GB2588254B - Li/Na-ion battery anode materials - Google Patents

Li/Na-ion battery anode materials Download PDF

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Publication number
GB2588254B
GB2588254B GB2002487.3A GB202002487A GB2588254B GB 2588254 B GB2588254 B GB 2588254B GB 202002487 A GB202002487 A GB 202002487A GB 2588254 B GB2588254 B GB 2588254B
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United Kingdom
Prior art keywords
ion battery
battery anode
anode materials
materials
ion
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Active
Application number
GB2002487.3A
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GB202002487D0 (en
GB2588254A (en
Inventor
S Groombridge Alexander
De La Verpilliere Jean
Santhanam Sumithra
Zhang Wanwei
E Houck Maurits
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Echion Technologies Ltd
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Echion Technologies Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Echion Technologies Ltd filed Critical Echion Technologies Ltd
Publication of GB202002487D0 publication Critical patent/GB202002487D0/en
Priority to GB2008352.3A priority Critical patent/GB2588264B/en
Priority to GB2011681.0A priority patent/GB2595745B/en
Priority to BR112022007307A priority patent/BR112022007307A2/en
Priority to BR112022007323A priority patent/BR112022007323A2/en
Priority to BR112022007117A priority patent/BR112022007117A2/en
Priority to US17/769,717 priority patent/US20220380226A1/en
Priority to CN202080072727.4A priority patent/CN114930570A/en
Priority to CA3166174A priority patent/CA3166174A1/en
Priority to CA3157452A priority patent/CA3157452A1/en
Priority to PCT/GB2020/052485 priority patent/WO2021074592A1/en
Priority to EP20793067.8A priority patent/EP4046213A1/en
Priority to KR1020227016654A priority patent/KR20220105638A/en
Priority to KR1020227016651A priority patent/KR20220103946A/en
Priority to EP20793068.6A priority patent/EP4046214A1/en
Priority to EP20793069.4A priority patent/EP4046215A1/en
Priority to PCT/GB2020/052487 priority patent/WO2021074594A1/en
Priority to CN202080072794.6A priority patent/CN114868278A/en
Priority to KR1020227016652A priority patent/KR20220105637A/en
Priority to CN202080071972.3A priority patent/CN114946047A/en
Priority to US17/769,716 priority patent/US20220384797A1/en
Priority to PCT/GB2020/052486 priority patent/WO2021074593A1/en
Priority to CA3157162A priority patent/CA3157162A1/en
Priority to US17/769,720 priority patent/US20220384798A1/en
Priority to JP2022521991A priority patent/JP2023501077A/en
Priority to JP2022523003A priority patent/JP2023501778A/en
Priority to JP2022522980A priority patent/JP2023501888A/en
Publication of GB2588254A publication Critical patent/GB2588254A/en
Application granted granted Critical
Publication of GB2588254B publication Critical patent/GB2588254B/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/362Composites
    • H01M4/366Composites as layered products
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G33/00Compounds of niobium
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G33/00Compounds of niobium
    • C01G33/006Compounds containing, besides niobium, two or more other elements, with the exception of oxygen or hydrogen
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/054Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/04Processes of manufacture in general
    • H01M4/0471Processes of manufacture in general involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/13Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139Processes of manufacture
    • H01M4/1391Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/62Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621Binders
    • H01M4/622Binders being polymers
    • H01M4/623Binders being polymers fluorinated polymers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
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    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/62Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624Electric conductive fillers
    • H01M4/625Carbon or graphite
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/60Compounds characterised by their crystallite size
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    • C01INORGANIC CHEMISTRY
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    • C01P2002/00Crystal-structural characteristics
    • C01P2002/70Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00Crystal-structural characteristics
    • C01P2002/80Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
    • C01P2002/88Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by thermal analysis data, e.g. TGA, DTA, DSC
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    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/01Particle morphology depicted by an image
    • C01P2004/03Particle morphology depicted by an image obtained by SEM
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    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/51Particles with a specific particle size distribution
    • C01P2004/53Particles with a specific particle size distribution bimodal size distribution
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    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/61Micrometer sized, i.e. from 1-100 micrometer
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/40Electric properties
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/42Magnetic properties
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M2004/026Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/027Negative electrodes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Composite Materials (AREA)
  • Battery Electrode And Active Subsutance (AREA)
GB2002487.3A 2019-10-18 2020-02-21 Li/Na-ion battery anode materials Active GB2588254B (en)

