GB2246970A - Adhesive bonded flexible abrasive finishing tool - Google Patents

Adhesive bonded flexible abrasive finishing tool Download PDF

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Publication number
GB2246970A
GB2246970A GB9018171A GB9018171A GB2246970A GB 2246970 A GB2246970 A GB 2246970A GB 9018171 A GB9018171 A GB 9018171A GB 9018171 A GB9018171 A GB 9018171A GB 2246970 A GB2246970 A GB 2246970A
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GB
United Kingdom
Prior art keywords
set forth
tool
monofilaments
shank
adhesive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB9018171A
Other versions
GB2246970B (en
GB9018171D0 (en
Inventor
Alfred F Scheider
R Brown Warner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jason Inc
Original Assignee
Jason Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jason Inc filed Critical Jason Inc
Priority to GB9018171A priority Critical patent/GB2246970B/en
Priority to DE19904026335 priority patent/DE4026335C2/en
Publication of GB9018171D0 publication Critical patent/GB9018171D0/en
Publication of GB2246970A publication Critical patent/GB2246970A/en
Application granted granted Critical
Publication of GB2246970B publication Critical patent/GB2246970B/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D13/00Wheels having flexibly-acting working parts, e.g. buffing wheels; Mountings therefor
    • B24D13/14Wheels having flexibly-acting working parts, e.g. buffing wheels; Mountings therefor acting by the front face
    • B24D13/145Wheels having flexibly-acting working parts, e.g. buffing wheels; Mountings therefor acting by the front face having a brush-like working surface
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B3/00Brushes characterised by the way in which the bristles are fixed or joined in or on the brush body or carrier
    • A46B3/02Brushes characterised by the way in which the bristles are fixed or joined in or on the brush body or carrier by pitch, resin, cement, or other adhesives
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46DMANUFACTURE OF BRUSHES
    • A46D1/00Bristles; Selection of materials for bristles

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Polishing Bodies And Polishing Tools (AREA)
  • Brushes (AREA)

Abstract

An adhesive bonded flexible abrasive finishing tool and method of making the same includes a cup-shape shank 22 of plastic or metal. Flexible nylon abrasive loaded monofilaments 21 of uniform length are formed into a cylindrical bundle. A measured amount of liquid instant cyanoacrylate adhesive 23 is placed into the bottom of the cup portion of the shank and the bundle of monofilaments is driven as a group endwise by a pressure plate through a split funnel mounted on the lip of the cup so that one end of the bundle and thus each monofilament is driven uniformly into the adhesive which then cures rapidly. The monofilaments may preferably be straight or somewhat crimped or wavy and may vary in sectional configuration and abrasive loading. The resulting brush or finishing tool is a low cost light weight tool having improved distribution and density of filaments and a flat even face without a final trimming operation. The tool is ideally suited for automated or robotics finishing operations. <IMAGE>

