GB2076019A - Erosion-resistant Alloys - Google Patents
Erosion-resistant Alloys Download PDFInfo
- Publication number
- GB2076019A GB2076019A GB8024790A GB8024790A GB2076019A GB 2076019 A GB2076019 A GB 2076019A GB 8024790 A GB8024790 A GB 8024790A GB 8024790 A GB8024790 A GB 8024790A GB 2076019 A GB2076019 A GB 2076019A
- Authority
- GB
- United Kingdom
- Prior art keywords
- erosion
- matrix
- alloy
- accordance
- titanium carbide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 55
- 239000000956 alloy Substances 0.000 title claims abstract description 55
- 230000003628 erosive effect Effects 0.000 title claims abstract description 35
- 239000011159 matrix material Substances 0.000 claims abstract description 46
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 45
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 40
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 22
- 229910052742 iron Inorganic materials 0.000 claims abstract description 20
- 239000002245 particle Substances 0.000 claims abstract description 14
- 229910052751 metal Inorganic materials 0.000 claims abstract description 3
- 239000002184 metal Substances 0.000 claims abstract description 3
- 238000005552 hardfacing Methods 0.000 claims description 23
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 239000011651 chromium Substances 0.000 claims description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 5
- 229910052804 chromium Inorganic materials 0.000 claims description 5
- 238000009826 distribution Methods 0.000 claims description 5
- 239000011572 manganese Substances 0.000 claims description 5
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052748 manganese Inorganic materials 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 239000010703 silicon Substances 0.000 claims description 4
- 229910000531 Co alloy Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 abstract description 5
- 229910017052 cobalt Inorganic materials 0.000 abstract description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 abstract description 5
- 239000000463 material Substances 0.000 description 17
- 229910000617 Mangalloy Inorganic materials 0.000 description 10
- 239000000758 substrate Substances 0.000 description 5
- 208000016261 weight loss Diseases 0.000 description 5
- 230000004580 weight loss Effects 0.000 description 5
- 229910001018 Cast iron Inorganic materials 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 238000003466 welding Methods 0.000 description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 208000020442 loss of weight Diseases 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000005482 strain hardening Methods 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 2
- 229910000619 316 stainless steel Inorganic materials 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- QFXZANXYUCUTQH-UHFFFAOYSA-N ethynol Chemical group OC#C QFXZANXYUCUTQH-UHFFFAOYSA-N 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/24—Selection of soldering or welding materials proper
- B23K35/32—Selection of soldering or welding materials proper with the principal constituent melting at more than 1550 degrees C
- B23K35/327—Selection of soldering or welding materials proper with the principal constituent melting at more than 1550 degrees C comprising refractory compounds, e.g. carbides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
- C22C29/06—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
- C22C29/10—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds based on titanium carbide
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C32/00—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
- C22C32/0047—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents
- C22C32/0052—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with carbides, nitrides, borides or silicides as the main non-metallic constituents only carbides
Abstract
Alloys which are resistant to erosion, particularly iron-based, cobalt-based and nickel-based alloys, contain a sufficient concentration of titanium carbide, typically from 5% to 60% by weight, to achieve the erosion-resistance required. The alloys also have preferred particle size ranges for the titanium carbide, the metal or alloy matrix and any other component, in order to exhibit the desired erosion resistance.
Description
SPECIFICATION
Erosion-resistant Alloys
The invention relates to hardfacing alloys generally and is particularly concerned with hardfacing alloys having enhanced resistance to erosive wear.
In the following description, all amounts given as percentages are by weight of the total of the alloy or alloy component as the case may be.
Manganese steel consisting of 12% manganese and 1% carbon, balance iron, is commonly employed when work-hardening is both permissible and desirable. Initially, manganese steel usually has a hardness of Rb88 to 92 which, after work-hardening, increases to Rc50 to 52.
Although manganese steel exhibits sufficient resistance to various kinds of wear, such as abrasive wear and adhesive wear including galling, it is lacing in resistance to erosive wear, particularly before it has been work-hardened. It has been found that even the well-known nickel-based hardfacing alloys are lacking in resistance to erosive wear.
