GB2299052A - Production of multilayer sheets - Google Patents
Production of multilayer sheets Download PDFInfo
- Publication number
- GB2299052A GB2299052A GB9505887A GB9505887A GB2299052A GB 2299052 A GB2299052 A GB 2299052A GB 9505887 A GB9505887 A GB 9505887A GB 9505887 A GB9505887 A GB 9505887A GB 2299052 A GB2299052 A GB 2299052A
- Authority
- GB
- United Kingdom
- Prior art keywords
- polycarbonate
- sheets
- multilayer
- absorber
- branched
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/04—Aromatic polycarbonates
- C08G64/06—Aromatic polycarbonates not containing aliphatic unsaturation
- C08G64/14—Aromatic polycarbonates not containing aliphatic unsaturation containing a chain-terminating or -crosslinking agent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/022—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the choice of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/07—Flat, e.g. panels
- B29C48/08—Flat, e.g. panels flexible, e.g. films
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/16—Articles comprising two or more components, e.g. co-extruded layers
- B29C48/18—Articles comprising two or more components, e.g. co-extruded layers the components being layers
- B29C48/21—Articles comprising two or more components, e.g. co-extruded layers the components being layers the layers being joined at their surfaces
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
- B32B27/365—Layered products comprising a layer of synthetic resin comprising polyesters comprising polycarbonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/07—Flat, e.g. panels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/16—Articles comprising two or more components, e.g. co-extruded layers
- B29C48/17—Articles comprising two or more components, e.g. co-extruded layers the components having different colours
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2369/00—Polycarbonates
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Laminated Bodies (AREA)
Description
A PROCESS FOR THE PRODUCTION OF MULTILAYER PLASTIC SHEETS
This invention relates to a process for the production of multilayer plastic sheets consisting of a core layer and at least one outer layer containing 1% by weight to 15% by weight and preferably 1% by weight to 8% by weight of W absorbers by co-extrusion of branched Sifree polycarbonates of 2, 2-bis- (4-hydroxyphenyl) -propane, characterized in that the branched polycarbonate has an M; of 27,000 to 29,500 and preferably of 28,000 to -29,000.
The characterizing M;'s correspond to relative viscosities (as measured at 250C on a 0.5% solution in
CH2C12) of 1.27 to 1.295 and 1.28 to 1.29, respectively.
The 's may be measured not only via the relative viscosity, but also by determination of the molecular weight by light scattering.
EP-OS 0 247 480 describes plastic sheets of the type in question in which the branched polycarbonate preferably has an M; of 20,000 to 40,000.
For example, a branched polycarbonate is used which has a Nrel of 1.32 (as measured at 25C on a 0.5% solution in CH2C12), corresponding to an ML of 32,000.
In addition, in the examination proceedings on EP
OS 0 247 480, multilayer plastic sheets of branched polycarbonate with an M; of 30,000 and a Tirti of 1.31 were subsequently filed as Examples (communication dated.
19.08.1992).
US-PS 5,108,835 also describes multilayer plastic sheets. In this case, however, only the core layer contains branched polycarbonate (see Example It.2.3, column 11 of US-PS 5,108,835). The branched polycarbonate used again has an Mt of 30,000 and a n el of 1.31 (Example I.2, column 10 of US-PS 5,108,835).
EP-320 632 also describes multilayer plastic sheets of branched polycarbonates (see, for example, page 4,
Table of EP-320 632).
However, general molecular weights of 10,000 to 200,000 are only mentioned in reference to the polydiorganosiloxane/polycarbonate block copolymers (page 6, lines 42/43 of EP-320 632). The polycarbonate used by way of Example has a T7rei of 1 1.31.
DE-OS 3 414 116 and US-PS 4,600,632 describe UVstabilized polycarbonate mouldings produced from polydiorganosiloxane/polycarbonate block copolymers.
US-PS 5,137,949 describes multilayer plastic sheets of which the tN-stabilized layers consist of polydiorganosiloxane/polycarbonate block copolymers.
