GB2468158A - Dissolving Treatment Agent Evenly Through Water for Washing Machine - Google Patents

Dissolving Treatment Agent Evenly Through Water for Washing Machine Download PDF

Info

Publication number
GB2468158A
GB2468158A GB0903442A GB0903442A GB2468158A GB 2468158 A GB2468158 A GB 2468158A GB 0903442 A GB0903442 A GB 0903442A GB 0903442 A GB0903442 A GB 0903442A GB 2468158 A GB2468158 A GB 2468158A
Authority
GB
United Kingdom
Prior art keywords
water
treatment agent
ball
container
washing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
GB0903442A
Other versions
GB0903442D0 (en
Inventor
Patrick Campbell Hunt
Jamie Cobb
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Therefore Ltd
Original Assignee
Therefore Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Therefore Ltd filed Critical Therefore Ltd
Priority to GB0903442A priority Critical patent/GB2468158A/en
Publication of GB0903442D0 publication Critical patent/GB0903442D0/en
Priority to PCT/GB2009/001458 priority patent/WO2009150423A1/en
Publication of GB2468158A publication Critical patent/GB2468158A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06FLAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F19/00Washing machines using vibrations for washing purposes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06FLAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F39/00Details of washing machines not specific to a single type of machines covered by groups D06F9/00 - D06F27/00 
    • D06F39/02Devices for adding soap or other washing agents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/40Specific cleaning or washing processes
    • C11D2111/46Specific cleaning or washing processes applying energy, e.g. irradiation

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Washing And Drying Of Tableware (AREA)

Abstract

Water 32 and treatment agent 30 is introduced into a container 20 and ultrasonic vibration disperses or dissolves the agent in the water evenly, the container with the water and agent then being placed in the drum of a washing machine, or the water and detergent being transferred into the washing machine. The container may be a washing ball 20 and the treatment agent may be a detergent or dye in the form of tablets, liquid or a powder. The ultrasonic vibrations may be between 20 and 40kHz and may be provided by a hand-held unit or integral unit 24 e.g. in a lid 25 of the ball. The ball 20 may be transparent for visual confirmation that the tablet has dissolved and may be part of a unit (figure 1) provided with wi-fi and means to determine the hardness of the water. The transducer may be mains or battery powered, with terminals (34, figure 3) on the ball to connect it to a recharging station and a compartment 28 housing rechargeable batteries and a driver circuit 27.

