GB2496321A - Process for producing a coloured fibre composite material and this fibre composite material, and formed part produced therefrom - Google Patents
Process for producing a coloured fibre composite material and this fibre composite material, and formed part produced therefrom Download PDFInfo
- Publication number
- GB2496321A GB2496321A GB1221808.7A GB201221808A GB2496321A GB 2496321 A GB2496321 A GB 2496321A GB 201221808 A GB201221808 A GB 201221808A GB 2496321 A GB2496321 A GB 2496321A
- Authority
- GB
- United Kingdom
- Prior art keywords
- fabric
- composite material
- fibre
- fibre composite
- sprayed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 35
- 239000002131 composite material Substances 0.000 title claims abstract description 17
- 238000000034 method Methods 0.000 title claims description 9
- 239000000463 material Substances 0.000 claims abstract description 11
- 239000004744 fabric Substances 0.000 claims description 36
- 239000000049 pigment Substances 0.000 claims description 12
- 239000003973 paint Substances 0.000 claims description 5
- 239000004922 lacquer Substances 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- 239000011521 glass Substances 0.000 claims description 3
- 238000003475 lamination Methods 0.000 claims description 3
- 238000005507 spraying Methods 0.000 claims description 3
- 239000002966 varnish Substances 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 2
- 229910052573 porcelain Inorganic materials 0.000 claims 1
- 239000011248 coating agent Substances 0.000 abstract description 6
- 238000000576 coating method Methods 0.000 abstract description 6
- 238000004040 coloring Methods 0.000 abstract description 4
- 230000006735 deficit Effects 0.000 abstract description 2
- 239000004753 textile Substances 0.000 abstract 3
- 239000002243 precursor Substances 0.000 abstract 1
- 239000003365 glass fiber Substances 0.000 description 5
- 229920002430 Fibre-reinforced plastic Polymers 0.000 description 4
- 239000011151 fibre-reinforced plastic Substances 0.000 description 4
- 230000003014 reinforcing effect Effects 0.000 description 4
- 238000001035 drying Methods 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000007740 vapor deposition Methods 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000001465 metallisation Methods 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 230000003678 scratch resistant effect Effects 0.000 description 2
- -1 serim Substances 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920006231 aramid fiber Polymers 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 108010025899 gelatin film Proteins 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000003655 tactile properties Effects 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/06—Fibrous reinforcements only
- B29C70/08—Fibrous reinforcements only comprising combinations of different forms of fibrous reinforcements incorporated in matrix material, forming one or more layers, and with or without non-reinforced layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
- B60R13/00—Elements for body-finishing, identifying, or decorating; Arrangements or adaptations for advertising purposes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0018—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular optical properties, e.g. fluorescent or phosphorescent
- B29K2995/002—Coloured
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/30—Vehicles, e.g. ships or aircraft, or body parts thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/30—Vehicles, e.g. ships or aircraft, or body parts thereof
- B29L2031/3005—Body finishings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/52—Sports equipment ; Games; Articles for amusement; Toys
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/722—Decorative or ornamental articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60R—VEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
- B60R13/00—Elements for body-finishing, identifying, or decorating; Arrangements or adaptations for advertising purposes
- B60R13/02—Internal Trim mouldings ; Internal Ledges; Wall liners for passenger compartments; Roof liners
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Composite Materials (AREA)
- Textile Engineering (AREA)
- Laminated Bodies (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
- Reinforced Plastic Materials (AREA)
- Coloring (AREA)
Abstract
In order to provide customer-specific colouring of a lightweight high-performance fibre composite material (10) serving as precursor material for thermoformed parts, without any resultant impairment of the haptic properties of the textile (11) therein, colour-pigmented reflective coating material is sprayed onto the entire surface of the textile (11) or onto graphically delimited parts thereof, before the textile (11) thus coloured is laminated to the fibre composite material (10).
Description
MetEod for producing a coloured fihre-reitiibreed plastic and cham.ferig of such fibrereinforced plastic, as well as forming the part produced therefrom The invention relates to a mcthod for producing a coloured fIbre-reinforced plastic and a colored fibre-reinforced plastic as a primary material as a reshaped part, as it is lonned for example as part of a sporl.s product, as a decorative element in the interior of passenger cars of soph.islicated eqLLipllient or as a battery cover or oI.her housing shell of a mobile phone or as used in other electronic consumer items.