Description

"Adhesive Bonded Flexible Abrasive Finishing Tool" This invention relates
generally as indicated to an adhesive bonded flexible abrasive finishing tool including a method of making the same, and more particularly to a low cost and light weight end brush type abrasive tool, having improved distribution and density of filaments and which, is- particularly suited to automatic or robotics applications.
7nd brushes or finishing tools are often manufactured utilizing rings, sleeves, pins or keys as anchors to secure the filament bundle in the cap of the shank with the filament bundle being folded as a hairpin in the cup of the shank. This results in a non-uniform distribution and density of the filaments and also normally requires secondary operations such as trimming of the brush face and crimping or swaging of the lip of the cup.
C) t Such internal anchors can in and of themselves affect the dynamic balance 001 of the 1, QUitC apart from causing non-uniform distribution of the 0 filiam ents. Expmples of end brushes or tools using mechanical anchors or keys may be seen in prior U.S. Patents 2,982,983, 3,312,993, and 2,421, 647,.
As ind:,-,qted in the latter two patents a solder or adhesive may be used in to the 're,,, or other anchor with the preferred adhesive in U.S. 2,992,933 being epoxy resins. Many adhesive systems are too viscous, to apply and use and require a substantial cure time. If the preferred filament is a plastic, such as a polyamide with abrasive heavily loaded therein it is difficult to bond the filaments uniformly with an adhesive to a metal or plastic shank without the aid of an anchor and the attendant problems. The adhesive should be a low viscosity liquid which can be readilv metered and which when applied to the bottom of the cup of the shank will uniformly cover the bottom of the cup to a uniform depth.
Moreover, the adhesive should not be a two-part system such as epoxy and should cure quickly.
A method of manufacture of such tool should enable the tool to be made and assernbled quickly without secondary operations such as the trimming of the tool face or modification of the shank to enhance the 0 securing of the filament bundle to the shank.
t) An adhesive bonded flexible abrasive tinishing tool and method of making the same includes a cup-shape shank of plastic or metal. Flexible nylon abrasive loaded monofilaments of uniform length are formed into a cylindrical bundle. A measured amount of liquid instant cyanoacrylate adhesive is placed into the bottom of the cup portion of the shank- and the bundle of monofilaments is driven as a group endwise by a pressure plate through a split funnel mounted on the lip of the cup so that one end of the bundle and tl-ws each monofilament is driven uniformly into the adhesive which then cures rapidly. The monofilaments may preferably be straight or somewhat crimped or wavy and may vary in sectional configuration and 0 abrasive loading. The resulting brush or finishing tool is a low cost light D 0 weight tool having improved distribution and density of filaments and a flat even face without a final trimming operation. The tool is ideally suited for automated or robotics finishing operations.
To the accomplishment of the foregoing and related ends the invention. then, comprises the features hereinafter fully described and particularly pointed out in the claims, the following description and the annexed drawing-s setting forth in detail certain illustrative embodiments of
C, ti'le inve-,,on, these being indicative, however, of but a few of the various 0 ways in -which the principles of the invention may be employed.
Ir the annexed drawings:
Figure 1 is an elevation partially broken away and in section of a finishing tool in accordance with the present invention; Figure 2 is a view of the tool from the top of Figure 1 showing the working face; Figure 3 is a transverse axial section of the shank; Figure 4 is an elevation of the preassembled cut bundle of filaments; Figure 5 is a section of the shank showing the liquid adhesive inserted in the bottom of the cup of the shank; 1 Figure 6 is a view showing the assembly of the bundle and shank; Figure -, is a view similar to Figure 1 showing the employment of a lightweight plastic shank; Figure 8 is a view similar to Figure 2 showing a tool formed with a different size filament in the bundle; ize Figure 9 is a similar view of a smaller tool using the same st 0 filament as in Figure 2; FicTure 10 is a view similar to Fil-ure 9 illustratinc, the face of a 0 0 C> tool with a different type of filament; Ficrure 11 is a view of a st,-aierht single filament which may be 0 t> C> - employed in the formation of the bundle; Figure 12 is a similar view of a wavy, or slightly crimped fila,,-nent Which may be employed in the formation of the bundle; Figures 13-16 are enlarged sections of various types of filaments 0 0 which may be used with the present invention; Fic-ure 17 is a similar section of a plastic monofilament without CI embedded abrasive which may be used with the method of the invention to for,m an end, brush.