EP-416 404 describes W-stabilized branched polycarbonates of special diphenols (page 7, lines 14-21 of the
EP and page 11, last paragraph of the EP).
It is mentioned (page 13, line 17) that polycarbonates of the type in question can be used for the production of sheets and multilayer sheets.
It has now been found that evaporation of the UV absorber decreases beyond an average molecular weight M; of < 30,000 so that, by keeping to a certain molecular weight range of the branched polycarbonate, evaporation of the UV absorber is negligible, even in the event of prolonged co-extrusion of multilayer sheets, and has no effect on the favourable mechanical properties of the resulting sheet. This is achieved through the choice of the claimed molecular weight range.
This is illustrated by the two Figures4
Another factor which has to be taken into account is that excessively low molecular weights of the branched polycarbonates, i.e. of the order of < 25,000, result in excessively low melting stability for certain applications of the sheets.
Si-free polycarbonates suitable for the purposes of the invention are the polymers obtainable in known manner from bisphenol A, carbonate donors, branching agents and chain terminators, which are preferably produced in the melt using diphenyl carbonate or by the interfacial process using phosgene (see, for example, DE-OS 1 570 533 and US-CIP-Re 27 682).
Suitable branching agents are those containing three or four or more than four functional groups, particularly those containing three or more than three phenolic hydroxyl groups, which are normally used in quantities of 0.05 mol-% to 2 mol-%, based on the bisphenol A used.
Some of the branching agents which may used~are phlorogucinol, 4, 6-dimethyl-2, 3, 6-tri-(4-hydroxyphenyl) -hept2-ene, 4, 6-dimethyl-2 '4, 6-tri-(4-hydroxyphenyl) -heptane, 1,3, 5-tri- (4-hydroxyphenyl) -benzene, 1,1, 1-tri-(4-hydrox- yphenyl) -ethane, tri- (4-hydroxyphenyl) -phenylmethane, 2,2-bis-4,4-bis-(4-hydroxyphenyl)-cyclohexyl)-propane, 2, 4-bis- (4-hydroxyphenylisopropyl)-phenol, 2,6-bis-(2 hydroxy-5 '-methylbenzyl) -4-methylphenol, 2-(4-hydroxy phenyl) -2- (2, 4-dihydroxyphenyl) -propane, - hexa-(4-(4-hydroxyphenylisopropyl) -phenyl) -orthoterephthalic acid ester, tetra-(4-hydroxyphenyl)-methane, tetra-(4-(4 hydroxyphenylisopropyl) -phenoxy) -methane, 1, 4-bis- (4' , 4" dihydroxytriphenyl)-methyl)-benzene, a,a' ,a11-tris- (4- hydroxyphenyl)-1,3,5-triisopropylbenzene and, more particularly, 3, 3-bis-(4-hydroxy-3-methylphenyl) -2-oxo- 2,3-dihydroindole, 1,4-bis-(4,4-dihydroxytriphenylmeth- yl)-benzene and 3,3-bis-(4-hydroxyphenyl)-2-oxo-2,3dihydroindole.
Other possible branching agents are 2,4-dihydroxybenzoic acid, trimesic acid and cyanuric chloride.
Suitable chain terminators are monophenols, such as phenol itself, p-tert.butylphenol, p-tert.octylphenol, p- nonylphenol, p-chlorophenol and p-cresol.
In the interfacial process, the quantity of chain terminator required to obtain the molecular weight range according to the invention of 27,000 to 29,500 is normally 2 to 4 mol-% of chain terminator, based on the molar quantity of bisphenol A used.
Where the transesterification process is used for production, the quantity of chain terminator required is measured by using the carbonic acid diester, for example diphenyl carbonate, in excess in relation to the bisphenol A in dependence upon the distillation columns used (typically 102 to 108 mols of diphenyl carbonate to 100 mols of bisphenol A).
Other carbonate donors besides diphenyl carbonate or phosgene are other carbonic acid diesters, such as dimethyl carbonate and diethyl carbonate.