In one test, a well-known nickel-based hardfacing alloy, consisting of 0.5% carbon, 2.2% boron, 13.5% chromium, 3.5% silicon and 2.8% iron, balance nickel, was deposited on a substrate of manganese steel by the plasma transferred arc process.In this test, Linde's Plasma Transferred Arc
System was employed at 200 amps and 30 volts, in order to deposit an overlay 3 mm (1/8 inch) thick of the hardfacing alloy on a piece of manganese steel measuring 50x50x25 mm (2 x2 x 1"). The resultant nickel-based hardfacing alloy surface was subjected to erosive wear, by impinging on it chilled cast iron grit at 4.2 Kg/cm2 (60 psig) for 4 minutes and comparing the weight loss from the erosive wear with that exhibited by a manganese steel control subjected to the same treatment.
Surprisingly, the nickel-based hardfacing alloy lost 4.5 grams, compared with a loss of only 2.8 grams by the manganese steel control.
It has now been discovered that nickel-based and other hardfacing alloys can be made which are much more resistant to erosive wear.
According to this invention, a hardfacing alloy comprises a metal or alloy matrix and titanium carbide in a concentration just sufficient to achieve the desired degree of erosive wear resistance.
In accordance with preferred features of the invention, the matrix is an iron-based alloy, a cobaltbased alloy or a nickel-based alloy.
Preferably, the titanium carbide is present in a concentration in the range from 5% to 60% by weight.
In accordance with an especially preferred embodiment of the present invention, the alloy consists of 10% to 25% of titanium carbide in a suitable matrix, preferably iron-based; such an alloy has notably enhanced erosion resistance and also exhibits low porosity and freedom from cracks, as is evidenced by the following tests.
Four test materials were employed.
Test material 1 was ordinary manganese steel plate comprising 12% manganese and 1% carbon, balance iron.
Test material 2 was an alloy comprising 1 5% titanium carbide, 7% nickel and 78% of an ironbased matrix comprising 29% chromium and 2.5% carbon, balance iron. This test material was applied to a substrate of manganese steel, measuring 50x50x25 mm (2x2"x1") by the plasma transferred arc method, as a deposit approximately 3 mm (1/8 inch) thick.
Test material 3 consisted of 50% tungsten carbide and 50% of a nickel-based matrix comprising 14% chromium, 3% boron and 4% silicon, balance nickel.
Test material 4 consisted of 20% titanium carbide, 7% nickel and 73% 316 stainless steel.
Test materials 3 and 4 were applied to manganese steel substrates in the same manner as test material 2.
The four kinds of test piece were subjected to a variety of treatments, including erosive wear, abrasive wear and hardness.
Erosive Wear Test
This consisted of impinging chilled cast iron (No. 16 iron) at 4.2 Kg/cm2 (60 psig) pressure on the surface of 3 samples of each test piece (except for test material 3, only 2 pieces of which were tested) for 4 minutes and recording the weight loss for each material. The following results were obtained.
Test Material 1 2 3 4
Weight loss (g) 2.7 0.10 3.2 2.0
2.6 0.20 3.8 1.8
3.1 0.17 - 1.9
Average weight loss 2.8 0.15 3.5 1.9
The iron-based titanium carbide alloy, 2, is clearly superior to the other materials.
Abrasive Wear Test
This test consisted of grinding each test sample by rotating it against a stationary steel disc in a container into which a slurry of 50 ml of water and 50 g of -140 mesh silicon carbide grit abrasive had been introduced. The test pieces were attached to a drill press actuated by a 2.3 Kg (5 Ib) load on a 15 cm (6") lever. The loaded sample was rotated at 250 rpm for 1 5 minutes. The loss of weight of the test piece was then determined.
Test Material 1 2 3 4
Weight loss (g) 1.37 0.24 1.3 0.59
1.44 0.14 1.2 0.60
These results show that the titanium carbide alloy in an iron-based matrix is clearly superior.
Hardness Test
The hardness of each material was determined by the standard test method of ASTM E-78-14,
Part 10-1975. The average of 5 test readings per sample are as follows.
Test Material 1 2 3 4
Hardness Rb90 Rc52 Rc52 Rc32
There was no loss in deposit hardness, as compared to the 50% tungsten carbide test material.