Description

WASHING MACHINE TREATMENT MATERIAL HANDLING
This invention relates to washing machine treatment material handling, i.e. to the way in which treatment materials such as detergents, fabric softeners and dyes which are designed to be used in washing machines are handled.
Although detergent formulations are known in a wide variety of forms -liquids, tablets, powders -all tend to include materials which are not themselves detergents, for example fillers in powder and tablet forms, and water in liquid forms. The presence of such materials, because it reduces the concentration of detergent, assists in measuring an appropriate amount for the contemplated washing treatment, but entails the disadvantage of extra weight. The extra weight and volume impact adversely -both as regards transportation from manufacturers to retail outlet, and handling by the user.
In recent years, a variety of hollow ball structures have been developed for introducing detergent into the washing chamber of a washing machine. The standard practice is to load the washing chamber with the clothing it is desired to i... fl...... +k-vvcip I, Ql I'..9 LI II I LI..) 1JIQI..., II tiLl LI l 4 JQI I IIJI C1 fJI lI I'...,QI L,.JI I 1Q11 II II LlI II VVI IIL,I I LI I detergent to effect the washing is distributed when the door is closed, the washing machine started, and the chamber partly filled with water and agitated. This does not provide a very even distribution of detergent and it may take some time before it has all been dispensed from the ball into the washing water. This applies both to liquid and powder detergent formulations. However, it does avoid the problems of spillage and detergent accretion when the detergent is introduced via a standard drawer unit set in the washing machine, which is opened to enable detergent to be put in and then closed before the wash cycle commences. Also, the ball itself is rinsed and cleaned during the washing process.
We have now found that these problems may be addressed and at least moderated by the use of an initial treatment step in which the detergent or other formulation is dispersed in a quantity of water by the person wishing to use the washing machine by means of ultrasonication. Substantially instant and effective distribution of the detergent or other treatment material may be achieved by using an ultrasound generator to disperse the material in a quantity of water. The quantity of water does not need to be carefully measured, though the quantity of treatment agent used is preferably determined with accuracy, in particular, so that it may be matched to the prevailing conditions, for example the hardness of the water in the area concerned and the quantity of washing to be processed in the washing machine.
According broadly to a first feature of the present invention, there is provided a treatment process using a washing machine which comprises, as a preliminary step, locating a desired quantity of treatment agent and water in a container and subjecting the treatment agent and water to ultrasound to dissolve or disperse the treatment agent evenly throughout the body of water. The contents of the container may then be emptied into the machine -either into the drum or into a standard detergent-receiving drawer -or the entire container with the dispersed treatment agent in it, may be placed in the drum, in the fashion of a "washing ball".
The process is of particu!ar value if the treatment agent in a detergent in the form of a solid tablet or tablets as this makes it possible to dose the quantity more accurately, as explained further below, but it can be used with liquid concentrates, powders, or even sachet presentations of detergents or other fabric treatment products.
The container is conveniently a ball because this has no corners which could damage clothing as it and the clothing are tumbled during the washing cycle.
There are two approaches to putting the present invention into practice: In a first approach, a container is filled to the desired extent with water and detergent, and then the water and detergent are subjected to ultrasound by inserting an ultrasonic transducer into the body of water and actuating it to provide ultrasonic vibration throughout the body of water. The ultrasonic transducer may, for example, be mounted on the end of a simple hand-held unit, consisting of a casing containing a power source for the transducer, either mains powered or including, for example, some dry battery cells, and the circuit to drive the transducer, and having an actuation button which, when pressed, causes the transducer to emit ultrasonic vibrations. The transducer may be located at the end of a suitable extension extending from the main body of the unit by 5 to 15 cm.
The frequency of the ultrasound may be chosen over a wide range; frequencies of 20 to 40 kHz have been shown to operate effectively. A wide variety of transducers is available, and an appropriate type and power rating may easily be sourced.
Alternatively to a hand-held unit, the transducer may be located on the end of a probe movably located in a housing which has a seating on which the container may be set. Moving the probe down to lower the transducer into the water may automatically actuate it. The housing could conceivably form part of a domestic washing machine, in which case the power for driving the transducer could be derived from the mains power fed to the machine itself.
The alternative approach is to provide within the ball itself a suitable power source, circuitry and transducer which may be arranged to operate by a suitable press switch forming part of the unit or automatically when water is put into the container. Using this latter approach, the user simply has to take the container and insert the appropriate quantity of detergent. It can then be filled with water or simply placed in the washing compartment without any further ado since, once the door is closed and the washing cycle commences, the water entering the washing chamber will fill the ball and trigger the ultrasound treatment.
A particular advantage of the approach provided by the present invention is that the amount of detergent material may be varied depending upon circumstances by presenting the detergent as a liquid, powder, or in relatively small solid pieces, for example tablets or balls, several of which are needed to make up the average amount of detergent needed. More than average may be added in, for example, the case of a hard water area and a large wash, and fewer in the case of a soft water area and/or a reduced load of washing. The detergent pieces are preferably, of course, configured to reduce the risk of their ingestion by children, for example by being made an unappetising colour and/or by being coated with a bittering material.