Referring firs+ to Figures 1 and 2 there is illustrated a flexible 0 abrasive finishing tool shown generally at 20 in accordance with the present e n t i on. T',,e tool, comprises a cylindrical bundle of abrasive loaded monoi"il-nents 21 which are inserted in a cup-shape shank 22 and bonded to the bottom surface of the cup of the shank by a liquid instant adhesive seen at 23.
As seen in Figure 3 the shank 22 includes an axially projecting cylindrical arbor 25 which may be gripped by the collet of a power tool. The 0 top of the collet is formed into a cup shown generally at 26 which includes a-n annular skirt 27 having a top lip 28 and a flat circular bottom wall 29 which extends normal to the axis of the shank. The bottom of the cup-shape portion tapers into the arbor as indicated at 30.
Referring now to Figure 4 it will be seen that the cylindrical bundle of abrasive loaded plastic monofilaments 21 is preassembled into such bundle and when preassembled the bundle will be provided with circular end faces 33 and 34 which are normal to the axis of the bundle. After the bundle of such monofilaments is formed, each cut to the same length, it may be temporarily held in such cylindrical bundle form by an elastic, tape or paper band indicated at 35.
As seen in Figure 5 the bottom wall 29 of the cup portion of the shank is provided with a uniform distribution of a metered amount of liquid instant adhesive seen at 23. The cylindrical bundle of monofilaments is then driven into the interior of the cup of the shank so that the liquid instant adhesive encrages each of the monofilaments at the face 34 bonding the t> 0 filaments to the shank. The opposite end face 33 of the bundle then becomes the working face of the tool without subsequent trimming as seen in Figures I and 2.
Referring now to Figure 6 there is illustrated a preferred form of assembling the tool of the present invntion. The shank 22 is supported in a jig 38 which may be provided with a hole 39 accommodating the arbor 25. The jig is provided with a tapered conical support surface 40 to ensure that the shank is supported in a vertical upright position. A metered amount of liquid instant adhesive 23 is then placed in the bottom of the cup-shape portion. A split g-uide funnel 42 is then positioned on top of the lip 28 of the cup-shape portion 26. The guide funnel has an interior conical surface 43 which tapers to shoulder 44 which is mounted on the lip 28 of the shank. At the shoulder the internal diameter of the conical surface is the same as the internal diameter of the cup of the shank.
The cylindrical bundle of monofilaments 21 is then placed within the funnel and driven downwardly by pusher plate 46 by a suitable linear actuator such as seen schematically by the arrow 47. In this manner the end face 34 of the bundle 21 is driven into the liquid adhesive 23 which quickly sets bonding each monotilament of the bundle to the bottom wall of the cupshape portion of the shank. Because of the low viscosity of the adhesive some of the adhesive will penetrate between the monofilaments at the face 34 bonding the inner end of each monofilament to adjacent monofilaments.
A suitable pressure limit may retract the pressure plate 46. The split funnel may then be removed and the completed adh,sive bonded flexible abrasive finishing tool may be removed from the support jig.
In the embodiment of the tool seen in Figures 1-6 the shank is " the shank illustrated at 50 metal. However, in the embodiment of Figure 'I is formed of plastic which is approximately one-third the weight of the metal shank. The configuration of the shank is otherwise the same and again a metered amount of liquid instant adhesive indicated at 23 is employed to bond the filament bundle to the shank and the tool may be made in essentially the same manner as in Figure 6.
The plastic shank may be formed of non-brittle plastic such as nylon as long as the plastic material has sufficient strength to absorb the hoop stress in the cup wall as the bundle is driven into the interior of the cup. The lighter weight tool such as seen in Figure 7 requires less torque for rotation and if employed on the end of a robotic arm, the lighter weight provides quicker and more accurate positioning of the tool.
In Figure 8 there is illustrated the working face of a tool in accordance with the present invention employing fairly large diameter cylindrical nylon abrasive mineral loaded monofilarnents as indicated at 52. The shank indicated at 54 may be plastic or metal. A conventional rivion abrasive mineral loaded monofilament as illustrated may be approximately 0.045 inch in diameter and loaded to about 30% by weight of abrasive m, in e r a!.
In Figure 9 there is illustrated a somewhat smaller tool using a smaller diameter nylon abrasive mineral loaded monofilament 56 and a smaller shank 58. In Figure 9 the diameter of the monofilament may be approximately half that in Figure 8.
In Figure 10 there is illustrated a small finishing tool in accordance with the present invention utilizing generally rectangular monofilaments shown at 60 again positioned in a metal or plastic shank 62. As described in more detail in Aipplicants' copending U.K. appLication entitlc-d "Rotary Abrasive Tool And Filament Therefor", Serial No. 2,2211,4721 filed.2nd June, 1999, such rectangular monofilaments may be approximately 0.045 x 0.090 inch or wider and because of the configuration of the monofilament, increased abrasive loading may be obtained up to approximately 45% by weight. The rectangular nature of the filament also significantly increases the stiffness of the filament. Because of the increased abrasive loading and the ability to pack more tightly the rectangular filament, the tool of Figure 10 presents more abrasive material to the working face.