In order to determine the optimum concentration of titanium carbide in an iron-based matrix,
hardness was determined by the same method for several alloys. The results were as follows:
Alloy Composition Hardness
A 10% TiC+ 12% Ni+78% Fe-Cr-C Rc48
B 15%TiC+5% Ni+80% Fe-Cr-C Rc51.5
C 25% TiC+7% Ni+68% Fe-Cr-C Rc54
D 35% TiC+ 10% Ni+55% Fe-Cr-C N.A.
E 45% TiC+ 12% Ni+43% Fe-Cr-C N.A.
The deposits for alloys D and E, containing 35% and 45% titanium carbide respectively, developed cracks and were not tested further.
Based on all available test data, an alloy consisting of 5% to 25% titanium carbide and 5% nickel, balance an iron-based alloy matrix consisting of 29% chromium, 2.8% carbon, 0.1% manganese and 0.8% silicon, balance iron, provides substantially enhanced erosive wear resistance in comparison with prior art alloys, without sacrificing other qualities.
In addition to the chemical compositions of the titanium carbide alloys of this invention it has been found that the particle size distribution of the titanium carbide preferalby is -270 mesh by down
and, still preferably, from 10 to 20 ,um. With larger particle sizes, there is some loss of erosive wear
resistance and, with lower particle sizes, deposit efficiency is lost and with some titanium carbide
particles oxidation is experienced.
Moreover, it has been found that optimum results are obtained if the nickel component is -140 mesh and the iron-based matrix is -60+325 mesh. If the matrix is larger than 60 mesh, it will not feed well through common sizes of torch nozzles. Of course, this is not a problem if the plasma transferred arc system is not used. If the matrix powder is smaller than 325 mesh, oxidation of the matrix
particles tends to occur. Here again, if the plasma transferred arc system is not employed, the smaller
particle size is not a problem.
Although the tests were made on deposits applied by the plasma transferred arc system, any
other fusion depositing system can be used, including oxyacetylene welding, tungsten inert gas
welding (GTAQ) and plasma mig inert gas welding.
In addition to the above tests conducted on titanium carbide alloys containing an iron-based
matrix, alloys having nickel-based and cobalt-based matrixes also exhibit notably enhanced erosive
wear resistance.
A series of comparative tests was carried out on cobalt-based and nickel-based matrixes, in order
to compare then to one another and to iron-based matrixes, without the use of additional nickel as
described above. 6 different weight concentrations of titanium carbide from 5% to 60% with the
balance matrix were tested. Each test alloy was deposited as a flat layer to a generally uniform
thickness of 3 mm (1/8") on a 50x50x25 mm (2"x2"x1") piece of 1020 steel substrate by the use of
Linde's Plasma Transferred Arc System, Model No. PT-9-H.D., at 200 amps and 30 volts. Each test
plate was bombarded with chilled cast iron grit (No. 1 6) at 4.2 Kg/cm2 (6 psig) for 4 minutes and the
erosive loss of weight was determined.
The compositions of the matrixes were as follows:
Fe Base Co Base Ni Base
C 0.12 1.2 1.9
Cr 13.00 29.0 27.0
Mn 0.50 1.0 0.15
Si 1.00 1.0 1.50
Fe Bai 3.0 10.00
W 4.5 5.20
Ni 3.0 Bal
Co Bal 9.0
The matrixes had a particle size distribution of -60+325 mesh. The titanium carbide was -270 mesh by down (15 to 20 micrometres).
The hardness of each test plate was determined by a standard Rockwell hardness tester.
In this series of tests, the matrixes are well-known hardfacing alloys. The test results below demonstrate that the addition of titanium carbide to well-known hardfacing alloys greatly enhances their hardness and erosive wear resistance.