With such a reshaped part, especially on a deep drawing method, conflicting demands ate olien placed in practice. In particu.i.ar, despite its extremely flat formation, it should be an. extraordinarily flexible and torsion-resistart material with a pleasing appearance and with excellent feel, however, with low material and production costs.
The exterior is outfItted with a definable coloring, hut a distinctive structure of a laminated fiber reinforcing fabric is supposed to remain significant in appearance, especially when one is not dealing with simple layouts hut more specific interpreted patterns.
In the presen.t case to simplify the representa:tion, it is always spoken oniy of fiber reinforcing fabric, which may be interpreted in the context of the present invention is equally as well as one or more layers as a knitted fabric, serim, fiber strands (rovings), felts arid the like matting. On hand are mostly defined oriented fibrous structures, that are, for example, are laminated on both sides with transparent thermosetting or preferably, with thermoplastic material to a prefened fibre-reinforced plastic, possibly also to a so-called organic sheets.
Especially with increased mechanical requirements for fibre-reinforced thermoplastic Thrmed parts, it is close Lu resorting to the fibre-rein bi-cement of carbon fibers. They exhibit not only very high strength, as a. formed part Lhcir trade structure also provides a pleasant feel and sophisticated look. Such formed parts, however, because of the electrically conductive properties of carbon and due to the therefore resulting shielding behavior, cannot he used in. devices such as,for exarnpJ.e, mobile pl-iones, where an antenna is integrated. This deficiency in poor insulation for electronic applications is not found in the also very solid Kcvlar and Aramid fibers, but due to their demand for protection helmets and bulletproof vests such fabrics as consumer goods are scarce at reasonable prices.
Therefore mostly remains only the rccoursc to thermoplastic laminates with the conventional glass fibre reinforcing labries, in particular the ones with layers, which also show very good mechanical strength. However, Ihe appearance of the resulting drawn glassy colourless formed parts is not at all appealing and therefore is unsuitable, particularly when compared to carbon-formed parts, especially [or use in higher-priced consumer goods. The individual glass fibers cannot he coloured, to thereby provide the subsequent tissue and the resulting formed parts created a more valuable appearance, because the fibers, caused by the surface structure of monolithic materials, adopt virtual]y no colour.
Although instead of the individual fibers, the glass fibre fabric as. a whole lets itself coat completely before its lamination, by dipping it in a dye bath with colour. Then., he one drying pahtt that then must still receive a metallic sheen vapor deposition, holds itself to an uneven fibre surface, but it this unevenness runs largely full of color, so that after drying the paint covering the now leveled fibre structure hardly appears as desired in its form and look -at least not more haptie or visually more appealing than in design review; the internal fibre structure has been lost externally.
Furthermore, as a resuLt, the metallization yet again has the disadvantages of electrical conductivity.
In recognition of such situations, however, the present invention is undermined by the technical problem, that with a glass fibre reinforced formed part without appreciably altering tactile qualities and the visual appearance to its fibre structure that appear in different preset colours and with this in particular. to let those in the higher, gray-black caj-bon highlights shine out.
This task is achieved by the essential characteristics indicated by the respective principal claim. Thereafter either the not yet woven fibre, particularly conhiliL.Lous fibers, or -preferably -th.e fibre fabric of thc later composite material will be sprayed with a colour-pigmented coating, such as the one, that is also referred to as china colour, to finishing brilliant-coloured items of glass or metal, by using it to print on scratch resistant surfaces. The selectively relatively densely attained precipitate on the fabric side or both sides, cg custom coloured, is then thermally fixed in the manner of lacquer curing before the mat i.s laminated transparently or translucently in a conventional manner. The requirement. of a metallic sheen vapor deposition of paint applied (as in. i.he conventiuiial colour-diving) is omitted for this spiay colouring.