As seen in Figure 11 the preferred form of monofilament 64 is a 0 straight monofilament. However, as indicated in Figure 12 abrasive finishing tools in accordance with the present invention may be made with crimped or wave form monofilaments as indicated at 65. While the crimped or wave form of monofilament reduces the monofilament density, it nonetheless presents the end of the monofilament as indicated at 66 at a slight random angle to the working face of the tool providing somewhat more aggressive action at the work face.
In Figure 13 there is illustrated a typical round monofilament which of course may vary in diameter as indicated. In Figure 14 there is illustrated a triangular monofilament 68. In Figure 15 there is illustrated a square or rectangular monofilament 70 and in Figure 16 there is illustrated the rectangular monofilament 60. Any of such configurations may be employed with the present invention.
Although in the preferred form of the tool, abrasive loaded nylon monofilaments are employed, it will be appreciated that other plastics may be employed both with and without such abrasive loading. Examples of other types of plastics are aramids, polyesters and polypropylenes. Figure 17 illustrates a plastic monofilament 72 without abrasive loading which may be cl formed by the method of the present invention into an end brush using the instant liquid adhesive and the method disclosed. The non-abrasive loaded filaments may also have the sectional configurations shown in Figures 14- 16.
As a liquid instant adhesive, it is preferred to employ a cyanoacrylate of low viscosity or high fludity. It is important that when the adhesive is applied to the bottom wall of the cup that it uniformly cover that wall as indicated in Figure 5.
having the for,,,nula.
-7 Useful with the present invention are alkyl cyanoacrylates CH2 --- / CN \1 COOR R CH3 C2H5 C3H-, etc.
A preferred cyanoacrylate adhesive is an alkoxy alkyl cyanoacrylate having the formula:
CH2 1- C '1 CN COOR R CH3 0 C2H5 C2H5 0 C2H5 Suitable adhesives are available from Loctite Corporation of Newington, Connecticut under the trademark SUPERBONDERS495 or the trademark BLACK 'MAX. SUPERBONDER is a registered trademark of Loctite Corporation. BLACK MAX is also a trademark of Loctite Corporation.
As the abrasive fill material for the plastic monofilarnents, conventional abrasive minerals such as aluminum oxide or silicon carbide may be employed. However, more exotic abrasive minerals may be used such as polycrystalline diamond or cubic boron nitride.
It can now be seen that there is provided a simple and easily constructed adhesive bonded flexible abrasive finishing tool. The tool nonetheless has significant advantages when compared to tools using "hairpin" anchors or rings, sleeves or locking pins. Without the latter a more uniform distribution of the fill materials is obtained and more fill material per tool is obtained because there is no interference with internal locking or mechanical devices.
Th,e method of manufacture also permits the formation of a tool with a flat finished tool face without a final costlv trimming operation. Obviously, the more exotic the abrasive material employed such as polycrystalline diamond, the more costly will be the trimming operation. Without the trimming operation there is no waste of such expensive fill materials. With the present invention the materials are cut one time and pressed into the cup shape shank. Any unevenness is buried inside the cup of the shank, and is held firmly by the instant adhesive.
Moreover, without the internal lock's and with the even distribution of the adhesive and the filament material, better concentricity is obtained avoiding run out or out of round condition problems. The better dynamic balance avoids chatter, bounce or intermittent marks on the workpiece. Such smoother operation also extends the life of the drive motor and makes the tool more effective for robotic operations.
Also, as indicated, the lightweight plastic shank form of the present invention requires less torque and is more readily quickly positioned bv a robotic arm.
The avoidance of the mechanical lock Jf)r the filaments internally o-^ the shank also avoids distorting the filaments, such distortion in.many cqses leading to fracture or early fracture in use.
The simplified method of manufacture permits the use of a wide variety of ac'vanced abrasive filament forms such as the noted straight and crimped round forms, as well as rectangular, flat, oval, square and many other shapes.
Although the invention has been shown and described with respect to certai.- preferred embodiments, it is obvious that equivalent alterations and modiffications will occur to others skilled in the art upon the reading and understanding of this specification. The present invention includes all such equivalent alterations and modifications-
1