Priority Applications (26)

Application Number Priority Date Filing Date Title
GB2008352.3A GB2588264B (en) 2019-10-18 2020-06-03 Active electrode material
GB2011681.0A GB2595745B (en) 2019-10-18 2020-07-28 Active electrode material
EP20793069.4A EP4046215A1 (en) 2019-10-18 2020-10-08 Li/na-ion battery anode materials
KR1020227016652A KR20220105637A (en) 2019-10-18 2020-10-08 active electrode material
BR112022007117A BR112022007117A2 (en) 2019-10-18 2020-10-08 LI/NA ION BATTERY ANODE MATERIALS
US17/769,717 US20220380226A1 (en) 2019-10-18 2020-10-08 Active electrode material
CN202080072727.4A CN114930570A (en) 2019-10-18 2020-10-08 Li/Na ion battery anode material
CA3166174A CA3166174A1 (en) 2019-10-18 2020-10-08 Li/na-ion battery anode materials
CA3157452A CA3157452A1 (en) 2019-10-18 2020-10-08 Li/na-ion battery anode materials
PCT/GB2020/052485 WO2021074592A1 (en) 2019-10-18 2020-10-08 Active electrode material
EP20793067.8A EP4046213A1 (en) 2019-10-18 2020-10-08 Active electrode material
KR1020227016654A KR20220105638A (en) 2019-10-18 2020-10-08 Lithium/Sodium Ion Battery Anode Material
KR1020227016651A KR20220103946A (en) 2019-10-18 2020-10-08 Lithium/Sodium Ion Battery Anode Material
EP20793068.6A EP4046214A1 (en) 2019-10-18 2020-10-08 Li/na-ion battery anode materials
BR112022007307A BR112022007307A2 (en) 2019-10-18 2020-10-08 LI/NA ION BATTERY ANODE MATERIALS
PCT/GB2020/052487 WO2021074594A1 (en) 2019-10-18 2020-10-08 Li/na-ion battery anode materials
CN202080072794.6A CN114868278A (en) 2019-10-18 2020-10-08 Active electrode material
BR112022007323A BR112022007323A2 (en) 2019-10-18 2020-10-08 ACTIVE ELECTRODE MATERIAL
CN202080071972.3A CN114946047A (en) 2019-10-18 2020-10-08 Li/Na ion battery anode material
US17/769,716 US20220384797A1 (en) 2019-10-18 2020-10-08 Li/na-ion battery anode materials
PCT/GB2020/052486 WO2021074593A1 (en) 2019-10-18 2020-10-08 Li/na-ion battery anode materials
CA3157162A CA3157162A1 (en) 2019-10-18 2020-10-08 Active electrode material
US17/769,720 US20220384798A1 (en) 2019-10-18 2020-10-08 Li/na-ion battery anode materials
JP2022521991A JP2023501077A (en) 2019-10-18 2020-10-08 Li/Na ion battery anode material
JP2022523003A JP2023501778A (en) 2019-10-18 2020-10-08 Active electrode material
JP2022522980A JP2023501888A (en) 2019-10-18 2020-10-08 Li/Na ion battery anode material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB201915151A GB201915151D0 (en) 2019-10-18 2019-10-18 Li/Na-ion battery anode materials

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GB202002487D0 GB202002487D0 (en) 2020-04-08
GB2588254A GB2588254A (en) 2021-04-21
GB2588254B true GB2588254B (en) 2021-10-20

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GB201915151A Ceased GB201915151D0 (en) 2019-10-18 2019-10-18 Li/Na-ion battery anode materials
GB2002487.3A Active GB2588254B (en) 2019-10-18 2020-02-21 Li/Na-ion battery anode materials