Suitable Wabsorbers are, in particular, those corresponding to formulae (1):
in which
R1 and R2 may be the same or different and represent H,
halogen, Cll0 alkyl, Cj10 cycloalkyl, C7-13
aralkyl, C6. aryl, -0-R5 or
where R5 = H or C14 alkyl,
R3 and R' may also be the same or different and represent
H, C1-4 alkyl, C56 cycloalkyl, benzyl or C6lX aryl, m = 1, 2 or 3 and n = 1, 2, 3 or 4, and (II)::
2-(2'-hydroxy-4'-tert. 2-(2'-hydroxy-4'-methyl- octylphenyl)-benzotriazole phenyl)-benzotriazole in which
R1 and R2 may be the same or different and represent C1l5 alkyl radicals or aralkyl radicals, such as
tert.octyl or methyl.
The UV absorbers are incorporated in the branched polycarbonates in known manner by mixing polycarbonate granules with the W absorbers and extruding the resulting mixture or by mixing solutions of the polycarbonates, for example in CH2Cl2, with solutions of the UV absorbers, for example in acetone, and subsequently evaporating the solvents in known manner.
Multilayer plastic sheets are both solid sheets and, in particular, double-walled sheets; one or even both sides of the plastic sheets may be provided with the layers containing UV absorber.
The particular core layer of the plastic sheets according to the invention may of course also contain a basic quantity of UV stabilizer, i.e. for example 0.1% by weight to 0.5% by weight, based on the weight of the core layer.
The thickness of the plastic sheets derives from a 0.5 mm to 16 mm thick core layer and at least one 10 pm to 50 pm thick outer layer containing UV absorber.
Co-extrusion as such is known from the literature (see, for example, EP-110 221 and EP-llO 238).
In the present case, the following procedure is preferably adopted:
An extruder for producing the core layer and further extruders for each outer layer are connected to a coextrusion adapter. The adapter is designed in such a way that the melts forming the outer layers are applied as thin layers to the melt of the core layer and adhere thereto. The multilayer melt strand thus produced is then brought into the required shape (sheet or multilayer sheet) in the subsequently closed die. The melt is then cooled in known manner under controlled conditions by calendering (sheets) or vacuum calibration (multilayersheets) and subsequently cut to length. The calibration or calendering stages may optionally be followed by a conditioning oven to eliminate stresses.
Accordingly, the process according to the invention has to be advantage that the choice of the special reaction parameters, more particularly the special molecular weights of the branched polycarbonates, eliminates the need for an additional outer layer free from UV absorber where it is desired to use low molecular weight, readily volatile UV absorbers.
The process according to the invention may be carried out both discontinuously and, above all, con- tinuously over a period of at least 5 hours and preferably at least 8 hours.
A measuring process for determining the mechanical strength of multi layer sheets is a penetration test adapted for multilayer sheets. In this test, a 5 mm diameter falling mandrel weighing 36 kg which is centered between the dividers penetrates the multilayer sheet and the force, energy consumption and deformation up to penetration are measured. An energy consumption of < 2
J, a fracture force of around 0.4 kN and a deformation of 9 mm are measured for 10 mm multilayer sheets with a surface of 0.8 mm and adequate mechanical properties. If the energy consumption value is < 2 J, the mechanical strength of the multilayer sheet is inadequate.
In addition, the multilayer plastic sheets obtainable by the process according to the invention have excellent surfaces which are free from deposits, evaporation marks or efflorescence stains.
In addition to the UV absorbers, typical additives, for example other stabilizers, flow aids, mold release agents, flameproofing agents, pigments, fine-particle minerals and the like, may be incorporated in the usual quantities in the branched polycarbonates to be used in accordance with the invention.
The additives in question are preferably added to the polycarbonate in conventional units.
The multilayer plastic sheets produced by the process according to the invention are used in particular as glazing and structural elements in house building and in the horticultural sector.
