GB2274908A - Pyrolysing waste - Google Patents
Pyrolysing waste Download PDFInfo
- Publication number
- GB2274908A GB2274908A GB9225168A GB9225168A GB2274908A GB 2274908 A GB2274908 A GB 2274908A GB 9225168 A GB9225168 A GB 9225168A GB 9225168 A GB9225168 A GB 9225168A GB 2274908 A GB2274908 A GB 2274908A
- Authority
- GB
- United Kingdom
- Prior art keywords
- vessel
- reaction vessel
- outlet
- liquid
- heating element
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B47/00—Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion
- C10B47/02—Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion with stationary charge
- C10B47/06—Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion with stationary charge in retorts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
- C10B53/07—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of solid raw materials consisting of synthetic polymeric materials, e.g. tyres
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
- Y02P20/143—Feedstock the feedstock being recycled material, e.g. plastics
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
A reaction vessel (12) in which waste vehicle tyres can be subjected to a pyrolytic action includes a convoluted heating element (14), a heat source (16) to supply heat to the heating element and a supply of nitrogen through inlet (20) and outlet (22) to ensure substantial absence of oxygen from the vessel and to carry over volatile gasses from the vessel for further treatment. <IMAGE>
Description
Disposal of Waste Material
The present invention relates to the disposal of waste material. In particular the invention relates to the disposal of used or unserviceable vehicle tyres.
It is well known that many millions of vehicles tyres are scrapped each year, either due to wear or unserviceability.
Such tyres contain valuable materials such as oils, carbon black and steel wire which if they can be recovered economically can be recycled for further uses.
Many proposals have been made for apparatus and methods of obtaining the above valuable materials from waste vehicle tyres. Such methods generally involve the reduction or pyrolysis of the tyres and distillation in order to obtain the oil content of the tyres. Not all of the methods proposed are economical in order to obtain these valuable materials.
The present invention seeks to provide an apparatus and method for the disposal of waste vehicle tyres in which the recyclable materials can be obtained economically and rapidly.
The present invention seeks to provide an apparatus, and method of using the apparatus in which the waste tyres are subjected to a pyrolytic action involving intimate contact between the waste materials and the heat source.
The present invention further seeks to provide an apparatus in which the heavier oils can be drained directly from a vessel in which the pyrolysis takes place.
Accordingly the present invention provides a vessel in which waste vehicle tyres can be subjected to a pyrolytic action, a heating element located within the vessel in intimate contact with a substantial proportion of the tyres within the vessel, a heat source to supply heat to the heating element, means for ensuring the substantial absence of oxygen from the vessel and means for carrying over volatile gases from the vessel for further treatment.
The present invention will now be more particularly described with reference to the accompanying drawing which illustrates one form of apparatus according to the present invention.
Referring to the drawing there is shown a pyrolytic apparatus (10) including a vessel (12) having a heating element (14).
In the present instance the heating element comprises a duct of convoluted form receiving a flow of hot air produced from a burner (16), the hot air being exhausted to atmosphere through an outlet (18) of the duct, or the heat can be used in a further portion of the apparatus.
The vessel (12) has an inlet duct (20) through which a supply of nitrogen gas flows in use. The vessel (12) has an outlet (22) through which the nitrogen flows together with volatile gases produced as a result of the pyrolytic process in the vessel (12).
The vessel (12) has a drain (24) and a collector (26) for the heavier oils produced as a result of the pyrolytic action taking place within the vessel (12).
The apparatus (10) also includes vessels (28) and (30) each of which contain water, the duct (22) discharging into the vessel (28) below the level of the water in that vessel. The vessel (28) has an duct (32) which discharges into the water within the vessel (30), and the vessel (30) has an outlet duct (34).
The vessel (28) also has a drain (36) for the water and an outlet (38) for liquids collecting on the top of the water within the vessel (28).
The duct (22) also has an outlet (40) and a collector (42) for liquid. The duct (22) also has a cooler in order to condense volatiles flowing through the duct (22).
In operation the vessel (12) is packed with waste vehicle tyres. The heating element (14) which can be of a convoluted or any appropriate form is in intimate contact with a substantial proportion of tyres within the vessel. Hot air at a temperature of approximately 13000C is supplied from the heater (16) and flows through the heating element and exhausts through outlet (18). Simultaneously nitrogen gas at slightly higher than atmospheric pressure is introduced into the vessel (12) through the ducts (20) in order to eliminate or reduce as far as possible any reaction of the waste material with any oxygen within the vessel. It will be appreciated that the waste materials are subjected to a pyrolytic action.
As a result of the pyrolytic action the heavier oils from within the vehicle tyres drains to the bottom of the vessel and can be removed through the outlet (24). The lighter volatiles are exhausted through the duct (22) which can be condensed by the cooler (44) if required. Any liquid oil carried over through the duct (22) can drain through the duct (40) into the collector (42). The lighter oils in gaseous form first flow into the water in the vessel (28) where the heavier of them tend to collect in liquid form on the surface of the water in that vessel. The oils now in liquid form can be removed through the outlet (38). The lighter oils in gaseous form are carried over into the water in the vessel (30) where they may condense as liquids on the surface of the water in that vessel.Alternatively the lighter gases and non-condensables together with the nitrogen can exhaust through outlet (34) where further treatment can take place.
It will be appreciated that the form of the heating element (14) can be of any appropriate shape so long as the heating element is in contact with as much of the surface area of the waste material within the vessel (12) as possible.
Also any form of condenser appropriate can be used in respect of the oils carried over in gaseous form from the vessel (12) through the duct (22). For example it may only be necessary to use one vessel containing water or it may be necessary to provide more than two vessels. Alternatively gas scrubbing or condensing apparatus can be used.