I-TiC in a Cobalt-based Matrix
Deposit
Deposit Loss in Weight {go Hardness
Matrix 3.2 Rc37
5% TiC+95% matrix 1.8 Rc49 15% TiC+85% matrix 1.0 Rc52
25% TiC+75% matrix 0.8 Rc58 35% TiC+65% matrix 0.8 Rc62
45% TiC+55% matrix 0.4 Rc64 60%TiC+40% matrix 0.1 Rc65 Il-TiC in an Iron-based Matrix
Deposit
Deposit Loss in Weight(g) Hardness
Matrix 2.8 Rc26
5% TiC+95% matrix 2.1 Rc34
15% TiC+85% matrix 1.5 Rc43
25% TiC+75% matrix 0.9 Rc64 35% TiC+65% matrix 0.7 Rc68
45% TiC+55% matrix 0.3 Rc69
60% TiC+40% matrix 0.4 Rc66 Ill-TiC in a Nickel-based Matrix
Deposit
Deposit Loss in Weight (g) Hardness
Matrix 4.6 Rc31 5% TiC+95% matrix 4.6 Rc32 15% TiC+85% matrix 4.4 Rc34 25% TiC+75% matrix 4.3 Rc45 35%TiC+65% matrix 4.1 Rc50
45% TiC+55% matrix 2.9 Rc56 60% TiC+40% matrix 2.4 Rc62
The following conclusions are supported by the test data.
1. The weldability of all alloy powders was rated excellent. The powders wet out readily with substrate material (1020 steel).
2. As little as 5% TiC particles in a matrix shows substantial differences in physical properties of the deposit. The deposit hardness and erosion resistance of the deposit are enhanced.
3. Deposits having 60% of TiC particles did not crack, indicating that high amounts of carbides can be used to obtain maximum hardness and erosion resistance.
4. Different matrix materials, such as iron-based, cobalt-based and nickel-based alloys, can be used to provide erosion-resistant deposits.
Claims (12)
1. An erosion-resistant hardfacing alloy, comprising a metal or alloy matrix and titanium carbide in a concentration just sufficient to achieve the desired degree of erosive wear resistance.
2. An erosion-resistant hardfacing alloy in accordance with Claim 1, in which the matrix is an iron-based alloy.
3. An erosion-resistant hardfacing alloy in accordance with Claim 1, in which the matrix is a cobalt-based alloy.
4. An erosion-resistant hardfacing alloy in accordance with Claim 1, in which the matrix is a nickel-based alloy.
5. An erosion-resistant hardfacing alloy in accordance with any preceding claim, in which the titanium carbide is present in a concentration in the range from 5% to 60% by weight.
6. An erosion-resistant hardfacing alloy in accordance with Claim 5, in which the titanium carbide concentration is in the range from 10% to 25% by weight.
7. An erosion-resistant hardfacing alloy in accordance with-Claim 6, which contains 5% by weight of nickel, the balance comprising an iron-based alloy containing 29% of chromium, 2.8% of carbon, 0.1% of manganese and 0.8% of silicon.
8. An erosion-resistant hardfacing alloy in accordance with any preceding claim, in which the titanium carbide has a particle size distribution of -270 mesh by down.
9. An erosion-resistant hardfacing alloy in accordance with Claim 8, in which the titanium carbide has a particle size distribution in the range from 10 to 20 ym.
10. An erosion-resistant hardfacing alloy in accordance with Claim 7 or Claims 7 and 8, in which the nickel has a particle size of-140 mesh.
11. An erosion-resistant hardfacing alloy in accordance with any preceding claim, in which the matrix material has a particle size distribution of -60+325 mesh.