Examples
Example 1
Multilayer sheets are extruded using a branched (0.3 mol-% of 3, 3-bis-(4-hydroxy-3-methylphenyl) -2-oxo-2,3- dihydroindole) polycarbonate with a molecular weight M, of 28,200 (tyre = 1.282).
A 40 ym thick UV absorber-containing polycarbonate layer of the same branched polycarbonate is applied by co-extrusion, the UV absorber used corresponding to formula (I) with R1 = R3 = R' = H and R2 = tert.octyl. The
UV absorber is used in a quantity of 7% by weight, based on the weight of the 40 pm thick outer layer.
The machine used was a vented Reifenhauser extruder with a screw diameter of 70 mm. Co-extrusion was carried out with a Stork extruder (30 mm screw). The die had a width of 350 mm, the divider height of the extruded sheet was 10 mm, the upper belt had a thickness of 0.2 mm. The extrusion parameters were as follows:
Rotational speed: 36 min./l
Current consumption: approx. 70 A
Screw pressure: 104 bar
Output: approx. 61 kg/h
Takeoff rate: 1.4 m/minute
Vacuum calibration: -0.2 bar
UV-stabilized multilayer sheets were extruded for 8 h under the extrusion conditions thus established. The surface of the multilayer sheets is excellent with hardly any sign of the so-called "plate out" effect. The machine was then switched off, the calibrator was opened and the coating formed was collected. A total of 30 mg of UV absorber was isolated.
comparison Example 1
A multi layer sheet was extruded under the same conditions as in Example 1, except that the branched polycarbonate used had an average molecular weight M; of 31,000 (8rev = 1.310). After an extrusion time of 8 h, however, 160 mg of UV absorber were isolated and some white marks were visible on the surface of the sheet.
Example 2
The procedure was as in Example 1, except that the
UV absorber used corresponded to formula (II) instead of formula (I) with
(Tinuvin 234u) 280 mg of W absorber were isolated after an extrusion time of 8 hours.
comparison Example 2
A multilayer sheet was extruded under the same conditions as in Example 2, except that the branched polycarbonate used had an average molecular weight Xw of 31,000 (8rel = 1.310). On this occasion, however, 1400 mg of Tinuvin 234 were isolated after an extrusion time of 8 h.
Example 3
The procedure was as described in Example 1, except that the branched polycarbonate had a molecular weight MX of 29,100 (rel 1.291). 50 mg of UV absorber were isolated after an extrusion time of 8 hours.
Example 4
The procedure was as in Example 2, except that the branched polycarbonate used had a molecular weight M; of 29,100 (#rel 1.291). 320 mg of UV absorber were isolated after an extrusion time of 8 hours.
comparison Example 3
The procedure was as in Example 1, except that the branched polycarbonate had a molecular weight M; of 32,100 (4r 321). 160 mg of W absorber were isolated after an extrusion time of 8 hours.
Comparison Example 4
A multilayer sheet was extruded under the same conditions as in Example 2, except that the branched polycarbonate used had an average molecular weight N; of 32,100 ( 1.321). On this occasion, however, 1700 mg of UV absorber (Tinuvin 234) were isolated after an extrusion time of 8 hours.
Table 1:
Evaporation of W absorber as a function of viscosity
rel W absorber Quantity evaporated Fracture energy 8 h [J] 1.282 Stab. LA 31 30 mg 2.11 1.310 Stab. LA 31 160 mg 2.18 1.282 Tin. 234 280 mg 2.15 1.310 Tin. 234 1400 mg 2.16 1.291 Stab. LA 31 50 mg 2.13 1.291 Tin. 234 320 mg 2.13 1.321 Stab. LA 31 190 mg 2.20 1.321 Tin. 234 1700 mg 2.21
Claims (3)
- CLAIMS 1. A process for the production of multilayer plastic sheets consisting of a core layer and at least one outer layer containing 1% by weight to 15% by weight of UV absorbers by co-extrusion of branched Si-free polycarbonates of 2,2-bis-(4-hydroxyphenyl)-propane, characterized in that the branched polycarbonate has an M; of 27,000 to 29,500.
