and arrangement of elements described in an exemplary embodiment without departing from the scope of the various embodiments as set forth in the appended claims.

Claims (1)

1. Claims 1. Composition, comprising a) at least one disaccharide and b) at least one amphoteric surfactant, wherein the composition is free from synthetic, film-forming polymers 2. Composition as claimed in Claim 1, characterized in that the composition contains at least one alcohol, preferably at least one aliphatic, branched or unbranched, monohydric alcohol, with 1 to 9, preferably with 2 to 4 C atoms, even more preferred selected from the ethanol, n-propanol, isopropanol, n-butanol, tert-butanol and isobutanol group.3. Composition as claimed in one of the Claims 1 or 2, characterized in that the at least one alcohol is contained with a proportion of from about 1.0 to about 30.0 % by weight, preferably from about 2.0 to about 20.0% by weight, even more preferably from about 3.0 to about 10.0% by weight, quite specifically preferably from about 3.5 to about 7.0% by weight in the composition, measured based on the total proportion of the composition.4. Composition according to one of the Claims from 1 to 3, characterized in that the composition features a pH value in the range from about 3.0 to about 6.0, especially preferably in the range from about 3.5 to about 5.5, particularly preferably from about 4.0 to about 5.0.5. Composition as claimed in one of the Claims 1 to 4, characterized in that the at least one disaccharide is contained in a proportion of from about 1.0 to about 15.0% by weight, preferably from about 1.5 to about 10.0% by weight, even more preferably from about 2.0 to about 7.0% by weight, specifically from about 2.5 to about 5.0% by weight, based on the total proportion of the composition.6. Composition as claimed in one of the Claims 1 or 5, characterized in that the at least one amphoteric surfactant is contained in a proportion of from about 0.01 to about 2.0% by weight, preferably from about 0.05 to about 1.0% by weight, even more preferably from about 0.1 to about 0.8% by weight, particularly specifically preferably from about 0.2 to about 0.6% by weight in the composition, measured based on the total proportion of the composition.7 Composition as claimed in one of the Claims Ito 6, characterized in that the at least one disaccharide comprises saccharose, preferably the at least one disaccharide is saccharose.8. Composition according to any one of claims 1 to 7, characterized in that the composition contains at least one modified and/or unmodified, natural protein hydrolysate.9. Composition as claimed in one of the Claims' to, characterized in that the composition does not contain any synthetic, film-forming polymer, especially no homopolymer or copolymer, comprising monomer units, selected from siloxane, vinyl pyrrolidone, vinyl caprolactam, N-vinyl formamide, vinyl ester, such as vinyl acetate, vinyl alcohol, acrylamide, methacrylamide, Cl to C7 alkyl acrylamide, Cl to C7 dialkyl acrylamide, Cl to C7 alkyl methacrylamide, Cl to C7 dialkyl methacrylamide, C I to C7 alkyl acrylate, acrylic acid, propylene glycol, maleic acid, styrol, itaconic acid and mixtures thereof 10. Use of a composition as claimed in one the Claims Ito 9 for temporary shaping and/or shape-retention of keratinous fibers, preferably human head hair.