Claims (1)

1. A method of making a rotary finishing tool comprising the steps of forming a measured bundle of plastic monofilaments, supporting a cupped shank, placing a measured amount of liquid adhesive in the bottom C, interior of said cupped shank so that such adhesive completely covers the b,ottom of the interior of the cup portion of the shank, and promptly driving such bundle into the cup portion of the shank so that all of the monofilaments at one end of the bundle are in contact with the adhesive, prior to the curing of the adhesive.
2. A method as set forth in claim I wherein said monofilaments are Rt)out 30% by weight loaded, with mineral abrasive.
3. A method as set forth in claim I wherein said liquid adhesive is a eyanoacrylate.
4. A method as set forth in claim 3 wherein said adhesive is an allvl evanoacrvIaLe.
5. A method as set forth in claim 3 wherein said adhesive is an al'No\-., alkv! cvc,:-,oacrvlate.
6. A method as set forth in claim 3 wherein said' adhesive in its uncured form has a low viscosity and completely covers the bottom of the cup portion of the shank.
A method as set forth in claim I wherein the shank is Plastic.
metal.
8.
A method as set forth in claim 1 wherein the shank is g. A method as set forth in claim 1 wherein said plastic monofilaments are abrasive loaded nylon.
10. A method as set forth in claim 1 wherein said plastic monofilaments are round in transverse section.
11. A method as set forth in claim 1 wherein said plastic monofilaments are a polygon in transverse section.
12. A method as set forth in claim 1 wherein said plastic monofilaments are rectangular in transverse section.
c) 13, A method as set forth in claim 12 wherein said monofilaments contain about 45% by weight of abrasive mineral.
14. A method as set forth in claim I wherein said bundle is formed by a plurality of monofilaments each cut to the same length.
15. A tool as set forth in claim I wherein said plastic monofilaments are made of a plastic selected from a group consisting of nylons, polypropylenes, aramids and polyesters.
16. An adhesive bonded flexiblE finishing tool comprising a cup shape shank having a bundle of plastic monofflaments secured in the cup shape shank, and a thin layer of instant adhesive securing one end of each monofilament in the bottom of the cup of the shank.
17. A tool as set forth in claim 16 wherein said adhesive is a evanoacrylate.
18. A tool as set forth in claim I'd wherein said adhesive is an alkyl cyanoacrylate.
19. A tool as set forth in claim IS wherein said adhesive is an alkoxy alkyl eyanoacrylate.
20. A tool as set forth in claim 16 wherein said shank is plastic.
21. A tool as set forth in claim 16 wherein said shank is metal.
22. A tool as set forth in claim 16 wherein said bundle of monofilaments is comprised of monofilaments of uniform length.
23. A tool as set forth in claim 16 wherein said plastic monofilaments are made of a plastic selected from a group consisting of nylons, I> olypropylenes, aramids and polyesters.
24. A tool as set forth in claim 16 wherein said monofilaments are straight.
25. A tool as set forth in claim 16 wherein said monofilaments are crimped.
26. A tool as set forth in claim 16 wherein said plastic monofilaments are round in transverse section.
27. A tool as set forth in claim 16 wherein said monofilaments are a polygon in transverse section.
IF 18. A tool as set forth in claim 16 wherein said monofilaments are rectangular in transverse section.
29. A tool as set forth in claim 16 wherein said monofilaments contain about 45% by weight of abrasive mineral.
30. A tool as set forth in claim 16 wherein said bundle of filaments is of the same uniform density and orientation within the cup shape shank.
31. A tool as set forth in claim 16 wherein said monofilaments are abou! 30% by weight loaded with mineral abrasive.
Any novel cornbi.nati-on or sub-combination (liselosed er -illii-tr,-ited herein.
incl,. -L - Published 1 992 at The Patent office Concepi House. Cardih Road Newport Gweni NP) I RH Further copies mav b- obtained Irom Sales Branch. Unit 6. Nine Mile Point- Cu-nifelinfach- Cross Ke. vs. NewportNPI 7HZ. Printed bv %Iuliiple% technique, lid ST Man Cra.% Kem
GB9018171A 1990-08-17 1990-08-17 Adhesive bonded flexible abrasive finishing tool Expired - Fee Related GB2246970B (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
GB9018171A GB2246970B (en) 1990-08-17 1990-08-17 Adhesive bonded flexible abrasive finishing tool
DE19904026335 DE4026335C2 (en) 1990-08-17 1990-08-21 Method of manufacturing a finishing tool and finishing tool made thereafter