- 2. A process as claimed in claim 1, characterized in that the polycarbonate has an N; of 28,000 to 29,000.
- 3. A process as claimed in claim 1, characterized in that co-extrusion is carried out continuously for at least 5 hours.
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ES94115644T ES2128484T3 (en) | 1993-10-18 | 1994-10-05 | PROCEDURE FOR OBTAINING PLATES OF SYNTHETIC MATTER OF VARIOUS LAYERS. |
EP94115644A EP0649724B1 (en) | 1993-10-18 | 1994-10-05 | Method of making multilayered plastic plates |
DE59407905T DE59407905D1 (en) | 1993-10-18 | 1994-10-05 | Process for the production of multilayer plastic sheets |
JP27306394A JP3635113B2 (en) | 1993-10-18 | 1994-10-13 | Multilayer plastic sheet manufacturing method |
GB9505887A GB2299052B (en) | 1993-10-18 | 1995-03-23 | A process for the production of multilayer plastic sheets |
AT0053395A AT401909B (en) | 1993-10-18 | 1995-03-24 | Process for the production of multi-layered plastics panels |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4335440 | 1993-10-18 | ||
GB9505887A GB2299052B (en) | 1993-10-18 | 1995-03-23 | A process for the production of multilayer plastic sheets |
AT0053395A AT401909B (en) | 1993-10-18 | 1995-03-24 | Process for the production of multi-layered plastics panels |
Publications (3)
Publication Number | Publication Date |
---|---|
GB9505887D0 GB9505887D0 (en) | 1995-05-10 |
GB2299052A true GB2299052A (en) | 1996-09-25 |
GB2299052B GB2299052B (en) | 1998-04-22 |
Family
ID=32045474
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB9505887A Expired - Fee Related GB2299052B (en) | 1993-10-18 | 1995-03-23 | A process for the production of multilayer plastic sheets |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0649724B1 (en) |
JP (1) | JP3635113B2 (en) |
AT (1) | AT401909B (en) |
DE (1) | DE59407905D1 (en) |
ES (1) | ES2128484T3 (en) |
GB (1) | GB2299052B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2016037865A1 (en) * | 2014-09-11 | 2016-03-17 | Covestro Deutschland Ag | Trim for motor vehicle glazing systems |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5856012A (en) * | 1993-10-18 | 1999-01-05 | Bayer Ag | Process for the production of multilayer plastic sheets |
EP0649724B1 (en) * | 1993-10-18 | 1999-03-10 | Bayer Ag | Method of making multilayered plastic plates |
DE19732090C1 (en) * | 1997-07-25 | 1999-03-25 | Bayer Ag | Polycarbonate molding compounds, process for their preparation and their use as coatings in coextruded plates |
DE10011278A1 (en) * | 2000-03-08 | 2001-09-13 | Bayer Ag | Large polycarbonate moldings with good optical properties, e.g. automobile windscreens, produced from a branched polycarbonate |
DE60106018T3 (en) * | 2000-05-09 | 2010-05-20 | Dow Global Technologies Inc., Midland | Branched polycarbonate blend |
DE10246957A1 (en) * | 2002-10-09 | 2004-04-22 | Bayer Ag | Composition containing polycarbonate and specified small amount of diphenyl carbonate, prepared from bisphenol and diaryl carbonate by ester exchange, is used for making laminate, e.g. massive or multiwall panel for glazing |
US9845379B2 (en) | 2013-10-08 | 2017-12-19 | Covestro Deutschland Ag | Polysiloxane-polycarbonate block cocondensates |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0110221A2 (en) * | 1982-11-25 | 1984-06-13 | Röhm Gmbh | Polycarbonate plastic panel |