12. An erosion-resistant hardfacing alloy in accordance with Claim 1, substantially as hereinbefore described.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US15055880A | 1980-05-16 | 1980-05-16 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| GB2076019A true GB2076019A (en) | 1981-11-25 |
| GB2076019B GB2076019B (en) | 1984-03-28 |
Family
ID=22535082
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB8024790A Expired GB2076019B (en) | 1980-05-16 | 1980-07-29 | Erosion-resistant alloys |
Country Status (10)
| Country | Link |
|---|---|
| JP (1) | JPS579853A (en) |
| AT (1) | ATA219181A (en) |
| BE (1) | BE886269A (en) |
| DE (1) | DE3035144A1 (en) |
| DK (1) | DK109281A (en) |
| FR (1) | FR2482627A1 (en) |
| GB (1) | GB2076019B (en) |
| IT (1) | IT1132724B (en) |
| NL (1) | NL8004642A (en) |
| SE (1) | SE8007443L (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3546343A1 (en) * | 1985-01-09 | 1986-07-10 | Valmet Oy, Helsinki | SYNTHETIC PRESS ROLLER AND METHOD FOR THE PRODUCTION THEREOF |
| US4795313A (en) * | 1986-05-28 | 1989-01-03 | Alsthom | Protective tip for a titanium blade and a method of brazing such a tip |
| US4806394A (en) * | 1986-02-04 | 1989-02-21 | Castolin S.A. | Method for producing a wear-resistant, titanium-carbide containing layer on a metal base |
| CN104004942A (en) * | 2014-05-07 | 2014-08-27 | 上海交通大学 | TiC particle-reinforced nickel-based composite material and preparation method thereof |
| EP3137643A4 (en) * | 2014-04-30 | 2017-09-06 | Sulzer Metco (US) Inc. | Titanium carbide overlay and method of making |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5038640A (en) * | 1990-02-08 | 1991-08-13 | Hughes Tool Company | Titanium carbide modified hardfacing for use on bearing surfaces of earth boring bits |
| DE19640789C2 (en) * | 1996-10-02 | 2002-01-31 | Fraunhofer Ges Forschung | Wear-resistant coated components for internal combustion engines, in particular piston rings and processes for their production |
-
1980
- 1980-07-29 GB GB8024790A patent/GB2076019B/en not_active Expired
- 1980-07-31 FR FR8017003A patent/FR2482627A1/en active Granted
- 1980-08-15 NL NL8004642A patent/NL8004642A/en not_active Application Discontinuation
- 1980-09-09 IT IT24563/80A patent/IT1132724B/en active
- 1980-09-18 DE DE19803035144 patent/DE3035144A1/en not_active Withdrawn
- 1980-10-23 SE SE8007443A patent/SE8007443L/en unknown
- 1980-11-20 BE BE0/202875A patent/BE886269A/en not_active IP Right Cessation
- 1980-12-16 JP JP17664980A patent/JPS579853A/en active Pending
-
1981
- 1981-03-10 DK DK109281A patent/DK109281A/en not_active Application Discontinuation
- 1981-05-15 AT AT0219181A patent/ATA219181A/en not_active Application Discontinuation
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3546343A1 (en) * | 1985-01-09 | 1986-07-10 | Valmet Oy, Helsinki | SYNTHETIC PRESS ROLLER AND METHOD FOR THE PRODUCTION THEREOF |
| DE3546343C2 (en) * | 1985-01-09 | 2001-03-01 | Valmet Paper Machinery Inc | Press roll for a paper machine and method for producing a press roll |
| US4806394A (en) * | 1986-02-04 | 1989-02-21 | Castolin S.A. | Method for producing a wear-resistant, titanium-carbide containing layer on a metal base |
| US4795313A (en) * | 1986-05-28 | 1989-01-03 | Alsthom | Protective tip for a titanium blade and a method of brazing such a tip |
| EP3137643A4 (en) * | 2014-04-30 | 2017-09-06 | Sulzer Metco (US) Inc. | Titanium carbide overlay and method of making |
| AU2015253670B2 (en) * | 2014-04-30 | 2019-07-18 | Oerlikon Metco (Us) Inc. | Titanium carbide overlay and method of making |
| CN104004942A (en) * | 2014-05-07 | 2014-08-27 | 上海交通大学 | TiC particle-reinforced nickel-based composite material and preparation method thereof |
| CN104004942B (en) * | 2014-05-07 | 2017-01-11 | 上海交通大学 | TiC particle-reinforced nickel-based composite material and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2076019B (en) | 1984-03-28 |
| FR2482627A1 (en) | 1981-11-20 |
| JPS579853A (en) | 1982-01-19 |
| BE886269A (en) | 1981-03-16 |
| DK109281A (en) | 1981-11-17 |
| SE8007443L (en) | 1981-11-17 |
| IT8024563A0 (en) | 1980-09-09 |
| ATA219181A (en) | 1985-02-15 |
| IT1132724B (en) | 1986-07-02 |
| FR2482627B3 (en) | 1983-05-13 |
| NL8004642A (en) | 1981-12-16 |
| DE3035144A1 (en) | 1981-11-26 |
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