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB9018171A GB2246970B (en) 1990-08-17 1990-08-17 Adhesive bonded flexible abrasive finishing tool

Publications (3)

Publication Number Publication Date
GB9018171D0 GB9018171D0 (en) 1990-10-03
GB2246970A true GB2246970A (en) 1992-02-19
GB2246970B GB2246970B (en) 1994-02-16

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GB9018171A Expired - Fee Related GB2246970B (en) 1990-08-17 1990-08-17 Adhesive bonded flexible abrasive finishing tool

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GB (1) GB2246970B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2269770A (en) * 1992-08-17 1994-02-23 Jason Inc Abrasive filament honing tool
GB2296881A (en) * 1992-09-15 1996-07-17 Jason Inc Rotary abrading tool comprising abrasive plastics elements secured in annular channel of hub by adhesive
US5611326A (en) * 1994-06-29 1997-03-18 S.E.A. Utensili Diamantati S.P.A. Diamond-set insert carrier tool for automatic and manual machines of dressing, smoothing and polishing type for the stone, ceramic and tile industries

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0924031B1 (en) * 1997-12-17 2003-04-16 Botech AG Gesellschaft für Beratung und Oberflächentechnik Tool for working surfaces and edges

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0142636A2 (en) * 1983-10-19 1985-05-29 Weiler Bürsten GmbH Brush with wire bristles for surface working

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2421647A (en) * 1943-04-22 1947-06-03 Osborn Mfg Co End brush
US2982983A (en) * 1957-05-22 1961-05-09 Osborn Mfg Co End brush construction
US3312993A (en) * 1965-01-11 1967-04-11 Osborn Mfg Co Brush construction
US3609792A (en) * 1970-04-28 1971-10-05 Nat Ind For The Blind Plastic set corn brooms and the like

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0142636A2 (en) * 1983-10-19 1985-05-29 Weiler Bürsten GmbH Brush with wire bristles for surface working

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2269770A (en) * 1992-08-17 1994-02-23 Jason Inc Abrasive filament honing tool
GB2269770B (en) * 1992-08-17 1996-05-15 Jason Inc Abrasive filament honing tool and method of making and using same
GB2296881A (en) * 1992-09-15 1996-07-17 Jason Inc Rotary abrading tool comprising abrasive plastics elements secured in annular channel of hub by adhesive
GB2296881B (en) * 1992-09-15 1997-03-05 Jason Inc Perforated strip abrading element and an abrading tool
US5611326A (en) * 1994-06-29 1997-03-18 S.E.A. Utensili Diamantati S.P.A. Diamond-set insert carrier tool for automatic and manual machines of dressing, smoothing and polishing type for the stone, ceramic and tile industries

Also Published As

Publication number Publication date
DE4026335C2 (en) 2003-06-26
GB2246970B (en) 1994-02-16
GB9018171D0 (en) 1990-10-03
DE4026335A1 (en) 1992-02-27

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Effective date: 20040817