After the pyrolytic action is complete and the flow of the heavier liquid oils through the duct (24) has ceased and no further condensation of gaseous oils is taking place the remains of the waste tyres within the vessel (12) can be extracted. Such waste typically comprises the steel wiring used as bracing materials and the solid residue is in a friable form from which the oil has been extracted. Typically the residue is in a crumb like form which can subsequently be processed to obtain carbon black.
The purpose of the invention is to obtain useful materials from waste tyres economically and at a higher rate without the need for complex machinery.
The provision of a heating element which is in contact with a substantial proportion on the vehicle tyres within the vessel enables the heat to be applied rapidly to a large volume of waste material so that the pyrolytic action is relatively rapid.
Also it has been found that with an apparatus of this type the heavier oils tend to drain directly from the vessel without the need for any further processing. The lighter oils which are carried in a gaseous form are easily condensed and recovered.
Claims (12)
1. A reaction vessel in which waste vehicle tyres can be
subjected to a pyrolytic action, a heating element
located within the vessel in intimate contact with a
substantial proportion of the tyres within the vessel, a
heat source to supply heat to the heating element, means
for ensuring the substantial absence of oxygen from the
vessel, and means for carrying over volatile gasses from
the vessel for further treatment.
2. A reaction vessel as claimed in claim 1 in which the
heating element comprises a duct of convoluted form
receiving a flow of heated medium.
3. A reaction vessel as claimed in claim 2 in which the
heated medium comprises a flow of hot air produced from
a burner, the hot air being exhausted either to
atmosphere or to a further portion of the vessel.
4. A reaction vessel as claimed in any one of the preceding
claims having an inlet duct through which a supply of an
inert gas flows and having an outlet through which the
inert gas flows together with volatile gasses produced as
a result of the pyrolytic process in the vessel.
5. A reaction vessel as claimed in claim 4 in which the
inert gas comprises nitrogen.
6. A vessel as claimed in claim 4 including one or more
receiving vessels containing liquid, the outlet from the
reaction vessel containing the inert gasses and volatile
gasses from the vessel discharging into the receiver
vessels below the level of the liquid in the or each
receiving vessel.
7. A reaction vessel as claimed in claim 6 in which the or
each vessel has a drain for the liquid and an outlet for
liquids collecting on top of the liquid in the receiver
vessels.
8. A reaction vessel as claimed in claim 4 in which the
liquid in the receiver vessels comprises water.
9. A reaction vessel as claimed in claim 4 in which the
outlet duct includes a receiver vessel for liquids
contained within the flow of inert gas and volatile
gasses.
10. A reaction vessel as claimed in claim 4 in which the
outlet duct includes condensing means.
11. A reaction vessel as claimed in any one of the preceding
claims including a drain and collector for heavier oils
produced as a result of pyrolytic action taking place
within the reaction vessel.
12. A reaction vessel constructed and arranged for use and
operation substantially as herein described and with
reference to the accompanying drawings.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9225168A GB2274908B (en) | 1992-12-02 | 1992-12-02 | Disposal of waste material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9225168A GB2274908B (en) | 1992-12-02 | 1992-12-02 | Disposal of waste material |
Publications (3)
Publication Number | Publication Date |
---|---|
GB9225168D0 GB9225168D0 (en) | 1993-01-20 |
GB2274908A true GB2274908A (en) | 1994-08-10 |
GB2274908B GB2274908B (en) | 1996-08-14 |
Family
ID=10725981
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB9225168A Expired - Fee Related GB2274908B (en) | 1992-12-02 | 1992-12-02 | Disposal of waste material |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB2274908B (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2387594A (en) * | 2002-04-20 | 2003-10-22 | Jonathan Charles Radford | Method and apparatus for pyrolysing waste materials |
WO2003104354A1 (en) | 2002-06-05 | 2003-12-18 | Izabella Bogacka | Indirectly heated waste plastic pyrolysis device |
US8307770B2 (en) | 2006-03-10 | 2012-11-13 | Pyropure Limited | Waste treatment apparatus and method |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1590748A (en) * | 1976-12-23 | 1981-06-10 | Eckelmann C R | Pyrolysis of rubber or like materials |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4250158A (en) * | 1978-02-15 | 1981-02-10 | Intenco, Inc. | Process for recovering carbon black and hydrocarbons from used tires |
US4740270A (en) * | 1986-06-19 | 1988-04-26 | Universite Laval | Vacuum pyrolysis of scrap tires |
DE59307232D1 (en) * | 1992-04-13 | 1997-10-09 | Siemens Ag | Smoldering device |
-
1992
- 1992-12-02 GB GB9225168A patent/GB2274908B/en not_active Expired - Fee Related
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1590748A (en) * | 1976-12-23 | 1981-06-10 | Eckelmann C R | Pyrolysis of rubber or like materials |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2387594A (en) * | 2002-04-20 | 2003-10-22 | Jonathan Charles Radford | Method and apparatus for pyrolysing waste materials |
WO2003104354A1 (en) | 2002-06-05 | 2003-12-18 | Izabella Bogacka | Indirectly heated waste plastic pyrolysis device |
US8307770B2 (en) | 2006-03-10 | 2012-11-13 | Pyropure Limited | Waste treatment apparatus and method |
US9851100B2 (en) | 2006-03-10 | 2017-12-26 | Pyropure Limited | Waste treatment apparatus and method |
Also Published As
Publication number | Publication date |
---|---|
GB9225168D0 (en) | 1993-01-20 |
GB2274908B (en) | 1996-08-14 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PCNP | Patent ceased through non-payment of renewal fee |
Effective date: 20041202 |