GB2209769A - Sputter coating - Google Patents

Sputter coating Download PDF

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Publication number
GB2209769A
GB2209769A GB8821920A GB8821920A GB2209769A GB 2209769 A GB2209769 A GB 2209769A GB 8821920 A GB8821920 A GB 8821920A GB 8821920 A GB8821920 A GB 8821920A GB 2209769 A GB2209769 A GB 2209769A
Authority
GB
United Kingdom
Prior art keywords
anode
target
generating means
field generating
magnetic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
GB8821920A
Other versions
GB8821920D0 (en
Inventor
Anthony Cyril Evans
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ion Tech Ltd
Original Assignee
Ion Tech Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB878721766A external-priority patent/GB8721766D0/en
Application filed by Ion Tech Ltd filed Critical Ion Tech Ltd
Priority to GB8821920A priority Critical patent/GB2209769A/en
Publication of GB8821920D0 publication Critical patent/GB8821920D0/en
Publication of GB2209769A publication Critical patent/GB2209769A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/34Gas-filled discharge tubes operating with cathodic sputtering
    • H01J37/3402Gas-filled discharge tubes operating with cathodic sputtering using supplementary magnetic fields
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34Sputtering
    • C23C14/35Sputtering by application of a magnetic field, e.g. magnetron sputtering

Abstract

A sputter system as illustrated in Fig. 2 has an anode which in operation includes the surface to be coated by sputtering a cathode which in operation includes the target which is the source of coating material, an electric field generating means between anode and cathode and magnetic field generating means which with the electric field contain electrons in the target area for increasing ionising collisions, the magnetic field generating means including magnetic material which extends towards the anode beyond the surface supporting the target on its side remote from the anode and preferably by more than the height of the original target body (which will be destroyed by the sputtering operation). In one embodiment the magnetic material forms north and south pole pieces, a pair of pole pieces of opposite polarity extending closer to each other in the region closer to the anode than in the region remote from the anode. This modification concentrates the magnetic lines of force to the region on the side of the target facing the anode, rather than within the target body. <IMAGE>

Description

SPUTTER COATING A well known method of coating thin films of material on a substrate 'rakes use of the process of sputtering. Sputtering occurs when a potential of a few hundred volts is applied between two plates in a gas chamber at a pressure of about 0.2m bar. The gas at this pressure is ionised under the action of the field (generally an inert gas is used, such as argon). The positive gas ions bombard the cathode as a result of which material is transferred from the cathode (the target) to the anode (the substrate). With diode sputtering the pressure is relatively high and the deposition rate is low (lnm/sec).
If a magnetic field is applied parallel to the cathode surface, the combined magnetic and electric fields confine the electrons to the vicinity of the cathode, increasing their path length by typically 100 times the length of electron path in the simple diode system.
The number of ionising collisions per electron with the gas is therefore greatly increased, increasing the plasma density and hence the deposition rate. Also the operating pressure is decreased by two or three orders of magnitude to the range 10 4 to 5 x 10 bar.
A practical example of a device that uses this type of plasma enhancement is the so-called planar magnetron. One form of this device uses a series of permanent magnets arranged behind the target to produce the required magnetic field. An electrostatic field generates the plasma. In this design, the target is a simple flat disc (Figure 1). Because the poles of the magnetic assembly are behind the target, a target material that has an appreciable magnetic susceptibility will tend to shield the space above the target frcm the influence of the magnets with a consequent reduction of the enhancement effect.
In the extreme case of highly magnetic materials such as iron the field is ccmpletely diverted through the target as a result of which the magnetron operates as a diode without electron confinement and hence at high pressure with slow deposition.
In the known planar magnetron described, the field produced by the magnets comprise lines of flux which extend through the target and return therethrough, the magnetic material being restricted to the area below the target. According to the invention, set out in Claim 1, the magnets are so arranged that the flux penetrates the target only to such a limited extent as to maintain a magnetic field above the target sufficient to contain the electrons and to arrange this magentic material extends above the bottom surface, and preferably the whole, of the target. The flux then skims the top surface region with little extent through the depth of the target.
The target may be in the shape of disc, rectangle or other shape with a central aperture. Preferably pole pieces are located in this aperture and around the edges and extend through the plane of the target.
The target and pole pieces are held at the same potential and are preferably of the same material, or the pole pieces may be capped with the target material.
In one example of the invention as shown in Figure 2, an earthed substrate 11 and an earthed cap-shape non-magnetic shield 12 are provided, as in Figure 1. Within the shield 12 two pole pieces 13 and 14 are provided, the piece 13 comprising an annular ring magnetized with equidistantly spaced magnets 23 around it, the outer boundary of the pole piece 13 lying closely adjacent the inside edge of the cup shield 12. The other pole piece 14 has a pole of opposite sign to 13 at its centre magnetised by magent 24 and is located centrally within the shield 12. At the upper portion of the outside edge of the pole piece 14 is formed recess 23 to support an aluminium spacing ring 16. This ring may be formed in more than one piece in order to be assembled within the recess or the ring may be positioned with the detachable pole piece removed. The target is placed round ring 16.The ring 16, target 21 and magnets 23 and 24 are supported on a cooled copper plate 22.
The pole piece 13, the ring 16 and target 21 are all annular, concentric with the pole piece 14.
Sputtering takes place primarily between the substrate 11 and the target 21 since the pole piece 14 provides a shield over the aluminium spacing ring 16. Because the pole pieces 13 and 14 are at a high negative potential (e.g. -1000 volts) as well as the target 21, some sputtering takes place between the substrate 11 and the pole pieces 13 and 14 which are therefore preferably made of the same material as the target 21 or capped with the target material to avoid contamination of the sputtered film. The pole pieces 13 and 14 extend above the surface of the target ring 21 and establish a suitable magnetic field above the ring 21 so that when the plasma is formed above the target ring by the voltage between the rings and the substrate most of the ions bombard the target.
The electrons are constrained by the magnetic field to remain close to the target and constrained from drifting out of the plasma by the negative electrostatic field on the inner and outer pole pieces. This electrostatic field provides the constraint which would have been provided by the greater vertical component of the magnetic flux in the device of Figure 1.