Such one-or two-sided spray application of lacquer with colour pigments in the solvent excess does not result in the effectively closed paint application of the surface, hut rathcr a more or less dense predeterniinable along the structure of the fabric surface adherng punctua.1 precipitation of the colour pigments, without flattening the structural fabric bumps. When viewing the fibre composite material with lhbric previously sprayed in this way. in particular in the incidence of light thereon, in the interior of the composite material absorption does not occur on likc a dipping leveled and matt coloured surface, and no surface reflection on a weakly wavy and shiny post-metallisation surface; but according to the intensity of the sprayed coating and the brilliance of its sense of the colour pigments scatter radiated light from a plui-ality of point light sources of the surfaces out of the individual libres from the inside of the laminated fabric structure This yields, without metallic vapor deposition, the desired brilliantly coloured shine effect, and while maintaining the visual and tactile properties of the fabric structure of its latter composite material fomied part.
This allows forming parts made of composite materials to be achieved, even with the inexpensive fiberglass fabrics available in a variety of brilliant colours and colour combinations, while maintaining a significant fabric structure. For manufacturing, the fabric is withdrawn from a supply reel and led through a. single or double acting spraybooth spraying with pigments with the solvent excess, and then for example through a tLlnncl oven, as found for lacquer curing in industrial applications, in finally be coiled as the brilliantly colored fabric web again, without impairment to the appearance of their fabric structure.
If the spraying of (lie coloured precipitate is not on such a large area as in an automalic spray cabin or, for example, with a spray gun, bul graphically specifically hounded by a nozzle aproximately like the type ol'print writing head system of ink jet printers, then for example, also multicolored ornaments, logos or labels can be applied to the still uncoated fabric, that are laminated by transparently or translucently, and thus they appear more structured and haptically highcrgrade in any colour combinations succinctly after the formation of the object of utility.
To colour a lightweight high performance fibre coinposil.e material that serves as a fibre-reinforced primary material for thcrmoforming ftnmed part, that is without mctalisation custom brilliant colouring, without thereby compromising the tactile quality appearance of its fibre fabric, the fabric is sprayed, all over or graphically confined, with gloss varnish before its laminating, according to invention. The pigments, which thereby pi.tnetually-close precipitate on the course of thc fibre surfaces of the fabric, are then thermally cured before the so-coloured fabric is laminated to tabular or continuous fibre composite material, as a raw material for a.
substantially thermally rcshapeable object.
Closer to ill usirate fibre composite material, dyed according to the invention, it is made to the following description of a preferred embodiment, outlined in the drawing.
In the single figure a greatly enlarged, and not to scale, broken section of a fibre composite ply 10 with single-ply fibre fabric 11 is sketched, whose warp and weft fibres 13 are here woven into a linen texture. l'he reinforcing fibres 1 3 are usually glass fibres, hut also other materials such as ararnid fibres can be tinted with brilliant colour appearance of the fabric, structure according to invention, hut with no impact on electrical functions. The fabric 11 was sprayed here with a coloured gloss, on one side. That made the fabric structure-following precipitation, here exaggeratedly discontinLtously sketched, as brilliant as fine-grained color pigments 12 on the interwov en fibres 13.
With the glossy varnish it is preferably a matter of a sol-gel-hybrid coating system, as for example, it is used after evaporating he coating solvent in sprayed hydrolysis sol to a highly erosslinked elearcoat gel film as a decorative, scratch-resistant protective coating on glass surfaces, or as a dirt-repellent coating on. saniLryware. The sol is doped in the scope of the present invention, however, with very fine-grained and more colour-intensive pignients 12, which adhere well to the fibre surfaces in the final thermally lifted condensation of the sol to gel, following the fabric structure.
The bound on Fabric 11 in the gel pigments 12 were kept in an infrared tunnel oven at a temperal.ure of the order of about iSO degrees Celsius after brief drying, and then slowly cooled, to roughly stabilize the fibre surfaces while promoting the condensation reaction of' lie sol to the gel. This was ypica1ly followed by the at least one-sided, but usually k 0-sided lamination of the tELLs dyed fabric 11 to the fibre eoniposite material 10 with a matrix 14, made of transparent or translucent plastic, such as polyamide or polypropylene, or polyurethane, that adhered we! 1 to the fabric 1. 1 The broadloom or sheets of the so e.g. custom coloured fibre composite material can he cut to specific product, for instance for thermal deep drawing to a high strength formed part, such as the very thin and fiat, however, surface strip-and due to its superficial. lissue structure haptieally and visually-appealing battery cover or the similar radio and electronics acceptable fiat housin.g shell of an electrical consumer device.