A major advantage of the present invention is that the improved dispersion achieved means that all of the detergent is used, i.e. detergent use becomes more efficient. Other advantages are that more effective dispersion enables lower wash temperatures to be used without loss of effectiveness, and that ingredients previously included to assist dispersion may be omitted from the formulation.
Separately, the use of a rapid ultrasonic dispersal step may enable the use of different detergent formulations which would be difficult to disperse conventionally.
A further major advantage, though not directly concerned with the efficiency of washing, is that the detergent to be used takes up less space than a box of washing powder or a liquid formulation. This provides the manufacturers and distributors with savings in transport and storage, and this can be seen as "green behaviour" by consumers. Finally, the invention enables the provision to the user of a simple-to-operate, clean and hygienic unit, examples of which are described in more detail below.
In the case of a container which has its own power supply and transducer, the length of time for which the water in it may be subjected to ultrasound may be simply sufficient to disperse or dissolve the detergent, for example 10 or 15 seconds, or it may be "left on" which accordingly means that, during the washing cycle, the water in the washing chamber is subjected to ultrasonic vibration which, it is suggested, may assist in removing soil and dirt from the fabrics of the clothing being washed.
Particularly in the latter case, the transducer is driven for a substantial amount of time and, after each wash, the power supply may need recharging. This may be simply effected by providing two contacts on the outside of the ball which mate with charging contacts in a suitable charging base station in which the ball is placed between washes.
The invention is illustrated by way of example with reference to the accompanying drawings in which: Figure 1 is a diagrammatic representation of a washing ball and base unit for use in accordance with the present invention showing the steps of the process; Figure 2 is a diagrammatic representation of an alternative construction where the washing ball contains an ultrasound transducer, and the three use steps; and Figure 3 is a representation of the ball shown in Figure 2 on a charging base.
Referring to Figure i, this shows a unit comprising a casing I having a hopper 2 for receiving a stack of detergent tablets 3. A slide dispenser in a channel 4 enables tablets 3 to be dispensed one by one into an internal perforated basin 10 located in a transparent ball 5 via an aperture in the top of the ball 5, with the ball 5 resting in a seating 6 in casing 1. A slidable ultrasonic headed plunger 7 is mounted so it can be pushed down, as shown in the central diagram to dip into the water in the ball -water level being at line 9. When the plunger is depressed, its ultrasonic head is actuated (powered by a suitable circuit in turn powered via a mains cable 12) and the vibrations cause the tablets 3 to disperse effectively after a few to several seconds. Because the container is transparent and the tablet is located in the bottom of the perforated basin 10, the operation of dispersion is clearly visible -the dispensed material appears to be being pushed out of the bottom of the basin into the surrounding, originally clear, liquid. The ball 5 is then removed from the unit 1 and contains a well-dispersed detergent liquid 11, shown at the lower right corner of the drawing.
The water may be put into the ball before it is set in seating 6, or the casing may include a water tank (or even be plumbed in via a pipe) from which water is dispensed into the ball before or as the plunger is pushed down. The casing may also include a wi-fi-enabled unit which can send information on usage back to a central point, for example for research into common use patterns Such a unit could also alert the user to relevant messages if provided with a suitable display, and even alert a detergent supplier to the need to send more stock as the level of tablet 3 in hopper 2 runs low.
In a variation, instead of a stack of tablets, the casing may include a hopper into which solid detergent in granular or powder form or liquid detergent may be introduced, and a suitable portion dosing mechanism provided. Such a portion dosing mechanism may include means for adjusting the amount dosed slightly, in order to match the dose to the water hardness in the area. Since this may not be known to the user, the casing may include some device to check and display the water hardness, and conceivably a mechanism for automatically adjusting the dispensing to suit the hardness.
Figure 2 shows a ball 20 having a perforated basin 21 in it into which a detergent block 30 may be placed. An ultrasonic transducer plate 24 is located in a lid 25 which fits into the top of basin 21.
When so fitted, contacts in the lid 25 make electrical connection with contacts at the top of basin 21 which are connected, via leads 26, to a power supply and driver circuit generally indicated at 27 and located in a compartment 28 to one side of the ball 20.
The ball shown in Figure 2 is used as follows: first, a detergent block 30 is placed in basin 21. The ball is then filled with water 32, shown shaded in the central and right hand diagrams, and lid 25 fitted. This causes the transducer to emit ultrasound (right hand diagram) to break up block 30 and distribute its constituents evenly, as can be seen through the transparent wall of the ball. The ball 20 is then placed in the washing chamber and the machine actuated; the treatment liquid flows out from the ball via a series of slots 33 around its periphery.
After use, the ball 20 is placed on its side in a recharging station 32, shown in Figure 3, which may be connected to a mains power supply by means of a mains lead 33. Terminals 34 on the side of ball 20 contact terminals 35 on the recharging station to enable the batteries in compartment 28 to be recharged.