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Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB202013576D0 (en) 2020-08-28 2020-10-14 Echion Tech Limited Active electrode material
GB2595761B (en) * 2020-06-03 2022-07-13 Echion Tech Limited Active electrode material
JP7289018B1 (en) 2020-06-03 2023-06-08 エチオン テクノロジーズ リミテッド Active electrode material
CN112430089B (en) * 2020-11-03 2022-09-30 桂林理工大学 ReO (ReO) 3 Shear structure MoNb 6 O 18 Method for producing materials and use thereof
CN113263184B (en) * 2021-04-13 2022-11-08 上海大学 Selenium-doped nano antimony, preparation method and application thereof
CN113651361A (en) * 2021-06-30 2021-11-16 桂林理工大学 Preparation method and application of tungsten-niobium composite oxide
CN114906882A (en) * 2022-05-18 2022-08-16 江苏大学 Preparation method and application of niobium-based bimetal oxide negative electrode material
CN115124081B (en) * 2022-08-03 2023-12-12 安徽工业大学 Method for preparing lithium ion battery embedded cathode material and material obtained by method
CN115536072B (en) * 2022-10-24 2023-08-11 沈阳国科金能科技有限公司 Ferromanganese based Na 0.67 Mn 0.9 Fe 0.1 O 2 Modification method of sodium ion battery anode material

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015138019A1 (en) * 2014-03-12 2015-09-17 Imra America,Inc. Negative electrode active material for energy storage devices and method for making the same
US20150270543A1 (en) * 2014-03-18 2015-09-24 Kabushiki Kaisha Toshiba Active material, nonaqueous electrolyte battery, and battery pack
KR20150131800A (en) * 2014-05-16 2015-11-25 부산대학교 산학협력단 Active material for anode, method of fabricating the same and battery having the same
EP2980891A1 (en) * 2014-07-30 2016-02-03 Kabushiki Kaisha Toshiba Composite
CN106299329A (en) * 2015-05-19 2017-01-04 中信国安盟固利动力科技有限公司 A kind of high power capacity titanium system's negative material and the lithium-ion-power cell of composition thereof
CN109244443A (en) * 2018-11-13 2019-01-18 瑞声科技(南京)有限公司 Lithium ion battery negative material and nonaqueous electrolyte battery
US20190280291A1 (en) * 2018-03-07 2019-09-12 Nanotek Instruments, Inc. Electrochemically stable elastomer-encapsulated particles of anode active materials for lithium batteries

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015138019A1 (en) * 2014-03-12 2015-09-17 Imra America,Inc. Negative electrode active material for energy storage devices and method for making the same
US20150270543A1 (en) * 2014-03-18 2015-09-24 Kabushiki Kaisha Toshiba Active material, nonaqueous electrolyte battery, and battery pack
KR20150131800A (en) * 2014-05-16 2015-11-25 부산대학교 산학협력단 Active material for anode, method of fabricating the same and battery having the same
EP2980891A1 (en) * 2014-07-30 2016-02-03 Kabushiki Kaisha Toshiba Composite
CN106299329A (en) * 2015-05-19 2017-01-04 中信国安盟固利动力科技有限公司 A kind of high power capacity titanium system's negative material and the lithium-ion-power cell of composition thereof
US20190280291A1 (en) * 2018-03-07 2019-09-12 Nanotek Instruments, Inc. Electrochemically stable elastomer-encapsulated particles of anode active materials for lithium batteries
CN109244443A (en) * 2018-11-13 2019-01-18 瑞声科技(南京)有限公司 Lithium ion battery negative material and nonaqueous electrolyte battery

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
Journal of Materials Chemistry A, Vol 5, 21-05-2017, Van et al, "Electrospun WNb12O33 nanowires: superior lithium storage capability and their working mechanism", pages 8972-8980 *
Journal of Solid State Chemistry, Vol 183, 01-05-2010, Saritha et al, "Electrochemical Li insertion studies on WNb12O33 - A shear ReO3 type structure", pages 988-993 *
Solid State Ionics, Vol 9-10, Dec 1983, Cava et al, "Lithium insertion, electrical conductivity, and chemical substitution in various crystallographic shear structures", pages 407-411 *

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