Claims (1)
- <claim-text>Patent Claims 1. A method for pioducing a colored composite material (10) by spraying a.fabric (II) or the fibers (13), before lamination of the fabric (11), with a paint.which is then thermally cured.</claim-text> <claim-text>2. A method according to the preceding claim, characterized in that the fabric (11) is sprayed with a colour-pigmented gloss varnisit 3. A method according to one of the precedhg claims, characterized in that the paint is sprayed onto the fabric (11) bounded graphically.4. A method according to one of the preceding claims, characterized iii that the sprayed pigments (12) of the varnish are btirnt into the surfaces of the tihrcs (13) of the fabric (11).5. A method according to one of the preceding claims, characterized in that the fabric (11) or even the not-yet woven fibres (13) are sprayed with so called porcelain colour of the type, with the use of colour pigments in the excess of solvents, as employed in particular for printing of articles made of glass or metal.6. A method according to one of the preceding claims, charactcrized in that the fabric (11) or even the not-yet woven fibre (13) is sprayed with a coloured pigment-offsetting sol a sol-gel-lacquer system.7. A fibre composite material (10), dyed according to any one of the preceding method, characterized in that the surfaces of the fibres (13) of its web (11) bear color pigments (12).8. A fibre composite material according Lo the preceding claim, characterized hy high gloss pigments (12).9 A fibre compositc material according to oue of the Iwo preceding claims, characterized in that the pigments (12) are hurncd into the fibre surlhees 10. From a blank cut of the fibre composite matet-ial (10), according to one of the three preceding claims, a thermoformed fial, haptically appcaling and custom-specific colouráble forming pan., iii particular a housing shell of an elecuimic devicc. sporting goods or molor vehicle decorative element.</claim-text>
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102010033096 | 2010-08-02 | ||
| DE102010045834 | 2010-09-20 | ||
| PCT/EP2011/003423 WO2012016626A1 (en) | 2010-08-02 | 2011-07-08 | Process for producing a coloured fibre composite material and this fibre composite material, and formed part produced therefrom |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB2496321A true GB2496321A (en) | 2013-05-08 |
Family
ID=45558950
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1221808.7A Withdrawn GB2496321A (en) | 2010-08-02 | 2011-07-08 | Process for producing a coloured fibre composite material and this fibre composite material, and formed part produced therefrom |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP2601040B1 (en) |
| CN (1) | CN103221197A (en) |
| CA (1) | CA2807380A1 (en) |
| DE (1) | DE202011110150U1 (en) |
| GB (1) | GB2496321A (en) |
| TW (1) | TW201206669A (en) |
| WO (1) | WO2012016626A1 (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2792470A1 (en) * | 2013-04-15 | 2014-10-22 | BlackBerry Limited | Woven fiber-reinforced composite material and method of manufacturing same |
| DE102014013289A1 (en) | 2014-09-14 | 2016-03-17 | Heiko Klingenberg | Process for the production of a fiber composite material from glass or carbon fibers by coating the fibers with water-dilutable paints before the forming or injection molding process and the further processing of decorative plastic components in the interior and exterior of automobiles and the production of sports equipment or hardboard, as well as the partial fluoroscopy of such objects |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2593818A (en) * | 1949-06-01 | 1952-04-22 | Owens Corning Fiberglass Corp | Colored glass fiber product and method of producing the same |
| US3240741A (en) * | 1962-10-31 | 1966-03-15 | Dow Corning | Method of pigmenting glass cloth with silanes |