Claims (9)

  1. CLAIMS1. A method of treating washing in a washing machine which includes, as a preliminary step, locating a desired quantity of treatment agent and water in a container, subjecting the treatment agent and water to ultrasound to dissolve or disperse the treatment agent evenly throughout the body of water, and introducing the contents of the container into the washing machine.
  2. 2. A method according to Claim 1 wherein the entire container with the dispersed treatment agent in it is placed in the drum of the machine prior to commencement of a washing cycle.
  3. 3. A method according to Claim 1 or 2 wherein the treatment agent is a detergent in the form of one or more solid tablets.
  4. 4. A method according to any one of Claims 1 to 3 wherein the container is shaped as a ball.
  5. 5. A method according to any one of C1ams I to 4 wherein the container is fiHed to the desired extent with water and treatment agent, and then the water and treatment agent are subjected to ultrasound by inserting an ultrasonic transducer into the body of water and actuating it to provide ultrasonic vibration throughout the body of water.
  6. 6. A method according to Claim 4 wherein the ball contains a suitable power source, circuitry and an ultrasonic transducer arranged to operate by a suitable press switch forming part of the unit or automatically when water is put into the container.
  7. 7. A washing ball Comprising a ball-shaped container adapted to receive a quantity of treatment agent together with a quantity of water, an ultrasonic transducer, a power supply for the transducer, and means to actuate the transducer for a sufficient period of time to disperse the treatment agent in the water by ultrasonication.
  8. 8. A washing ball according to Claim 7 wherein the power supply is rechargeable, and the ball includes two contacts on the outside of the ball which mate with charging contacts in a suitable charging base station on to which the ball is placed.
  9. 9. A washing machine including a container for the receipt of a quantity of treatment material, means for introducing a quantity of water into the container, means for subjecting the treatment agent and water in the container to ultrasonic vibration to disperse the treatment agent in the water, and means for transferring the water with treatment agent thereby dispersed therein from the container into a main washing drum forming part of the washing machine
GB0903442A 2008-06-11 2009-02-27 Dissolving Treatment Agent Evenly Through Water for Washing Machine Withdrawn GB2468158A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
GB0903442A GB2468158A (en) 2009-02-27 2009-02-27 Dissolving Treatment Agent Evenly Through Water for Washing Machine
PCT/GB2009/001458 WO2009150423A1 (en) 2008-06-11 2009-06-11 Washing machine treatment material handling

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB0903442A GB2468158A (en) 2009-02-27 2009-02-27 Dissolving Treatment Agent Evenly Through Water for Washing Machine

Publications (2)

Publication Number Publication Date
GB0903442D0 GB0903442D0 (en) 2009-04-08
GB2468158A true GB2468158A (en) 2010-09-01

Family

ID=40565899

Family Applications (1)

Application Number Title Priority Date Filing Date
GB0903442A Withdrawn GB2468158A (en) 2008-06-11 2009-02-27 Dissolving Treatment Agent Evenly Through Water for Washing Machine

Country Status (1)

Country Link
GB (1) GB2468158A (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110277343A1 (en) * 2008-02-20 2011-11-17 William Howe Dispensing vessel for clothes dryer
US20170088994A1 (en) * 2015-09-28 2017-03-30 Jared Greiman Vibrating washing device
CN106811907A (en) * 2016-11-07 2017-06-09 广东乐惠购网络科技有限公司 A kind of intelligent washing machine
CN107268227A (en) * 2017-08-02 2017-10-20 合肥美的洗衣机有限公司 Portable Washing Equipment
WO2017211699A1 (en) * 2016-06-09 2017-12-14 Unilever Plc Laundry liquid mixing apparatus
CN109518401A (en) * 2019-01-09 2019-03-26 Tcl家用电器(合肥)有限公司 Washing machine component
US11131055B2 (en) 2018-02-26 2021-09-28 Conopco, Inc. Methods and system for monitoring and replenishing one or more laundry components
US11807974B2 (en) 2017-10-05 2023-11-07 Conopco, Inc. Methods and devices for individualized laundry
US11910982B2 (en) 2019-11-01 2024-02-27 Conopco Inc. Recyclable auto-dosing container

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04363331A (en) * 1990-06-29 1992-12-16 Japan Synthetic Rubber Co Ltd Dyeing method for polymer particle
KR950001349B1 (en) * 1992-02-12 1995-02-17 삼성전자주식회사 Detergent resolution device for washing machine
WO2003018897A1 (en) * 2001-08-21 2003-03-06 Newlands Technology Limited Cleaning aid
JP2004300588A (en) * 2003-03-28 2004-10-28 Howa Kk Method for dyeing fiber and dyed product thereof
CN200971436Y (en) * 2006-10-31 2007-11-07 杭州松下家用电器有限公司 Device of detergent dissolving and foaming for washing machine
CN101372804A (en) * 2007-08-21 2009-02-25 苏州三星电子有限公司 Detergent dissolution apparatus of washing machine