Claims (4)

CLAIMS :
1. A sputter system comprising an anode, means for supporting a target of material to be sputtered, electric field generating means and magnetic field generating means for generating a magnetic field with which the electric fields will contain electrons over the target position, the magnetic field generating means including magnetic material which extends towards the anode beyond the surface supporting the target on its side remote from the anode.
2. A system as claimed in Claim 1 wherein the magnetic material extends closer to the anode than the intended position of the target.
3. A system as claimed in Claim 2 wherein the magnetic material forms north and south pole pieces, a pair of pole pieces of opposite polarity extending closer to each other in the region closer to the anode than in the region remote from the anode.
4. A sputter system substantially as hereinbefore described with reference to and as illustrated in Fig. 2 of the accompanying drawings.
GB8821920A 1987-09-16 1988-09-19 Sputter coating Withdrawn GB2209769A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB8821920A GB2209769A (en) 1987-09-16 1988-09-19 Sputter coating

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB878721766A GB8721766D0 (en) 1987-09-16 1987-09-16 Sputter coating
GB8821920A GB2209769A (en) 1987-09-16 1988-09-19 Sputter coating

Publications (2)

Publication Number Publication Date
GB8821920D0 GB8821920D0 (en) 1988-10-19
GB2209769A true GB2209769A (en) 1989-05-24

Family

ID=26292740

Family Applications (1)

Application Number Title Priority Date Filing Date
GB8821920A Withdrawn GB2209769A (en) 1987-09-16 1988-09-19 Sputter coating

Country Status (1)

Country Link
GB (1) GB2209769A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0461014A1 (en) * 1990-06-08 1991-12-11 Saint Gobain Vitrage International Equipment for high-rate cathodic sputtering
GB2256084A (en) * 1991-05-13 1992-11-25 Integrated Plasma Ltd Plasma deposition and etching of substrates.
GB2298655A (en) * 1995-03-09 1996-09-11 Leybold Ag Cathgode arrangement for a device for sputtering a pair targets
WO2001049893A1 (en) * 1999-12-29 2001-07-12 Zakrytoe Aktsionernoe Obschestvo 'patinor Coatings Ltd.' Vacuum coating device
CN102610470A (en) * 2011-01-25 2012-07-25 北京北方微电子基地设备工艺研究中心有限责任公司 Magnetron and semiconductor equipment

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2051877A (en) * 1979-04-09 1981-01-21 Vac Tec Syst Magnetically Enhanced Sputtering Device and Method
EP0084970A2 (en) * 1982-01-26 1983-08-03 Materials Research Corporation Magnetically enhanced plasma process and apparatus
US4414086A (en) * 1982-11-05 1983-11-08 Varian Associates, Inc. Magnetic targets for use in sputter coating apparatus
GB2129021A (en) * 1982-10-22 1984-05-10 Hitachi Ltd Sputtering apparatus
EP0115119A2 (en) * 1983-01-26 1984-08-08 Materials Research Corporation Shaped field magnetron electrode
EP0163445A1 (en) * 1984-05-17 1985-12-04 Varian Associates, Inc. Magnetron sputter device having planar and concave targets

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2051877A (en) * 1979-04-09 1981-01-21 Vac Tec Syst Magnetically Enhanced Sputtering Device and Method
EP0084970A2 (en) * 1982-01-26 1983-08-03 Materials Research Corporation Magnetically enhanced plasma process and apparatus
GB2129021A (en) * 1982-10-22 1984-05-10 Hitachi Ltd Sputtering apparatus
US4414086A (en) * 1982-11-05 1983-11-08 Varian Associates, Inc. Magnetic targets for use in sputter coating apparatus
EP0115119A2 (en) * 1983-01-26 1984-08-08 Materials Research Corporation Shaped field magnetron electrode
EP0163445A1 (en) * 1984-05-17 1985-12-04 Varian Associates, Inc. Magnetron sputter device having planar and concave targets

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0461014A1 (en) * 1990-06-08 1991-12-11 Saint Gobain Vitrage International Equipment for high-rate cathodic sputtering
BE1004442A3 (en) * 1990-06-08 1992-11-24 Saint Roch Glaceries Installation of a high rate sputtering.
GB2256084A (en) * 1991-05-13 1992-11-25 Integrated Plasma Ltd Plasma deposition and etching of substrates.
GB2298655A (en) * 1995-03-09 1996-09-11 Leybold Ag Cathgode arrangement for a device for sputtering a pair targets
GB2298655B (en) * 1995-03-09 1998-07-15 Leybold Ag Cathode arrangement for a device for sputtering a pair of targets
WO2001049893A1 (en) * 1999-12-29 2001-07-12 Zakrytoe Aktsionernoe Obschestvo 'patinor Coatings Ltd.' Vacuum coating device
US6692624B2 (en) * 1999-12-29 2004-02-17 International Technology Exchange, Inc. Vacuum coating apparatus
CN102610470A (en) * 2011-01-25 2012-07-25 北京北方微电子基地设备工艺研究中心有限责任公司 Magnetron and semiconductor equipment
CN102610470B (en) * 2011-01-25 2015-01-14 北京北方微电子基地设备工艺研究中心有限责任公司 Magnetron and semiconductor equipment

Also Published As

Publication number Publication date
GB8821920D0 (en) 1988-10-19

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