EP0247480A2 (en) * | 1986-05-28 | 1987-12-02 | Bayer Ag | Branched thermoplastic polycarbonates protected against UV light |
US5098790A (en) * | 1988-09-07 | 1992-03-24 | Kaysersberg Packaging, S.A. | Multilayer, uv-radiation stabilized polycarbonate panel |
EP0649724A1 (en) * | 1993-10-18 | 1995-04-26 | Bayer Ag | Method of making multilayered plastic plates |
US5445872A (en) * | 1993-03-10 | 1995-08-29 | Ciba-Geigy Corporation | Laminated thermoplastics stabilized with bisbenzophenones |
GB2290745A (en) * | 1994-07-01 | 1996-01-10 | Ciba Geigy Ag | Coextruded stabilised laminated thermolastics |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4185009A (en) * | 1975-01-03 | 1980-01-22 | Bayer Aktiengesellschaft | Branched, high-molecular weight thermoplastic polycarbonates |
US4812498B1 (en) * | 1986-12-22 | 1995-04-11 | Adeka Argus Chemical Co Ltd | Polycarbonate resin compositions having improved resistance to deterioration when exposed to light and containing alkylidene bis(benzotriazolyl phenols). |
DE3739765A1 (en) * | 1987-11-24 | 1989-06-08 | Bayer Ag | COATED SHAPED BODIES AND A METHOD FOR THEIR PRODUCTION |
US4948666A (en) * | 1988-04-22 | 1990-08-14 | Mobay Corporation | Stain resistant polycarbonate panels |
US5086097A (en) * | 1991-01-07 | 1992-02-04 | Mobay Corporation | Ultraviolet stabilizer for polycarbonate compositions |
-
1994
- 1994-10-05 EP EP94115644A patent/EP0649724B1/en not_active Expired - Lifetime
- 1994-10-05 ES ES94115644T patent/ES2128484T3/en not_active Expired - Lifetime
- 1994-10-05 DE DE59407905T patent/DE59407905D1/en not_active Expired - Lifetime
- 1994-10-13 JP JP27306394A patent/JP3635113B2/en not_active Expired - Fee Related
-
1995
- 1995-03-23 GB GB9505887A patent/GB2299052B/en not_active Expired - Fee Related
- 1995-03-24 AT AT0053395A patent/AT401909B/en not_active IP Right Cessation
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0110221A2 (en) * | 1982-11-25 | 1984-06-13 | Röhm Gmbh | Polycarbonate plastic panel |
EP0247480A2 (en) * | 1986-05-28 | 1987-12-02 | Bayer Ag | Branched thermoplastic polycarbonates protected against UV light |
US5098790A (en) * | 1988-09-07 | 1992-03-24 | Kaysersberg Packaging, S.A. | Multilayer, uv-radiation stabilized polycarbonate panel |
US5445872A (en) * | 1993-03-10 | 1995-08-29 | Ciba-Geigy Corporation | Laminated thermoplastics stabilized with bisbenzophenones |
EP0649724A1 (en) * | 1993-10-18 | 1995-04-26 | Bayer Ag | Method of making multilayered plastic plates |
GB2290745A (en) * | 1994-07-01 | 1996-01-10 | Ciba Geigy Ag | Coextruded stabilised laminated thermolastics |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2016037865A1 (en) * | 2014-09-11 | 2016-03-17 | Covestro Deutschland Ag | Trim for motor vehicle glazing systems |
US11207871B2 (en) | 2014-09-11 | 2021-12-28 | Covestro Ag | Bezel for motor vehicle glazing systems |
Also Published As
Publication number | Publication date |
---|---|
GB2299052B (en) | 1998-04-22 |
DE59407905D1 (en) | 1999-04-15 |
EP0649724B1 (en) | 1999-03-10 |
AT401909B (en) | 1996-12-27 |
ES2128484T3 (en) | 1999-05-16 |
GB9505887D0 (en) | 1995-05-10 |
ATA53395A (en) | 1996-05-15 |
JP3635113B2 (en) | 2005-04-06 |
JPH07178789A (en) | 1995-07-18 |
EP0649724A1 (en) | 1995-04-26 |
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