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04363331A (en) * 1990-06-29 1992-12-16 Japan Synthetic Rubber Co Ltd Dyeing method for polymer particle
KR950001349B1 (en) * 1992-02-12 1995-02-17 삼성전자주식회사 Detergent resolution device for washing machine
WO2003018897A1 (en) * 2001-08-21 2003-03-06 Newlands Technology Limited Cleaning aid
JP2004300588A (en) * 2003-03-28 2004-10-28 Howa Kk Method for dyeing fiber and dyed product thereof
CN200971436Y (en) * 2006-10-31 2007-11-07 杭州松下家用电器有限公司 Device of detergent dissolving and foaming for washing machine
CN101372804A (en) * 2007-08-21 2009-02-25 苏州三星电子有限公司 Detergent dissolution apparatus of washing machine

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110277343A1 (en) * 2008-02-20 2011-11-17 William Howe Dispensing vessel for clothes dryer
US8205351B2 (en) * 2008-02-20 2012-06-26 Edison Nation, Llc Dispensing vessel for clothes dryer
US20170088994A1 (en) * 2015-09-28 2017-03-30 Jared Greiman Vibrating washing device
US10982373B2 (en) 2016-06-09 2021-04-20 Conopco, Inc. Laundry liquid mixing apparatus
WO2017211699A1 (en) * 2016-06-09 2017-12-14 Unilever Plc Laundry liquid mixing apparatus
CN109312523A (en) * 2016-06-09 2019-02-05 荷兰联合利华有限公司 Liquid detergent mixing apparatus
CN109312523B (en) * 2016-06-09 2021-03-16 荷兰联合利华有限公司 Laundry detergent mixing device
CN106811907A (en) * 2016-11-07 2017-06-09 广东乐惠购网络科技有限公司 A kind of intelligent washing machine
CN107268227B (en) * 2017-08-02 2019-07-19 合肥美的洗衣机有限公司 Portable Washing Equipment
CN107268227A (en) * 2017-08-02 2017-10-20 合肥美的洗衣机有限公司 Portable Washing Equipment
US11807974B2 (en) 2017-10-05 2023-11-07 Conopco, Inc. Methods and devices for individualized laundry
US11131055B2 (en) 2018-02-26 2021-09-28 Conopco, Inc. Methods and system for monitoring and replenishing one or more laundry components
WO2020143289A1 (en) * 2019-01-09 2020-07-16 Tcl家用电器(合肥)有限公司 Washing machine assembly
CN109518401A (en) * 2019-01-09 2019-03-26 Tcl家用电器(合肥)有限公司 Washing machine component
US11585040B2 (en) 2019-01-09 2023-02-21 Tcl Home Appliances (Hefei) Co., Ltd. Washing machine assembly
US11910982B2 (en) 2019-11-01 2024-02-27 Conopco Inc. Recyclable auto-dosing container

Also Published As

Publication number Publication date
GB0903442D0 (en) 2009-04-08

Similar Documents

Publication Publication Date Title
GB2468158A (en) Dissolving Treatment Agent Evenly Through Water for Washing Machine
US8397328B2 (en) Apparatus and method for controlling concentration of wash aid in wash liquid
CN110114528B (en) Retrofittable sensor unit for controlling a dispensing device
CN102164504B (en) For dispensing and the integrated approach and system of stirring/mixing beverage ingredient
CN204211975U (en) Washing machine
JP2003511119A (en) Smart dispensing device
EP2299892B1 (en) Connectable dosing device
GB0205249D0 (en) Improvements in or relating to a container
CA2352060A1 (en) Rechargeable dispensing device
US11071435B2 (en) Dosing device for a cleaning machine
EP3365489A1 (en) Laundry product dosing device and laundry methods
EP3688218A1 (en) A dispensing mechanism for dispensing tablets of a washing product
WO2009150423A1 (en) Washing machine treatment material handling
JP6200099B2 (en) How to process laundry
US5656583A (en) Filter pouch cleaner and method for cleaning coffee or tea maker
HUE032651T2 (en) Metering device for a dishwashing machine having an optical transmitter and/or receiver unit
KR101602888B1 (en) Apparatus for Manufacturing Liquid Detergent in Home
JP2010136794A (en) Dishwasher
CN108309119A (en) The fragrant soap liquid dispenser of one
JP2017510318A (en) Illuminated dispenser
US20030075237A1 (en) Dispensing device and method of cleaning using said device
CN113529363A (en) Detergent feeding device and washing machine
KR101098135B1 (en) Dispenser auto Washing system and method
JP2017507692A (en) Kit for processing substrates
CN219457637U (en) Monocrystalline silicon piece texturing covering device capable of reducing light reflection loss

Legal Events

Date Code Title Description
WAP Application withdrawn, taken to be withdrawn or refused ** after publication under section 16(1)