| EP0600735A2 (en) * | 1992-12-03 | 1994-06-08 | Canon Kabushiki Kaisha | Image output apparatus, image output method, ink jet print method and printed product obtained with said method |
| DE19537190A1 (en) * | 1995-10-06 | 1997-04-10 | Warema Renkhoff Gmbh & Co Kg | Vertical strip for venetian blind |
| DE19652081A1 (en) * | 1995-12-21 | 1997-06-26 | Hirsch Armbaender | Band especially suitable for wrist watch strap obviates additional processing stages |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1346139A (en) * | 1972-05-22 | 1974-02-06 | Oschatz Glasseide Veb | Process for the activation of solid body surfaces |
| US5342291A (en) * | 1991-08-29 | 1994-08-30 | Minnesota Mining And Manufacturing Company | Printed woven fiber materials and method |
| US5700858A (en) * | 1995-06-08 | 1997-12-23 | Thomas Deir | Plastisol paint and method of use |
| US6204207B1 (en) * | 1996-08-01 | 2001-03-20 | Leucadia, Inc. | Extruded netting exhibiting stretch and bonding |
| DE19753719A1 (en) * | 1997-12-04 | 1999-06-17 | Daimler Chrysler Ag | Top surface covering material |
| JP2000094533A (en) * | 1998-09-17 | 2000-04-04 | Sekisui Chem Co Ltd | Production of frp molding |
| AU2001268404A1 (en) * | 2000-06-14 | 2001-12-24 | The Procter And Gamble Company | Long lasting coatings for modifying hard surfaces and processes for applying the same |
| US20040126571A1 (en) * | 2002-12-17 | 2004-07-01 | Robert Bordener | Plastic material with decorative attributes |
| WO2004104110A1 (en) * | 2003-05-21 | 2004-12-02 | Merck Patent Gmbh | Photostabilised effect pigments |
| CN1895877A (en) * | 2005-07-11 | 2007-01-17 | 磁震科技开发股份有限公司 | Composite-material bright face shell production and products |
| CN2820531Y (en) * | 2005-07-29 | 2006-09-27 | 蔡莳铨 | Structure of colorful composite material |
| DE102006044310A1 (en) * | 2006-09-18 | 2008-03-27 | Nano-X Gmbh | Silane coating material and method of making a silane coating material |
| CN101239519A (en) * | 2007-02-09 | 2008-08-13 | 和成欣业股份有限公司 | Manufacturing method of colored panel and products produced thereby |
| JP5603349B2 (en) * | 2008-12-19 | 2014-10-08 | スリーエム イノベイティブ プロパティズ カンパニー | Microporous material from ethylene-chlorotrifluoroethylene copolymer and process for producing the same |
-
2011
- 2011-07-08 CN CN2011800379864A patent/CN103221197A/en active Pending
- 2011-07-08 DE DE202011110150U patent/DE202011110150U1/en not_active Expired - Lifetime
- 2011-07-08 CA CA2807380A patent/CA2807380A1/en not_active Abandoned
- 2011-07-08 EP EP11741404.5A patent/EP2601040B1/en active Active
- 2011-07-08 WO PCT/EP2011/003423 patent/WO2012016626A1/en active Application Filing
- 2011-07-08 GB GB1221808.7A patent/GB2496321A/en not_active Withdrawn
- 2011-07-25 TW TW100126156A patent/TW201206669A/en unknown
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2593818A (en) * | 1949-06-01 | 1952-04-22 | Owens Corning Fiberglass Corp | Colored glass fiber product and method of producing the same |
| US3240741A (en) * | 1962-10-31 | 1966-03-15 | Dow Corning | Method of pigmenting glass cloth with silanes |
| EP0600735A2 (en) * | 1992-12-03 | 1994-06-08 | Canon Kabushiki Kaisha | Image output apparatus, image output method, ink jet print method and printed product obtained with said method |
| DE19537190A1 (en) * | 1995-10-06 | 1997-04-10 | Warema Renkhoff Gmbh & Co Kg | Vertical strip for venetian blind |
| DE19652081A1 (en) * | 1995-12-21 | 1997-06-26 | Hirsch Armbaender | Band especially suitable for wrist watch strap obviates additional processing stages |
Non-Patent Citations (1)
| Title |
|---|
| UHLMANN D R ET AL sol-gel derived coatings on glass * |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2012016626A1 (en) | 2012-02-09 |
| CN103221197A (en) | 2013-07-24 |
| TW201206669A (en) | 2012-02-16 |
| DE202011110150U1 (en) | 2013-01-18 |
| CA2807380A1 (en) | 2012-02-09 |
| EP2601040B1 (en) | 2017-06-28 |
| EP2601040A1 (en) | 2013-06-12 |
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